Saeed Mahdavi; Mohammad Hadi Rezvani
Abstract
Kenaf as an industrial plant can play an important role in providing shortage of virgin fiber for paper and board based on the history of cultivation in Iran. Harvesting time of kenaf is one of the most important economic-technical aspect, so the growth rate of kenaf (variety of Cuba) and the weight ...
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Kenaf as an industrial plant can play an important role in providing shortage of virgin fiber for paper and board based on the history of cultivation in Iran. Harvesting time of kenaf is one of the most important economic-technical aspect, so the growth rate of kenaf (variety of Cuba) and the weight ratio of bast, core and pith individually were measured at 5, 6 and 7 months after planting and kenaf biomass was determined after 7 month. Soda-AQ pulping from kenaf bast fiber was adjusted at 14% and 16% chemical charges, 175°C, 120 min., liquor to bast fiber of 5:1 and adding 0.2% AQ. Handsheet was made by the bast pulp from the three harvested times with base weight of 110 g/m2. The results showed that by increasing the harvest period from 5 to 6 and 7 months, stalk height and diameter increased 9% and 5%, and vice versa, respectively. The weight ratio of kenaf bast to core has decreased by increasing of harvest time. Dry and green biomass of kenaf was determined at 33.1 and 7.7 t/ha, respectively. Screen yield, kappa number, and reject were of pulp were measured for combinations of optimal cooking in range of 48.8% to 52.9%, 35.4 to 72.6, and 0.92% to 2.5%, respectively. The beating energy consumption of pulp that prepared from 7 month harvesting time was greater than the others. Optimal conditions were determined as harvesting time of 5 month and cooking variables of 120 min, 165 °C and 16% NaOH for carton top liner. Handmade paper properties compared to kraft liner paper confirms the superiority of paper made from virgin kenaf bast fiber according to national standard of Iran (ISIRI 3054).
Aisona Talaei; Mohammad Hadi Rezvani; Hosseinali Rajabi Cham Heidari
Abstract
The widespread use of chemically/thermally modified wood in outdoor applications and in environments with high relative humidity and high temperature has doubled the importance of using hydrophobic monomers. To evaluate the effect of fluorocarbon modification as a binder on the physical properties and ...
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The widespread use of chemically/thermally modified wood in outdoor applications and in environments with high relative humidity and high temperature has doubled the importance of using hydrophobic monomers. To evaluate the effect of fluorocarbon modification as a binder on the physical properties and chemical structure of paulownia wood, thermal modification was performed at two temperature levels of 150 and 160°C and chemical modification with fluorocarbon at two levels of 15 and 25%. Chemical/thermal modification causes the fluorocarbon monomer and heat to be uniformly transferred into the wood and to reduce its hydrophilicity by causing chemical changes in the wood structure. Specimens were divided into control, thermal and thermal fluorocarbon treatment groups. The thermal fluorocarbon treatment caused modification of the hydroxyl groups and hydrophobicity in specimens. Infrared spectroscopy confirmed the presence of fluorocarbons and bonding with wood polymers. The fluorocarbon reaction resulted in chemical changes, weight gain and bulking of the specimens. The water uptake and volumetric swelling of the heat-treated fluorocarbon specimens were lower than the control and heat-treated ones. Improvement of water repellency efficiency and anti-swelling efficiency of thermal fluorocarbon specimens increased the dimensional stability compared to the thermal control and created a super hydrophobic and leak-resistant coating on the cell walls and inside the lumens. It was attributed to the greater penetration of fluorocarbons and the reduction of wood porosity.
Mohammad mahdi Mehrandish; Aisona Talaei; Mohammad Hadi Rezvani
Abstract
Flammability is one of the most important parameters that limits the range of wood use. Therefore, it is important to improve the fire retardancy properties of wood. The aim of this study was to evaluate the effect of modification with citric acid and its comparison with borax and ammonium chloride on ...
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Flammability is one of the most important parameters that limits the range of wood use. Therefore, it is important to improve the fire retardancy properties of wood. The aim of this study was to evaluate the effect of modification with citric acid and its comparison with borax and ammonium chloride on the flammability of paulownia wood. Test specimens were prepared and in vitro cylinders were saturated with chemical solutions at 10% depletion. Based on pre-treatment conditions, the modification was performed by heating with oven at different temperature and time levels. The fire performance of the samples was evaluated by measuring different parameters. The effect of different fire retardants on water absorption and short-term swelling of the specimens was also studied. The fire test showed that by treating the samples with citric acid and fire retardant materials, less mass reduction, flame retardation time and longer ignition time were obtained. These findings were attributed to the formation of a protective carbon layer by citric acid and fire retardant materials. The flame retardant properties of borax treatment yielded better results than those using citric acid and ammonium chloride. In addition, water absorption and dimensional stability were improved by the presence of citric acid and fire retardant agents. The results of FTIR spectra showed that the carboxylic acid groups reacted with the hydroxyl groups of the wood and increased the weight of the samples. Changes in the crystallinity indices of cellulose, carbonyl and hydroxyl were also obtained from FTIR spectra.
Management and Economics wood
Mohammad Hadi Rezvani; Aisona Talaei; Hosseinali Rajabi Cham Heidari
Abstract
One of the main strategies to develop the extent of wood modification is using active functional groups in wood structure or the so-called impregnation with modified N-methylol compound. The aim of this study was to evaluate the physical properties of paulownia wood after modify with Polycrease ECR Cell ...
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One of the main strategies to develop the extent of wood modification is using active functional groups in wood structure or the so-called impregnation with modified N-methylol compound. The aim of this study was to evaluate the physical properties of paulownia wood after modify with Polycrease ECR Cell wall resin, to name modified dimethylol-dihydroxyethyleneurea (mDMDHEU). Physical test samples were prepared according to ASTM and EN standard and treated with pressure vessel method at two concentration levels; 15 and 25 percent of soluble resin. For polymerization, treated samples were heated in oven for 24-hour periods at 145 and 155 ºC respectively. Weight percent gain (WPG), bulking, water soaking, swelling, anti-swelling efficiency (ASE), leaching and contact angle were determined. High mDMDHEU concentration increased the weight gain and cell wall bulking. Highest weight percent gain (10.70%) and bulking efficiency (6.85%) in to levels of 25% were determined at 155 ˚C. In comparison with the unmodified wood, the mDMDHEU modified wood due to absorbed polymer enhancement exhibited improved dimensional stability and reduced water uptake, and maximum dimensional stability were determined in samples modified using to level 25% mDMDHEU containing solutions and curing temperature 155 ºC. Moreover, mDMDHEU treatment was resistant to leaching. Contact angle measurement further confirmed the improved hydrophobicity of wood after modification. Modification with mDMDHEU improved significantly the physical properties. The improve of the resistance of chemically modified wood exposed to can be attributed to the reduction of wood moisture, bulking of cell walls and cell cavities blocking affect to dominant reactivity mDMDHEU with cell wall wood polymer.
Management and Economics wood
Aisona Talaei; Mohammad Hadi Rezvani
Abstract
In this research the effect of chemical modification with Polycrease ECR on the functional performance of poplar wood to use as wood polymer were investigated. Polycrease ECR the modified dimethyloldihydroxy-ethyleneurea (DMDHEU) was used for chemical modification of wood by impregnation method. Specimens ...
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In this research the effect of chemical modification with Polycrease ECR on the functional performance of poplar wood to use as wood polymer were investigated. Polycrease ECR the modified dimethyloldihydroxy-ethyleneurea (DMDHEU) was used for chemical modification of wood by impregnation method. Specimens prepared according to the ASTM standard and treated in two levels of 30 and 50%. Modification process of specimens were performed at 24 hours in temperature of 120°C. Functional performance including Weight percent gain (WPG), bulking, long term water absorption and volumetric swelling in 8 weeks, bending strength (MOR) and modulus of elasticity (MOE), compression strength parallel to the grain, shear strength and withdrawal resistance of screw parallel to the grain was measured. Two-way analysis of variance (ANOVA) was used for statistical analysis. Obtained results of modified specimens were compared with untreated control. Results showed that modification with Polycrease ECR had significant effects on physical and mechanical properties in treated specimens. Chemical modification in 30% level, lead to reduce long term water absorption and volumetric swelling. Reduction in mechanical properties were not considerable. Chemical modification with Polycrease ECR in 30 % level compared to 50 % level, showed better physical and mechanical properties. Generally, influence of chemical modification on the physical properties (long term water absorption and volumetric swelling) were dominant.
