Pulp and paper
somayeh heydari; Ahmad Reza Saraeyan; Mohamadreza Dehghani firozabadi; Alireza Shakeri; babak shokri
Abstract
Ethylene vinyl alcohol (EVOH) copolymer is of semi crystalline materials with excellent barrier properties to gases. Also, it has shown outstanding chemical resistance. Despite its low gas permeability, EVOH copolymer displays poor water and water vapor resistance. In this study, Trimethoxymethylsilane ...
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Ethylene vinyl alcohol (EVOH) copolymer is of semi crystalline materials with excellent barrier properties to gases. Also, it has shown outstanding chemical resistance. Despite its low gas permeability, EVOH copolymer displays poor water and water vapor resistance. In this study, Trimethoxymethylsilane (as hydrophobic coating) was deposited by Plasma Enhanced Chemical Vapor (PECVD) method on the coated paper with Ethylene vinyl alcohol in order to improve the paper's barrier properties of moisture transmission. Coating by PECVD method was done in the certain conditions of time 6 min and pressure 300 m Torr. Different treatments were applied for power including 50, 70 and 90W.Then contact angle was measured in order to determined improvement of the paper's barrier properties of moisture transmission . The result showed that papers which were coated with Trimethoxymethylsilane had higher contact angle water 55.7% more than the control. The results revealed that the best condition was obtained by 50 W power. The structural and chemical properties of deposited layer were observed with Fourier Transform infrared spectroscopy- Attenuated Total Reflectance (FTIR-ATR) and Energy Dispersive X-ray Spectroscopy (EDS). The results confirmed bonding of silane on the surface EVOH polymer.
Pulp and paper
somayeh heydari; Ahmad Reza Saraeyan; Mohammad Reza Dehghani Firouzabadi; Alireza Shakeri; babak shokri
Abstract
DOR:98.1000/1735-0913.1398.34.100.66.1.9.1604 In this study, EVOH was coated on paper made of CMP pulp by extrusion method in order to improve the paper's barrier properties of oxygen transmission. Ethylene vinyl alcohol (EVOH) shows poor moisture resistance despite less gas permeability. Then, dimethoxydimethylsilane ...
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DOR:98.1000/1735-0913.1398.34.100.66.1.9.1604 In this study, EVOH was coated on paper made of CMP pulp by extrusion method in order to improve the paper's barrier properties of oxygen transmission. Ethylene vinyl alcohol (EVOH) shows poor moisture resistance despite less gas permeability. Then, dimethoxydimethylsilane was deposited using Plasma Enhanced Chemical Vapor Deposition on EVOH film as the hydrophobic layer. A random factorial experiment was designed with three factors at three levels including time (6-8-10 min), pressure (30-0400-500 m Torr), and radio frequency power (50-70-90 W). The contact angle, oxygen transmission rate, tensile strength, and strain energy were measured to obtain the optimum condition. Expert Design method using response surface was used to optimize the condition coating Dimethoxydimethylsilane in order to improve the hydrophobic properties, reduce OTR, increase tensile strength and strain energy. Based on this method the optimum condition was suggested as: time 6 min, pressure 499.99 m Torr and power 50W. Keywords: Extrusion , Contact angle, Oxygen transmission rate, Response Surface methodology.
Pulp and paper
Moghadaseh Akbari; Hossein Resalati; Ahmad reza Saraeyan; Mohammad reza Dehghani Firoz Abadi
Abstract
During the paper manufacturing process, especially when mechanical pulp or recycled pulp used, a large amount of soluble and colloidal substances (DCS) are comprised and dispersed or dissolved in the process water. Accumulation of DCS during the papermaking operation with the increasing closure process ...
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During the paper manufacturing process, especially when mechanical pulp or recycled pulp used, a large amount of soluble and colloidal substances (DCS) are comprised and dispersed or dissolved in the process water. Accumulation of DCS during the papermaking operation with the increasing closure process water systems, can have a variety of deleterious effects on papermaking process and paper products. In this study, The effect of anionic trash neutraliziation was investigated by using different catcher anionic tarsh and also pulp washing (removal of anionic trash) on the CMP pulp and paper properties. After the initial preparation chemi-mechanical pulp (CMP), bleached long fiber kraft pulp and mixing the pulps with each other, filler of precipitated calcium carbonate (PCC) was added. Then a cationic retention aid That in this research has been cationic polyacrylamide were added to the mix. To neutralization of and reduce the negative effects of anionic trash, different levels of poly DADMAC with molecular weight 100000-200000 (0.025, 0.05, 0.1, 0.15%) and poly aluminium chloride (PAC) (0.1, 0.25, 0.5%) was added before adding of retention aid. Results showed that the use of different neutralizers imprived of zeta potential and drainage time of pulp, and increase of total retention; but reduces burst index of paper that was not significant statistically. CMP pulp washing and drainage treatment caused reducing COD and on the other hand reduced the amount of anionic trash with organic origin. Washing treatment pulp improved drainage time from pulp, total retention; but reduced burst index. Based on these findings, using cationic polyelectrolyte can introduce as a good strategy to reduce the harmful effects anionic trash and more retention suspension components.
Pulp and paper
Iman Akbarpoor; Hossein Resalti; Ahmad reza Saraeyan
Abstract
In this study, Deinking of old newspaper was investigated by chemical and enzymatic methods. Chemical treatment was done using chemicals at different times of 10, 20 and 30 minutes, consistency of 10%, temperature of 50±1!C along with washing, flotation and combination of washing/flotation. While, ...
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In this study, Deinking of old newspaper was investigated by chemical and enzymatic methods. Chemical treatment was done using chemicals at different times of 10, 20 and 30 minutes, consistency of 10%, temperature of 50±1!C along with washing, flotation and combination of washing/flotation. While, Enzymatic treatment was accomplished at different concentrations of 0.025, 0.05, 0.1 and 0.2% of cellulase enzyme (on the basis of oven dried waste paper), pH range of 5-5.5, different times of 10,15 and 20 minutes, consistency of 10%, temperature of 50±1!C along with washing. The results comparison of optimum chemical and enzymatic treatments showed that, deinked pulp by chemical method had higher brightness and yellowness. Also, deinked pulp by chemical method resulted the papers with higher bulk, higher caliper and higher air resistance.
Pulp and paper
Ahmad reza Saraeyan; Somayeh Heidari; Ahmad reza Shakeri
Abstract
Increased environmental concerns over the use of certain synthtic packaging in combination with consumer demands led to increased interest in alternative packaging materials research. Paper is biodegradable and widely used in packaging applications therefore perfectly safe for the environment. In an ...
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Increased environmental concerns over the use of certain synthtic packaging in combination with consumer demands led to increased interest in alternative packaging materials research. Paper is biodegradable and widely used in packaging applications therefore perfectly safe for the environment. In an effort to produce more environmentally friendly materials, renewable and biodegradable biopolymers have been utilized as paper coating substances. in this study carried out to determine effect of the four type of biopolymers such as anionic starch, chitosan, polyvinyl alcohol and etylenvinyl alcohol, on the smoothness, Water absorption, air resistance, burst Index properties paper made of bagasse soda pulp. Coating done whith coater tester. Coating weight was 3-6 g/m2. The results of the mechanical and physical properties of the handsheets showed that, led to increase index burst handsheets coated with etylenvinyl alcohol and anionic starch indices as 34.4 and 26.26% compared to control sample. Air resistance and smoothness was for coated paper with starch more than control sample indices as 173.23 and 18.73%. also coated paper with chitosan showed minimum value..
Pulp and paper
Farhad Zeinaly; Ahmad Reza Saraeian; Mohammadhadi Aryaei monfared; Ali Kazemi Tabrizi
Abstract
In conducting environmentally friendly processes for pulp production, first step is to reduce the effluent pollution load in each stage, and because the bleaching process is the most polluting stage in the production of pulp, improving it is one of the most important matters. The first act to ameliorate ...
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In conducting environmentally friendly processes for pulp production, first step is to reduce the effluent pollution load in each stage, and because the bleaching process is the most polluting stage in the production of pulp, improving it is one of the most important matters. The first act to ameliorate bleaching process of chemical pulps is the reduction of colored materials, mostly lignin, which enter to the bleaching section. Thus, the use of oxygen delignification stage after pulping and before bleaching process is the key stage in improving process and cleaner production. In this study, the effect of conducting oxygen-delignifying treatment by two kinds of machines, and under different process condition, on chemical, physical, mechanical and optical properties of bagasse soda pulp was investigated. The bagasse soda pulp with the kappa number of 20, 955 ml/g viscosity, and 37% ISO brightness was prepared from Pars Hafttapeh Company. Oxygen-delignifying treatments were carried out with three different temperatures of 90, 100 and 110°C, and two oxygen pressures of 5 and 7 bars, with and without magnesium sulfate addition, by two kinds of machines. Results indicated that oxygen delignification treatment led to intense decrease in pulp kappa number, while the pulp viscosity did not change. Results of measuring delignified pulp viscosity showed that the magnesium sulfate addition caused to prevention of pulp viscosity downfall. The increase in reaction temperature had a significant effect on the process improvement, but raising the oxygen pressure did not have a meaningful effect on the process. The pulp brightness was increased about 4-6%. And also, due to the need of shorter time in order to reach the reaction temperature in the Iranian made machine, pulp delignifying by this machine was a little lower than Quantum machine.
Pulp and paper
Mehrnoosh Tavakoli; saraeyan ahmad reza; hossein resalati; ali ghasemian
Abstract
The present study was carried out aiming to investigate the effect of using Deinked Mixed Office Waste Pulp (MOW) on the properties of Alkaline Peroxide Mechanical Pulp (APMP) from cotton stalk. APMP pulps was prepared using chelating agents such as Na2SiO3 and DTPA (control sample) and without ...
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The present study was carried out aiming to investigate the effect of using Deinked Mixed Office Waste Pulp (MOW) on the properties of Alkaline Peroxide Mechanical Pulp (APMP) from cotton stalk. APMP pulps was prepared using chelating agents such as Na2SiO3 and DTPA (control sample) and without these agents in two-stage pulping withL/Wratio 6:1(ml/g), 20 minutes impregnation time at 70 0Cfor firststage, 60 minutes impregnation at 75 0Cfor second stage. Also, pulp was preparedfrommixed office waste paper, whichweredeinked with conventional flotation and then each pulp was separately refined up to about 300 ml CSF. The handsheets were made from control sample pulps, APMP without chelating agents, MOW deinked pulp and mixing with 10%, 20% deinked pulp with control APMP. Physical and mechanical properties were determined using TAPPI standard methods. Deinked MOW pulp had the maximum values of density, brightness, strength properties and APMP pulp without chelating agents had the minimum values. Among mixed pulps, APMP pulp containing 20% deinked MOW pulp showed the maximum value of density, brightness, burst index and tear index.
Chemical conversion
mahdiye mazandarani; ali ghasemian; ahmadreza Saraeyan; mahdi mashkour; SeyedRahman Jafari Petroudy
Abstract
In the present study, preparation of cotton stalk (Sahel variety) as one of the common agricultural residues was studied through three stages as Soda-AQ chemical pulping, delignification and alkaline treatment, aiming for the production of cellulose nanocrystal. In order to identify the optimum condition ...
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In the present study, preparation of cotton stalk (Sahel variety) as one of the common agricultural residues was studied through three stages as Soda-AQ chemical pulping, delignification and alkaline treatment, aiming for the production of cellulose nanocrystal. In order to identify the optimum condition for the preparation of cellulose nanocrystal, acidic hydrolysis of the produced alpha-cellulose was done using 64% sulfuric acid, 25, 35 and 45 minute as time and at 35, 45 and 55 degree centigrade as temperature. Atomic Force Microscopy (AFM), X-Ray Diffraction, and Dynamic Light Scattering (DLS) were used to identify the quantitative and qualitative properties of cellulose nanocrystals. AFM micrographs showed that more severe condition of the treatments decreased the thickness of the cellulose nanocrystals. XRD results also demonstrated that the preparation stages of alpha-cellulose as well as acidic hydrolysis treatments much effectively increased the degree of crystallinity. DLS results indicated that 98.7 percent of the produced nanocrystals under the condition of 55 degree centigrade and 45 minute were in the range of 18-95 ηm, whose highest abundance was in the range of 18-39 ηm. Thus, the mentioned condition were determined as the best and optimum condition for the production of cellulose nanocrystal from cotton stalk cellulose.
Zinat Farhadi; Ahmad reza Saraeian; Mohammad reza Dehghani firuzabadi
Abstract
This study was done to investigate the effect of bark content on the physical and mechanical properties of kraft pulp from chips Ppopulous deltoids. Three tree of the populous deltoids from the same age were randomly selected cut from Shastkalate research forest Gorgan. A disc was taken from each tree. ...
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This study was done to investigate the effect of bark content on the physical and mechanical properties of kraft pulp from chips Ppopulous deltoids. Three tree of the populous deltoids from the same age were randomly selected cut from Shastkalate research forest Gorgan. A disc was taken from each tree. The discs were completely debarked and wet weight of wood and bark from each disc was determined. Then weight ratio of wood/bark was determined in each disc. Kraft pulp was prepared under following pulping condition: sulfidity 25%, AA: 20%, temp: 170 0c, l/w: 6/1 and bark content as 0 , 6, 12, 18 and 24%, by weight. Pulp with kappa number around 20 was prepared from each treatment, which were separately beaten to reach freeness value around 350 ml,CSF. To determined the effect bark content on yield and kappa number of the pulp and their physical and mechanical properties, F test was used in completely randomized, and for comparison of the means, Dunkan test was used. Yield and kappa number of the pulps were as 50/32 - 52/03% and 20/37 - 21/17, respectively. With increasing, of the bark content, density of paper was decreased and the lowest value of which was 0/477 g/cm2for bark – contained pulp. Also, with increasing of the bark content to 18%, strength properties of the related pulp was improved.
Physics and anatomy
ahmad saraiyan; soodeh zhand
Abstract
In this study, the effect of boiling water pre-treatment on yield, optical, physical and mechanical properties of NSSC (Neutral Sulfite Semi Chemical) pulp from Zagroos wheat straw (Golestan province) was investigated. Chopped wheat straw was pretreated in boiling water for 30 minutes, water to straw ...
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In this study, the effect of boiling water pre-treatment on yield, optical, physical and mechanical properties of NSSC (Neutral Sulfite Semi Chemical) pulp from Zagroos wheat straw (Golestan province) was investigated. Chopped wheat straw was pretreated in boiling water for 30 minutes, water to straw ratio of 10:1. NSSC pulping was carried out at constant pulping conditions including liquor to straw ratio of 10:1, maximum pulping temperature of 160ºC and 30 minutes pulping time. In order to study the effect of NaOH on strength properties of paper, in some trails only Na2S03 were used. Pulping was followed by defibration in laboratory refiner to reach 380±25mlCSF freeness. Handsheets at 60gr/m² were made from each pulp. The strength properties were determined on the basis of TAPPI standard. Results show that pre-treatment imparted a significant increasing effect on the strength properties of papers such as tensile, burst, breaking length, stiffness and density, except RCT strength. Increasing the chemical charge specially NaOH improved the pulp freeness, yield and handsheet density but the handsheet thickness was reduced.
Soodeh Zhand; Masih Masoudifar; Ahmad reza Saraeian; Ali Ghasemian
Abstract
The purpose of this study was to compare the properties of wheat straw (Zagros sp) collected in Golestan province NSSC pulp under alkaline pretreatment with 1% sodium hydroxide and boiling pretreatment. Wheat Straw pretreatment with 1% sodium hydroxide and hot water at water to straw ration of 10 to ...
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The purpose of this study was to compare the properties of wheat straw (Zagros sp) collected in Golestan province NSSC pulp under alkaline pretreatment with 1% sodium hydroxide and boiling pretreatment. Wheat Straw pretreatment with 1% sodium hydroxide and hot water at water to straw ration of 10 to 1 was conducted at 70ْC for half an hour. NSSC pulping was carried out at constant pulping condition including liquor to straw ratio of 5:1, maximum temperature at 160ºC for 30 minutes. In order to study the effect of sodium hydroxide on strength properties of paper in some cases only Na2S03 was used. After pulping, defibration was carried out by laboratory refiner to reach 380±25ml (CSF). Sixty gram/m² hand sheets were prepared from each pulp. The strength properties were determined according to TAPPI standard. Results showed that with the exception of RCT strength, pretreatment had significant effect on increasing the strength properties of papers and by alkaline pretreatment, brightness of the pulps decreased and tensile strength, burst strength, breaking length, stiffness and density increased. Using chemical pretreatment especially sodium hydroxide resulted in reduction in yield and brightness level and improvement in strength of the pulps.
Ahmad reza Saraeian; Mozhdeh Mashkour
Abstract
Considering the problems initiated by sodium silicate on reducing the life expectancy of processing equipments and paper strength, recycling of old newspaper using Poly (acrylic acid), Sodium Salt Grafted to Poly (ethylene oxide) complex were investigated. The organic complex was used at 0.3, 0.5, 0.7, ...
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Considering the problems initiated by sodium silicate on reducing the life expectancy of processing equipments and paper strength, recycling of old newspaper using Poly (acrylic acid), Sodium Salt Grafted to Poly (ethylene oxide) complex were investigated. The organic complex was used at 0.3, 0.5, 0.7, 1, 2 and 3% levels (based on dry weight of waste paper) in deinking. The effect of various charges of the organic complex on the physical and optical properties of deinked pulp was studied and compared with the control (ONP deinked using 0.5% sodium silicate). The results of physical properties measurements showed that the lowest paper caliper (143.07 µm) and the highest density (0.43 g/cm3) were obtained by increasing the complex charge up to 2%. Also, the highest and lowest freeness was observed applying 3% (426.66 mL CFS) and 2% (350 mL CSF) organic complex respectively. These values were less than the freeness of the control sample. The results of optical properties analysis indicated that the brightness increased to 48.01% ISO and the yellowness was reduced to 6.23 % ISO by as the dosage of organic complex was increased up to 1%. The opacity of paper decreased as the organic complex charge increased. In general, the paper with higher density and brightness, lower yellowness and suitable opacity could be produced using 0.7- 2% Poly Acrylic Acid-Sodium Salt grafted to Polyethylene Oxide complex in deinking of old newspaper
Soodeh Zhand; Masieh Masoudifar; Ahmad Reza Saraeian; Ali Ghasemiyan
Abstract
In this study the effect of alkaline pretreatment with 1% NaOH on physical, optical and mechanical properties and refining of NSSC (Neutral Sulfite Semi Chemical) wheat straw pulp were investigated. The wheat straw (Zagros Sp.) was obtained from croplands Golestan province. Splinted wheat straw was pretreated ...
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In this study the effect of alkaline pretreatment with 1% NaOH on physical, optical and mechanical properties and refining of NSSC (Neutral Sulfite Semi Chemical) wheat straw pulp were investigated. The wheat straw (Zagros Sp.) was obtained from croplands Golestan province. Splinted wheat straw was pretreated with 1% NaOH(on the basis of OD weight) at 70 degrees for 30 minutes. The main pulping was performed at 160 ˚C with the fixed ratio of 5:1 Na2S03 and NaOH. After pulping defibration was done by lab-refiner to 380±25ml (CSF) and total yield and changes in Kappa was determined. Hand sheets of 60 gr. /m² were made on the basis of TAPPI standard and physical, optical and mechanical properties determined. The results show that alkaline pre-treatment has a significant effect in increasing of physical, optical and mechanical properties. Calculating primary freeness of pulps indicates that by increasing chemical compounds and NaOH, freeness decreases and that by increasing chemical compounds paper density increases, whereas yield, caliper and bulk decrease.
Saeid Kamrani; Ahmad reza Saraeian; Hossein Resalati; Ali Ghasemian
Abstract
The main objective of this study was to determine the trends of fiber dimension variation along the longitudinal direction of wheat straw as a criteria for papermaking. Zagross wheat straw was collected from the agricultural and natural resources research center, Golestan province .The fiber biometric ...
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The main objective of this study was to determine the trends of fiber dimension variation along the longitudinal direction of wheat straw as a criteria for papermaking. Zagross wheat straw was collected from the agricultural and natural resources research center, Golestan province .The fiber biometric characteristics including fiber length, fiber diameter, lumen diameter and cell wall thickness in three internodes were determined .Results showed that, the difference in fiber diameter, lumen diameter and cell wall thickness were sttistically significant between three internodes of wheat straw at 99% confident Based on the computed papermaking indices (flexibility ,softness and runkle number), it was predicted that the papers produced from the first and the third internode of wheat straw may have higher tensile,folding and burst strength and the papers produced from the second internode may have higher tear strength.
Sabah Ashrafi birghani; Ahmadreza Sraeyan
Abstract
The purpose of this study was to compare the effects of various concentrations of sodium hydroxide and treatment times on the properties of bagasse and Eastern cottonwood (Populus deltoids) cold soda pulp and paper. The cold soda pulp was prepared using various concentrations of sodium hydroxide (5, ...
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The purpose of this study was to compare the effects of various concentrations of sodium hydroxide and treatment times on the properties of bagasse and Eastern cottonwood (Populus deltoids) cold soda pulp and paper. The cold soda pulp was prepared using various concentrations of sodium hydroxide (5, 10, 15% based on oven dry weight), different treatment times (20, 40, 60 min.), and constant liquor to wood ratio of 10:1 at 25 ºC and atmospheric pressure. The pulp prepared after 40 min treatment time was selected and refined to the freeness of 400 ml CSF. Analysis of the properties of hand sheets was conducted based on completely randomized design. Duncan multiple range grouping test was used to classify the properties of papers. The results indicated that, the yield of pulp obtained from Eastern cottonwoodand bagasse pulp varied between 86.54% to 94.52% and 70.65 to 87.32% respectively. The absorbed alkali was varied from 2.15% to 4.78 % for Eastern cottonwood and 3.06% to 6.80% for bagasse. Eastern cottonwood had the highest yield, thickness and strength properties whereas the highest absorbed alkali and paper density were observed in bagasse. It was observed that as the concentration of sodium hydroxide was increased from 5% to 15%, the yield of pulp and the thickness of paper decreased, while the absorbed alkali, density and the strength properties of paper increased. In general, the cold soda pulp from Eastern cottonwood provided higher quality compared with bagasse under the same pulping conditions.
Pulp and paper
Saeideh Sharifi; Ahmad reza Saraeyan; Hossein Resalati
Abstract
Preparation and pre-treatment of raw material influences the pulp production time and color elimination. Pulp consistency during the treatment also influences the color reaction. In the preparation of the APMP pulp, bagasse was pretreated by either boiling water, 1% NaOH as well as 1% NaOH + 1% ...
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Preparation and pre-treatment of raw material influences the pulp production time and color elimination. Pulp consistency during the treatment also influences the color reaction. In the preparation of the APMP pulp, bagasse was pretreated by either boiling water, 1% NaOH as well as 1% NaOH + 1% H2O2. The liquor to bagasse ratio, treatment time and temperature of alkaline peroxide treatment were constant as 10:1, 30 min, and 70 °C respectively. The treatment duration was determined so that at least five percent of the initial hydrogen peroxide remained at the end of chemical treatment. Characteristics of hand sheets were determined according to the TAPPI standard. The results showed that, the duration of the treatment for pulp consistency of 10, 15 and 20% was 50, 30 and 10 minute, for sample pretreated with boiling water and 290, 230 and 170 minute for the sample pretreated with 1% NaOH + 1% H2O2. The highest brightness of the paper reached with bagasse pretreated in boiling water at 20 % consistency.
Physics and anatomy
Meisam Aliabadi; Eiman Akbarpoor; Ahmadreza Saraeyan; Jalil Roshnasan
Abstract
This research was performed to investigate fiber biometrical properties (length, diameter and fiber thickness) of hornbeam species from Astara in Iran. Initially, disks were prepared with three trees of hornbeam species and then fiber isolation was carried out using Franklin method. Length, diameter ...
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This research was performed to investigate fiber biometrical properties (length, diameter and fiber thickness) of hornbeam species from Astara in Iran. Initially, disks were prepared with three trees of hornbeam species and then fiber isolation was carried out using Franklin method. Length, diameter and wall thickness of fiber provided were determined by laboratory microscope using eye scaled lens. The measurement of fiber dimensions was made at the pith region and at the distances of 2,6,12 and 15 centimeters and four geographical sides. The results indicated that length, diameter and wall thickness of fiber increased significantly with enhance of distance from pith. The highest fiber length, diameter and wall thickness obtained were 1.509 mm, 23.93 µm and 3.897 µm, respectively. The consequences attained from changing of fiber dimensions at various distances from pith to bark indicated that fiber dimensions change decreased by increase in distance from pith up to 15 cm and the highest change of fiber was observed at distance of 2-6 cm from pith. The results of measuring the fiber dimensions at various geographical sides didn't indicate any significant deference between the values of fiber length, diameter and wall thickness at 1% level of probability. The combined effects of distance from pith and different geographical sides also did not show any significant deference on fiber dimensions.
Iman Akbarpoor; Hossein Resalati; Ahmad reza Saraeian
Abstract
In this study, deinking of waste newspaper was investigated by conventional and enzymatic methods. Conventional deinking was done in pulping times of 10, 20 and 30 minutes along with different processes of washing, flotation and combined washing/ flotation. Enzymatic deinking was accomplished ...
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In this study, deinking of waste newspaper was investigated by conventional and enzymatic methods. Conventional deinking was done in pulping times of 10, 20 and 30 minutes along with different processes of washing, flotation and combined washing/ flotation. Enzymatic deinking was accomplished at different charges of 0.025, 0.05, 0.1 and 0.2% cellulase enzyme (based on oven-dried waste paper), pulping times of 10,15 and 20 minutes, pH range of 5-5.5 along with one-stage washing process. Optimum compositions were selected from chemical and enzymatic treatments and then physical and mechanical properties of the paper produced in optimum conditions were compared. Achieved results from comparison of the physical properties of optimum chemical and enzymatic treatments showed that, the paper produced from deinked pulp by conventional method had higher calliper, bulk and porosity. Using of 0.1% cellulase resulted the papers with higher tensile and breaking length compared to chemical treatments. The papers could be produced with similar burst and tear indexes compared to chemical treatments using of 0.1% cellulose, as well.
Physics and anatomy
Jalal Shakhes; Ahmad reza Saraeyan; Farhad Zynali
Abstract
This work investigated effect of height and cultivar on morphological properties of bast and core fiber of tobacco stalk (Nicotiana tabacum). Also, in this research cultivar effect on chemical properties of tobacco stalk were investigated. Selected cultivars include Barley and Virginia, and investigative ...
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This work investigated effect of height and cultivar on morphological properties of bast and core fiber of tobacco stalk (Nicotiana tabacum). Also, in this research cultivar effect on chemical properties of tobacco stalk were investigated. Selected cultivars include Barley and Virginia, and investigative height positions were chosen 5, 50 and 75% of stalk height. Results indicated that bast fiber length, diameter and wall thickness are more effective than those of core fiber. Chemical analysis of stalk’s parts indicated that cellulose and ash contents of bast were higher than those of core, but lignin content of bast was significantly less than that of core. Also, extractive material of bast was less. Statistic results showed that length and wall thickness of Barley’s bast fiber were higher compare to Virginia, but there was no significant difference in terms of morphological properties of core fibers between these cultivars. Cellulose percentage of Barley cultivar was higher, where as lignin, extractives and ash contents of Barley were lower than that of Virginia cultivar. Also, cultivar type didn’t have significant effect on contents of tobacco stalk parts (bast, core and pith). Results indicated that, fiber length, diameter and wall thickness of bast decreased as height increases, but in core fiber, just fiber length decreased and other properties of core fiber had different behavior. Moreover, bast and pith percentages increased by height increasing while, core percentage decreased. In general, results of this research showed that, tobacco stalk are a suitable row material for pulp and paper production, re fiber dimensions and chemical components.
Hossein Shob chary; Ahmad reza Saraeyan; Ali Ghasemian
Abstract
This study was conducted to investigate the properties of cotton stalks APMP pulp. APMP prepared from chipped cotton stalks. the pulps were prepared separately from debarked and bark containing stalks using three two-stage treatments.Sodium hydroxide charge as a constant level of 4% and hydrogen ...
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This study was conducted to investigate the properties of cotton stalks APMP pulp. APMP prepared from chipped cotton stalks. the pulps were prepared separately from debarked and bark containing stalks using three two-stage treatments.Sodium hydroxide charge as a constant level of 4% and hydrogen peroxide at three levels of 0, 1 and 2% were used in to two-stages, sodium hydroxide as a constant level of 2% and hydrogen peroxide at three levels of 2, 3, 4% were applied. Other conditions of pulping was time's of 20 min for first stage and 100 min for second stage, temperature 70°C and l/w:6:1 as fixed factors considered. Pulp yield determined after neutralization and defiberation. All the pulps were refined up to 300 (ml, CSF) freeness and handsheets were made, then and properties of papers measured using TAPPI standards. Results showed that the pulp yield and brightness was higher in free-bark compared to bark-containing conditions. Also paper produced in free-bark condition with cotton stalks core, resulted the higher tensile and burst indexes and higher breaking length compared to whole cotton stalk.While tear index didn’t show significant difference.Generally, caliper and bulk rates were high in total treatments (free-bark and bark-containing conditions) from cotton stalk APMP process.
Meisam Aliabadi; Eiman Akbaepoor; Ahmad reza Saraeian
Abstract
In this study, the effect of organic complex "sulvy-x" on the optical properties of hornbeam CMP pulp bleached with hydrogen peroxide was investigated. Sulvy-x was used in two sequences silicate-free and silicate containing in hydrogen peroxide bleaching. The brightness of papers increased to 60.52 and ...
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In this study, the effect of organic complex "sulvy-x" on the optical properties of hornbeam CMP pulp bleached with hydrogen peroxide was investigated. Sulvy-x was used in two sequences silicate-free and silicate containing in hydrogen peroxide bleaching. The brightness of papers increased to 60.52 and the yellowness decreased to 22.6 with increasing silicate charges up to 1% . However, at higher levels than 1% , the brightness decreased and the yellowness increased. Without dosage of sodium silicate but using 0.5% of sulvy-x, maximum brightness of 59.3% and minimum yellowness of 23.4 % ISO was achieved. In silicate-containing bleaching, combination of 0.5% sulvy-x and 0.7% sodium silicate resulted the highest brightness (60.28 % ISO) and the lowest yellowness (23 % ISO). Optimum charge of sodium hydroxide and hydrogen peroxide were determined as 2.5% and 5%.The best time for bleaching of hornbeam CMP pulp was 90 minutes in either sequences. With regard to results obtained, utilization of the organic complex of sulvy-x could be a suitable substitution for sodium silicate which produces the pulp with higher brightness and lower yellowness in conventional peroxide bleaching.
Pulp and paper
Saeid Kamrani; Ahmad reza Saraeyan; Eyman Akbarpoor
Abstract
In this study, mechanical and optical properties of CMP, one stage APMP and two stage APMP pulps ( from Tajan wheat straw Golestan province ) were investigated. wheat straw collected at research center of Agriculture and Natural resources of Golestan province. Fiber dimensions such as average fiber length ...
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In this study, mechanical and optical properties of CMP, one stage APMP and two stage APMP pulps ( from Tajan wheat straw Golestan province ) were investigated. wheat straw collected at research center of Agriculture and Natural resources of Golestan province. Fiber dimensions such as average fiber length , diameter cell , lumen and fiber wall thickness were assessed at 1.18mm, 18.156, 11.461 and 3.396 microns, respectively. chemical components such as cellulose , lignin , ash and extractives were assessed at 53.7, 21.1, 5.1 and 8.5 percent, respectively. Based on the preliminary experiment results, impregnation temperature was 950C, impregnation times of 10, 20, 30, 40 minutes, caustic charge 10% and peroxide charge was 3% in CMP ,one stage APMP and two stages APMP pulps. Considering pulp properties and treatment conditions, many treatments including 20 and 40 minutes treatments were selected for making of handsheet. The selected pulps were refined up to 350 ml (CSF) freeness prior to making of hasndsheet. Final results indicated that two stages APMP pulp (impregnation in time 40 minutes) had the highest burst strength, breaking length and brightness. Also, the results of yield and tear strength showed that, there was no meaningful difference at the 5% level between three methods CMP, one and two stages of APMP pulps.
Pulp and paper
Somayeh Ghasemi; Ahmad reza Saraeyan
Abstract
Comparative study of pulp yield of sap wood and heart wood of Populus deltoides under both Kraft and soda cooking process have been showed that the heart wood pulp has a lower yield than that of sap wood pulp. Yield of heart wood and sap wood soda pulps was 4 percentages higher than Kraft pulp. Contrary ...
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Comparative study of pulp yield of sap wood and heart wood of Populus deltoides under both Kraft and soda cooking process have been showed that the heart wood pulp has a lower yield than that of sap wood pulp. Yield of heart wood and sap wood soda pulps was 4 percentages higher than Kraft pulp. Contrary to yield, residual lignin content (Kappa number) is more in heart wood pulp than sap wood pulp in both processes. Kappa numbers of heart wood and sap wood Kraft pulps were about 34% lower than soda pulps. The results showed that in spite of lower yield of heart wood than sap wood, the residual lignin of heart wood pulp was more than sap wood pulp. The higher delignification efficiency of Kraft cooking is related to cooking liquor compositions, especially Na2S
Pulp and paper
Ali Khalili gasht rodkhani; Ali Ghasemian; Ahmad reza Saraeyan; Mohammad Dahmardeh ghale no; Sayed mehdi Manzorolajdad
Abstract
This study was aimed to investigate the effects of mixing OCC fibers with mixed hardwoods kraft pulp at Iran Wood and Paper Industry Co (Chuka). OCC has been repulped according to the common method in paper recycling industry and its freeness, along with that of virgin kraft pulp, were measured. The ...
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This study was aimed to investigate the effects of mixing OCC fibers with mixed hardwoods kraft pulp at Iran Wood and Paper Industry Co (Chuka). OCC has been repulped according to the common method in paper recycling industry and its freeness, along with that of virgin kraft pulp, were measured. The pulps were beaten to reach the required freeness values to make kraft liner paper, and have been then mixed at 10/90, 20/80, 30/70, 50/50 and 70/30 percentage rates of OCC and virgin kraft pulp, respectively. Handsheets were made from each composition and their mechanical and optical properties have been measured, according to required standard test methods, and compared with those of the control (100% virgin kraft pulp), using ANOVA method. Grouping of the mean values was done by Duncan test and normalization equation was computed to determine the best treatment. The results indicate decreasing the values of tensile, tear and burst, folding endurance and density in comparison with those of the control (100% virgin kraft pulp), but bulk, thickness and opacity have been increased. The score belonging to each treatment show to produce paper possessing proper mechanical and optical properties using OCC fibers, the allowed proportion of these fibers is 50 percent.
Pulp and paper
Hossein Resalti; Morteza Abdolah bik marandi; Ahmad reza Saraeyan
Abstract
The effect of using commercial xylanase enzyme in prebleaching of bagasse kraft pulp was investigated. Xylanase enzyme from Trichoderma viride was added to pulp at various doses of 10, 25 and 50 IU/g pulp for reaction time 2h and then the enzyme treated pulp was bleached in ADED sequences (Acid sulfuric ...
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The effect of using commercial xylanase enzyme in prebleaching of bagasse kraft pulp was investigated. Xylanase enzyme from Trichoderma viride was added to pulp at various doses of 10, 25 and 50 IU/g pulp for reaction time 2h and then the enzyme treated pulp was bleached in ADED sequences (Acid sulfuric +Dioxide chlorine 4, 6, 8, 10% + Alkaline extraction + Dioxide chlorine 2% as available chlorine). The results have shown that with increased dioxide chlorine in D1 bleaching sequence, final brightness of bleached pulp was increased significantly (P<0.01). Furthermore, in the case of treated samples by xylanase enzyme optical properties of bleached pulp such as brightness and opacity were increased significantly (P<0.01). For yellowness, revolution of refiner for distinct pulp freeness and kappa number have shown decreased significantly (P<0.01). Maximum of brightness and minimum of kappa number and yellowness were belong to 25 IU/g pulp treatment that about 10.8, 3.98% and 2.24 unit have difference significantly (P<0.01) as compared with control sample respectively. Maximum of opacity and Minimum was belong to 50IU/g pulp treatment that about 3 and 13.24% have difference significantly as compared with control sample respectively. Regardless of obtained results 25IU/g pulp treatment could be selected as optimal treatment.
