Mohammad hamed Shojaie; Amir Hooman Hemmasi; Mohammad Talaei poor; Esmail Ghasemi
Abstract
Utilization of ionizing rays like gamma-ray in polymers to correct their properties has attracted so much attention from researchers. Therefore, in this study, polypropylene as the composite matrix, maleic anhydride (MAPP) as the compatibilizer material, and poplar wood as the filler were placed under ...
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Utilization of ionizing rays like gamma-ray in polymers to correct their properties has attracted so much attention from researchers. Therefore, in this study, polypropylene as the composite matrix, maleic anhydride (MAPP) as the compatibilizer material, and poplar wood as the filler were placed under the radiation of gamma-ray with different doses from 0 to 75 kGy. The white rot fungi (Trametes versicolor) and, brown rot fungi (Gloeophyllum Trabeum) were used in fungal decay test. The main purpose of this study is to investigate the probable benefits of gamma-ray radiation for improvement of some of the composites physical and mechanical properties, and also, to investigate the biodegradation in fungal decay and thermal properties. The results indicates that radiation of gamma-ray improves the physical and mechanical properties of some structures, and the decay resistance of the WPCs against brown and white rot fungus according to their weight losses. The uniformity of the micrographs obtained from the scanning electron microscope (SEM) indicated that the interaction between the polymer and wood fibers.
Mojtaba Asadi; Behzad Bazyar; Amir Hooman Hemmasi; Mohammad Talaeipour; Ismail Ghasemi
Abstract
AbstractThe paper aims to study differential, dynamic-mechanical and biodegradability analysis of polylactic acid/wood fiber (PLA) composites using three levels of nano-graphene (0.75, 1.5 and 3%). In order to mix the materials together and to make standard specimens, an internal mixer and pressure press ...
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AbstractThe paper aims to study differential, dynamic-mechanical and biodegradability analysis of polylactic acid/wood fiber (PLA) composites using three levels of nano-graphene (0.75, 1.5 and 3%). In order to mix the materials together and to make standard specimens, an internal mixer and pressure press were used. In the analysis of differential polishing calorimeter, the addition of fibers as well as nano-graphene had a positive effect on the glass transition temperature and the degree of crystallinity, which indicates a change from softness and flexibility to hardness and hardness. Dynamic-mechanical analysis has shown that the addition of wood fibers to pure polylactic acid can case an increase in the storage modulus of the composite and with the addition of nano-graphene to increasing composition, while the highest amount of storage modulus was related to polylactic acid composites / 30% of fibers and 30% of fibers. Results of tan δ peak showed that with the presence of wood fibers and nano-graphene, the temperature was transferred to a higher temperature and the limited movement of molecules due to the improvement of the fiber reaction in the PLA polymer. The results of biodegradability test also showed that the addition of fibers to pure PLA caused a significant increase in the weight loss of the composite. Additionally, nano-graphene to PLA composites decreases with the less weight in composites.
Yashar Einollahi; Amir Hooman Hemmasi; Habibollah Khademi Eslam; Esmaeil Ghasemi; Mohammad Talaei poor
Abstract
Considering the increase of environmental pollutant resulted from agglomerating rubbish and wastes containing stable petroleum-based polymers, substitution of these polymers with bio-polymers and solving their problems and defects in the production process as well as the final products is an important ...
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Considering the increase of environmental pollutant resulted from agglomerating rubbish and wastes containing stable petroleum-based polymers, substitution of these polymers with bio-polymers and solving their problems and defects in the production process as well as the final products is an important topic. In this study, the possibility of the production of poly lactic acid (PLA)-rice husk composite with acceptable properties, and also the effect of using flame retardant mineral fillers of aluminum three hydrates (ATH) and magnesium di-hydroxide (MDH) on physical and thermal properties of the produced composite were investigated. Results indicated that the density of PLA-rice husk composite was higher than petroleum-based polymers composites (PP/HDPE-rice husk composites); and flame retardant mineral fillers addition led to an increase in the composite density. Also, flame retardant mineral fillers addition decreased the composite water absorption and thickness swelling, in a way that they were comparable with petroleum-based polymers composites. Results of thermal gravimetric analysis (TGA) showed that flame retardant mineral fillers addition also decreased the temperature of the composite weight loss curve peaks, and the weight loss rate toward temperature rising.
Composite wood products
Salume Esmaeilzadeh Saeih; Habibollah Khademi Eslam; Esmaeil Ghasemi; behzad baziyar
Abstract
Abstract Effects of temperature, cellulose Nano fibers and Nano clay particles on mechanical, physical and morphological properties of biodegradable composites made of recycled thermoplastic starch biopolymer and regular mixed industrial sawdust are investigated. To this aim Cellulose Nano Fibers and ...
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Abstract Effects of temperature, cellulose Nano fibers and Nano clay particles on mechanical, physical and morphological properties of biodegradable composites made of recycled thermoplastic starch biopolymer and regular mixed industrial sawdust are investigated. To this aim Cellulose Nano Fibers and Nano Clay particles were selected to be 0, 3 and 5 weight percent and were added to prepared biodegradable composites by using internal mixer and samples prepared by injection molding. Mechanical properties including tensile modulus and strength, flexural modulus and strength were extracted at temperatures ranging from 23 ºC to 80 ºC. Impact test and water absorption and thickness swelling were also performed according to related standards. Results show that elevating the temperature drastically reduce mechanical properties. Nano Clay addition results in better mechanical properties except for impact and water absorption and thickness swelling are improved. Using 5% Cellulose Nano Fibers improves mechanical and morphological properties better than 3% addition. Dynamic mechanical thermal analysis revealed Nano composites samples with 5% Nano Clay and Cellulose Nano Fibers has higher storage modulus and glass transition temperatures in compare to pure composite samples. This Nano particles can be successfully used to improve properties and performance except for fracture resistance.
Composite wood products
Mehdi Kalagar; behzad baziyar; Habibalah Khademislam; Esmaeil Ghasemi; Amir homan Hemmasi
Abstract
In this paper, poly lactic acid (PLA)/ wheat straw fibers manufactured by twin screw extruder and molding compression have been studied. Wheat straw fibers were treated with trietoxymethel silane for better compatibility between two phases. Physical properties, tensile properties of the composites were ...
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In this paper, poly lactic acid (PLA)/ wheat straw fibers manufactured by twin screw extruder and molding compression have been studied. Wheat straw fibers were treated with trietoxymethel silane for better compatibility between two phases. Physical properties, tensile properties of the composites were analysis. The effect of the wheat straw fibers on the thermal properties of PLA has also been investigated in DSC experiments. The effects of silane treatment on the wheat straw fibers have been analyzed by FTIR. Scanning electron microscopy from samples surface were used for better study of water absorption and thickness swelling. Composites wheat straw fiber were treated shows signification lower water absorption and thickness swelling than composites PLA/ untreated wheat straw fibers. The lower amount of water absorption and thickness swelling occurred in the pure PLA. The existence crack and break occurred in the surface of PLA/ untreated wheat straw fibers composites after immersion in the water indicating higher water absorption and thickness swelling were in these samples. Wheat straw fibers were treated with silane due to better wetting and better linkage in the interfacial surface with PLA matrix showed higher tensile properties then PLA/ untreated wheat straw fiber composites. Differential scanning calorimeter test showed that with addition wheat straw fibers were treated to pure PLA the increased glass transition temperatures. The nucleating effect of wheat straw fibers, special treatment with silane cause to increased in the crystallization temperature composites than pure PLA which a positive effect showed on the degree of crystallization.
