rouzbeh asadi khansari; Mohammadreza Dehghani Firouzabadi; Hossein Resalati
Abstract
The purpose of this research is to evaluate the effect of various paper coatings on initial contact angle and its evolution over time. We investigated nine coatings on two types of 75 g and 125 g printing papers. Seven coating compositions containing 80% clay, 20% ground calcium carbonate, dispersing ...
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The purpose of this research is to evaluate the effect of various paper coatings on initial contact angle and its evolution over time. We investigated nine coatings on two types of 75 g and 125 g printing papers. Seven coating compositions containing 80% clay, 20% ground calcium carbonate, dispersing agent and various levels of polyvinyl acetate and lactic acid as binders were used. In the last two coatings, we used 100% precipitated calcium carbonate pigments, cationic starch, methacrylate, dispersant and two levels of cellulose nanofibers. In these suspensions, the amount of cellulose nanofibers in composition 8 is twice composition 9. After coating using rod method, the papers were dried then coated and control samples were calendered. We then performed contact angle measurements using water droplet and Kit No were performed. We noticed largest contact angle and smallest angle change over time for sample 6 containing 75% binder. Last two coatings contained cellulose nanofibers, which caused presence of hydroxyl group on the surface and lowered the contact angle. Composition eight was the most hydrophilic sample. Best barrier property Kit No and largest droplet volume after 20 seconds was accompanied with the increase of the binder percentage in the formulation. For the control sample and three treatments with highest binders, the contact angle over time remains relatively constant which is a sign of hydrophobicity. The correlation between contact angle and volume of the water droplet was determined to be 0.951 and 0.936 in the 75g and 125g papers relatively. We did not notice a significant difference in contact angle and Kit No between 75g and 125g samples.
Pulp and paper
Moghadaseh Akbari; Hossein Resalati; Ahmad reza Saraeyan; Mohammad reza Dehghani Firoz Abadi
Abstract
During the paper manufacturing process, especially when mechanical pulp or recycled pulp used, a large amount of soluble and colloidal substances (DCS) are comprised and dispersed or dissolved in the process water. Accumulation of DCS during the papermaking operation with the increasing closure process ...
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During the paper manufacturing process, especially when mechanical pulp or recycled pulp used, a large amount of soluble and colloidal substances (DCS) are comprised and dispersed or dissolved in the process water. Accumulation of DCS during the papermaking operation with the increasing closure process water systems, can have a variety of deleterious effects on papermaking process and paper products. In this study, The effect of anionic trash neutraliziation was investigated by using different catcher anionic tarsh and also pulp washing (removal of anionic trash) on the CMP pulp and paper properties. After the initial preparation chemi-mechanical pulp (CMP), bleached long fiber kraft pulp and mixing the pulps with each other, filler of precipitated calcium carbonate (PCC) was added. Then a cationic retention aid That in this research has been cationic polyacrylamide were added to the mix. To neutralization of and reduce the negative effects of anionic trash, different levels of poly DADMAC with molecular weight 100000-200000 (0.025, 0.05, 0.1, 0.15%) and poly aluminium chloride (PAC) (0.1, 0.25, 0.5%) was added before adding of retention aid. Results showed that the use of different neutralizers imprived of zeta potential and drainage time of pulp, and increase of total retention; but reduces burst index of paper that was not significant statistically. CMP pulp washing and drainage treatment caused reducing COD and on the other hand reduced the amount of anionic trash with organic origin. Washing treatment pulp improved drainage time from pulp, total retention; but reduced burst index. Based on these findings, using cationic polyelectrolyte can introduce as a good strategy to reduce the harmful effects anionic trash and more retention suspension components.
Pulp and paper
Jalil Roshanasan; Mohammadreza Dehghani firozabadi; Mohammad Dahmardeh ghaleh no; Saeideh Sharifi
Abstract
The lignin dissolution in Kraft pulping for wheat straw was studied. Kraft pulping was carried out under the conditions: chemical charge of 18% (as NaOH, based on o.d. bagasse), sulfidity of 25% and liquor to wheat straw ratio of 10:1. Six cooking maximum temperatures of 85,100,110,120,130 and 150 ◦C, ...
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The lignin dissolution in Kraft pulping for wheat straw was studied. Kraft pulping was carried out under the conditions: chemical charge of 18% (as NaOH, based on o.d. bagasse), sulfidity of 25% and liquor to wheat straw ratio of 10:1. Six cooking maximum temperatures of 85,100,110,120,130 and 150 ◦C, were selected and reaction time varied from 0 to 250 min. based on maximum temperature. The Klason lignin, acid soluble lignin, ash and extractive contents of wheat straw were 18.4%, 2.07%, 3.24% and 4.56 respectively.
During alkaline pulping of wheat straw, about 64% and 52% of lignin was removed before reaching to the temperature 100 ◦C and 85 respectively. The values pulp and carbohydrates yield were, about 64%, 58% for 85 ◦C and 61%, 57% for 100◦C.
Pulp and paper
Mahdis Shafaee; Ali Ghasemiyan; Mohammad reza Dhghani Firozabadi; Poneh Ebrahimi
Abstract
In recent years, there has been a lot of attention in producing and using of renewable and environmental friendly cellulose film and coverage. Regarding to the application of these films and coverages in different industries such as food, packaging and medical industries, their antimicrobial property ...
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In recent years, there has been a lot of attention in producing and using of renewable and environmental friendly cellulose film and coverage. Regarding to the application of these films and coverages in different industries such as food, packaging and medical industries, their antimicrobial property is apparent. The purpose of this research is producing cellulose antibacterial film. At first, long fibr pulp convert to NFC using a supergrinder and then nanosilver treated films prepared applying silver nitrate through two different ways. In the first method, silver nanoparticles with considerations of 5 and 10 ppm reduced on NFC particles’ surface using retention aid. In second methods the prepared NFC film has been immersed in solution of Ag nanoparticle in concentration levels of 5 and 10 ppm. On higher concentration of used nanosilver solution, the amount of retained Ag nanoparticle in the first method was higher than the second one whereas, on lower concentration one, the differences of retained nanosilver values between two methods was a little. It has worth of mentioning that immerging method has the benefit of avoiding Ag nanoparticle wasting during pulp draining and nanosilver solutions could be reused simply.
Pulp and paper
Moghadaseh Akbari; Nadia Kabodi torabi; Hossein Rrsalati; Gasem Asadpour atoei; Mohammad reza Dehghani firozabadi
Abstract
Aim of this study is precipitated calcium carbonate cationic modification and comparison of impact of using its with conventional filler (unmodified) on strength properties of paper. One of the defects of adding fillers to paper is decreasing of mechanical strength of paper because of reduction in bonding ...
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Aim of this study is precipitated calcium carbonate cationic modification and comparison of impact of using its with conventional filler (unmodified) on strength properties of paper. One of the defects of adding fillers to paper is decreasing of mechanical strength of paper because of reduction in bonding area between fibers. In this study whit purpose of maintaining the strength of paper, and change the surface charge of precipitated calcium carbonate and replace it with conventional fillers are used.in this research with aim of precipitated calcium carbonate and replacing it with conventional filler was used. Condition of cationic precipitated calcium carbonate preparation was 90 ċ temperature, 3 hours time and 55% water content of cooking process. loading amount of starch was 9, 12 and 15 percent based on precipitated calcium carbonate weight.Papers made at three level: 10, 16, 30 percent of filler in paper sheets contain conventional fillers were compared. Results indicated that papers containing modified-filler have more values of retention rather than those with unmodified filler, both in 20% and 30% filler dosages.papers contained cationic filler have more mechanical strength index in respect of papers contained conventional fillers.
Pulp and paper
Mohammadreza Dehghani Firouzabadi; Afshin Tvasoli; Saeed Mahdavi
Abstract
We studied the possibility of replacing imported long fiber pulp (ILFP) with kenaf bast fiber soda pulp (KBFSP) to improve the quality of paper made with bagasse soda pulp (BSP). To do so, we produced BSP with kappa number 13.5 similar to that prepared by Pars Paper Mill. We also produced KBFSP with ...
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We studied the possibility of replacing imported long fiber pulp (ILFP) with kenaf bast fiber soda pulp (KBFSP) to improve the quality of paper made with bagasse soda pulp (BSP). To do so, we produced BSP with kappa number 13.5 similar to that prepared by Pars Paper Mill. We also produced KBFSP with kappa number 21.6 similar to the unbleached imported ILFP. The yield percent for BSP and KBFSP were respectively 48.9 and 55.6 %. The maximum pulping temperature was 165 °C; alkaline was 20% based on sodium hydroxide and ratio of liquor to dry weight of the raw material was 8:1. All the three pulps were beaten up to a freeness degree of 400 ml, CSF. Amounts of 0, 10, 20 and 30 percent ILFP and KBFSP were mixed with 100, 90, 80 and 70 percent BSP to produce hand sheets. In all cases of KBFSP mixing with BSP, the thickness of the generated hand sheets were higher than those produced through mixing ILFP with BSP while the density was lower. The difference in burst strength and breaking length of a mixture of 30% KBFSP with 70% BSP in the hand sheets were non-significant as compared with those of ILFP and BSP. Tear strength and opacity of mixing 30% KBFSP with 70% BSP were significantly higher than those of the ILFP and BSP with the same mixing ratio. We suggest that KBFSP provides a suitable replacement for ILFP to improve physical and strength properties of paper made with BSP.
