Yashar Einollahi; Amir Hooman Hemmasi; Habibollah Khademi Eslam; Esmaeil Ghasemi; Mohammad Talaei poor
Abstract
Considering the increase of environmental pollutant resulted from agglomerating rubbish and wastes containing stable petroleum-based polymers, substitution of these polymers with bio-polymers and solving their problems and defects in the production process as well as the final products is an important ...
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Considering the increase of environmental pollutant resulted from agglomerating rubbish and wastes containing stable petroleum-based polymers, substitution of these polymers with bio-polymers and solving their problems and defects in the production process as well as the final products is an important topic. In this study, the possibility of the production of poly lactic acid (PLA)-rice husk composite with acceptable properties, and also the effect of using flame retardant mineral fillers of aluminum three hydrates (ATH) and magnesium di-hydroxide (MDH) on physical and thermal properties of the produced composite were investigated. Results indicated that the density of PLA-rice husk composite was higher than petroleum-based polymers composites (PP/HDPE-rice husk composites); and flame retardant mineral fillers addition led to an increase in the composite density. Also, flame retardant mineral fillers addition decreased the composite water absorption and thickness swelling, in a way that they were comparable with petroleum-based polymers composites. Results of thermal gravimetric analysis (TGA) showed that flame retardant mineral fillers addition also decreased the temperature of the composite weight loss curve peaks, and the weight loss rate toward temperature rising.
Composite wood products
Moein Dehghan; Ali Ahmadi ladjimi; Habib Dahmardeh
Abstract
DOR:98.1000/1735-0913.1398.34.63.66.1.1575.1610 In the present research the biodegradability Properties of poly-lactic acid-canola stem flour composites in three levels of 25, 35, and 45% canola stem flour made by compression molding technique were studied . In order to study the biocompatibility behavior ...
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DOR:98.1000/1735-0913.1398.34.63.66.1.1575.1610 In the present research the biodegradability Properties of poly-lactic acid-canola stem flour composites in three levels of 25, 35, and 45% canola stem flour made by compression molding technique were studied . In order to study the biocompatibility behavior of the composite, three methods of biological degradation were used for Trametes versicolor and Gloeophyllum trabeum fungi, long-term water absorption and composites burial in the soil for 4 months. The results of statistical analyzes showed that the amount of composites weight loss increased against the degradation by fungi and burial in the soil by increasing the amount of rapeseed canola stem flour while pure poly-lactic acid had a very high durability against these factors. In addition, there was no effect on the weight loss of samples in the long run leach test so that the weight of composites and poly- lactic acid samples was constantly increasing and there was no effect on weight and thickness loss. The growth of myceliums fungi was clearly detectable and detectable in reviewing the images of electron microscopy from the fracture properties of composites, unlike poly-lactic acid so that fungi crossed their polymer into rapeseed shoot flour and reduced the weight of the composites. The results of the FTIR spectroscopy on poly-lactic acid prepared before and after exposure to the Gloeophyllum trabeum fungus confirmed the validity of the above results. According to the results of this study, poly-lactic acid, as a biodegradable polymer, has been shown to be very durable against degradation by natural biological agents.
Composite wood products
Hamid Ibaghi esfahani; mehdi kalagar; hosien sepahri rad
Abstract
In this study, the tensile and dynamic-mechanical properties of composites made by poly-lactic acid polymer (PLA) and high density polyethylene (HDPE) as matrix and sawdust to reinforcement 30 % weight were investigated. Maleic anhydride bonded with polyethylene (MAPE) was used to increase coupling agent ...
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In this study, the tensile and dynamic-mechanical properties of composites made by poly-lactic acid polymer (PLA) and high density polyethylene (HDPE) as matrix and sawdust to reinforcement 30 % weight were investigated. Maleic anhydride bonded with polyethylene (MAPE) was used to increase coupling agent by 3%. The use of sawdust increased the stiffness of composites while the use of this material reduced the tensile strength of composites. The highest tensile properties (elastic modulus and tensile strength) were related to poly lactic acid /polyethylene / sawdust / coupling agent composites. The addition of natural fibers to both matrices (PLA and MAPE) increased the composite storage modulus compared to pure polymers, while the modulus of storage in pure polyethylene and its composite was higher. Simultaneous use of two polymers with an equal ratio (33.5% by weight) and composite sawdust have shown the stiffness between the composites made with single polymers. The use of natural fibers reduced the mobility of the molecular chain and transported the temperature of the composite to higher temperatures, which eventually moved the corresponding corners to the right and lower. However, in some cases, the transmission of pixels has not followed the normal process. The addition of the coupling agent (MAPE) makes bonding more common between two phases in all composites and ultimately increases stiffness.
Composite wood products
Amir Nourbakhsh
Abstract
In this research was to use the effects micro cellulose, and Multi walled Carbon Nanotube on the mechanical properties of wood plastics composites. This article presents the application of Multi walled Carbon Nanotube in order to evaluate and compare their suitability as reinforcement for thermoplastics. ...
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In this research was to use the effects micro cellulose, and Multi walled Carbon Nanotube on the mechanical properties of wood plastics composites. This article presents the application of Multi walled Carbon Nanotube in order to evaluate and compare their suitability as reinforcement for thermoplastics. The effects of loading micro cellulose and Multi walled Carbon Nanotube content on the mechanical properties were also studied. The results showed that mechanical properties of the composites made with 50 micron cellulose and 1.5 and 2.5 % of Multi walled Carbon Nanotube were significantly superior to those of the lower length (20 micron) and control samples. Addition of Multi walled Carbon Nanotube could enhance the mechanical properties of the blends, due to the improvement of interface bond between the filler and matrix of wood plastics composites. The significant improvements in mechanical properties of the blends composites made with Multi walled Carbon Nanotube and micro cellulose were further supported by SEM and TEM micrographs.
Composite wood products
Ahmad Samariha; Habibollah Khademi Eslam
Abstract
Abstract The effect of adding steamed and non-steamed fiber on physical and mechanical properties of the composites made of recycled polypropylene was investigated. Recycled polypropylene was used as a basic matrix at a 57% level, and poplar fibers were used at 180 °C for 1 h at a constant level ...
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Abstract The effect of adding steamed and non-steamed fiber on physical and mechanical properties of the composites made of recycled polypropylene was investigated. Recycled polypropylene was used as a basic matrix at a 57% level, and poplar fibers were used at 180 °C for 1 h at a constant level of 40% in two forms: non-steamed and steamed. The ratio of steamed fibers to non-steamed fibers in composites was 100:0, 50:50, and 0:100, respectively. For all components, the coupling agent was maleic anhydride at a level of 3%. Mixing was done using an internal mixer at 180 °C and 60 rpm, and the samples were constructed by injection molding method. To investigate the effect of steam treatment on the fiber structure and crystallization, X-ray diffraction analysis and FTIR spectra were used. The results showed that the Steaming had no significant effect on resistance. But with steaming increased mechanical properties and physical properties of reduced. Keywords: Composites, Recycled polypropylene, Steamed fiber, XRD, FTIR
Composite wood products
Hamid Ibaghi esfahani; Mehdi Kalagar; Hossein Sepehridad
Abstract
To study the tensile properties and impact strength in Wood Plastic Composites (WPC) polypropylene as a matrix and teada pine sawdust as reinforcement / filler is used. Ethylene / propylene / Diane / monomer (EPDM) as modified impact resistance with 10, 20 and 30 percent improved impact resistance and ...
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To study the tensile properties and impact strength in Wood Plastic Composites (WPC) polypropylene as a matrix and teada pine sawdust as reinforcement / filler is used. Ethylene / propylene / Diane / monomer (EPDM) as modified impact resistance with 10, 20 and 30 percent improved impact resistance and maleic anhydride grafted polypropylene (MAPP) at a rate of 3 percent as a fasteners to improve response and polymers and fillers were added to the composite. To evaluate the fracture surface of a structure scanning electron microscope (SEM) was used. The apply of 10 % elastomer and 3 % coupling agent cause to improved of tensile properties and the use of higher levels of elastomer (20 and 30 %) has shown a decreasing trend in these properties. The results showed that PP matrix by adding sawdust to a significant reduction in impact strength of composite than pure PP is observed. An EPDM additive used in all contents of composites PP / sawdust has improved impact strength. Simultaneous use of EPDM and MAPP used a positive effect in tensile properties and impact strength. The apply of EPDM (30%) and 3% (MAPP) has demonstrated the highest level of impact strength. SEM images show that the use of EPDM and MAPP composites will improve the connection of interface.
Composite wood products
Ahmad Jahan- Latibari; Roozbeh Abidnejad; Mehran Roohnia
Abstract
At this research, the influence of Multi Walled Carbon Nano Tubes (Non-functionalized and functionalized) on mechanical properties of polypropylene – old corrugated container (OCC) fibers composites was investigated. OCC fibers polypropylene composites were prepared using 20% OCC fibers, 80% polypropylene ...
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At this research, the influence of Multi Walled Carbon Nano Tubes (Non-functionalized and functionalized) on mechanical properties of polypropylene – old corrugated container (OCC) fibers composites was investigated. OCC fibers polypropylene composites were prepared using 20% OCC fibers, 80% polypropylene and 3% MAPP. Three levels of multi walled carbon nano tubes (0% - 0.5% - 1%) were added. Acidic oxidation method was used to functionalize the MWCNTs. Mechanical properties were measured as defined in ASTM testing methods. The results indicated that at higher dosage of MWCNTs, the tensile strength properties of the composite were improved but the influence of the functionalizing was not statisitaclly significant. The bending strength and elasticity as wellas the izod impact were increased as the higher amount of nanotubes were added to the composite. Scanning Electron Microscopes showed the development of bonding between the composite components. Compostes without coupling agent showed lower bonding strength between polypropylene and fiber as indicated by fiber pull out. However, in the composites containing coupling agent, the fiber fracture was observed.
Composite wood products
Habib alah Khademieslam; Mehdei Kalagar
Abstract
In this investigation, tensile and physical properties of polypropylene (as matrix)/wheat straw fiber/paper mill sludge (as filler) composites was studied. The ratio of wheat straw fiber/ paper mill sludge was selected as 40/0, 30/10, 20/20, 10/30 and 0/40 (w/w) were used. Also, for better ...
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In this investigation, tensile and physical properties of polypropylene (as matrix)/wheat straw fiber/paper mill sludge (as filler) composites was studied. The ratio of wheat straw fiber/ paper mill sludge was selected as 40/0, 30/10, 20/20, 10/30 and 0/40 (w/w) were used. Also, for better compatibility between the two phases 3% MAPP as coupling agent was used. Mixing process was done in twin screw internal mixer extruder, and then composite samples were manufactured by injection molding. Result indicated that the tensile modulus of elasticity improved with increasing fillers and also it was observed that the toughness of composite increased when compared to the pure PP, while due to the usage of more paper sludge, these properties was improved. Tensile strength of composite decreased with adding 40% wheat straw fiber, but with addition of sludge tensile strength increased significantly. Adding wheat straw in PP matrix and its hydrophilic properties resulted in the highest rates of water absorption and thickness swelling. However, adding paper sludge and lower amount of lignocellulosic material, and the compatibilizer noticeably decreased the physical properties due to better bonding between two phases.
Composite wood products
Alireza Sokhtesaraei; Sahab Hejazi; Laya Jamalirad; Mohammad Ahmadi; Sead behnam Hosseini
Abstract
In this study, the physical and mechanical properties of polypropylene composites reinforced with alkaline sulfite-anthraquinone, soda-anthraquinone and monoethanolamine-anthraquinone and chemical mechanical produced from non-extrated and pre-extracted bagasse with hot water were studied. MAPP coupling ...
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In this study, the physical and mechanical properties of polypropylene composites reinforced with alkaline sulfite-anthraquinone, soda-anthraquinone and monoethanolamine-anthraquinone and chemical mechanical produced from non-extrated and pre-extracted bagasse with hot water were studied. MAPP coupling agent (3%) was added and the performance of pretreated and unpretreated bagasse composites were compared. The ratio of the polypropylene and reinforcement material (pulp) was considered at 50/ 50 (w/w). The results showed that the pulping process has a significant effect on all physical and mechanical properties of produced composites. In general, composites containing chemical pulps showed greater dimensional stability and mechanical strengths but lower water absorption than that of mechanical pulp. Composites containing treated fibers with alkaline sulfite-anthraquinone and soda pulp had the highest mechanical properties and dimensional stability. Composites made from fibers in which hemicelluloses were extracted and then were treated with chemical pulping processes had the highest mechanical strength and dimensional stability among all of samples. The highest mechanical strengths and dimensional stability were observed in composites which were reinforced with treated fibers compared with control samples containing untreated bagasse fibers. In general, the results showed the superior physical and mechanical characteristics for pulp - plastic composites compared with wood flour plastic composites.
Composite wood products
Amir Norbakhsh; Abolfazl Kargarfard
Abstract
In this research the impact of micro cellulose particles length, and coupling agent (MAPP) on the mechanical and thermal properties of Nano/ wood plastics composites were investigated. The results showed that mechanical properties of the composites made with 50 micron micro cellulose particles and 5 ...
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In this research the impact of micro cellulose particles length, and coupling agent (MAPP) on the mechanical and thermal properties of Nano/ wood plastics composites were investigated. The results showed that mechanical properties of the composites made with 50 micron micro cellulose particles and 5 % of MAPP were significantly different to those of the lower length (20 micron) and 2.5% of MAPP. Addition of MAPP enhanced the mechanical and thermal properties of the blends, due to the improvement of interface bond between the filler and matrix of Nano/ wood plastics composites. The significant improvements in mechanical properties of the blended composites made with MAPP and NC were further supported by SEM and TEM micrographs. Nano/ clay particles distribution and thermo gravimetric analysis (TGA) indicated that the addition of 5% MAPP and the longer micro cellulose particles remarkably increased the thermal stability of the blends compared to other treatments of Nano/ wood plastics composites.
Composite wood products
Seyedeh Zahra Hosseini; Ali akbar Enayati
Abstract
This study has been undertaken to investigate effects of synthetic waste fibers of polyester in improving mechanical properties of wood plastic composites. Two types of polyester fibers (carpet fibers and polish fibers), high density polyethylene along with 40 wt% wood flour of populus, 2 wt% of maleic ...
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This study has been undertaken to investigate effects of synthetic waste fibers of polyester in improving mechanical properties of wood plastic composites. Two types of polyester fibers (carpet fibers and polish fibers), high density polyethylene along with 40 wt% wood flour of populus, 2 wt% of maleic anhydride grafted polyethylene (MAPE) and ethylene- glycidyl methacrylate copolymer (E-GMA) as coupling agent were used. After two-stage mixing, resulted granules were hot pressed (at160℃, under 10 Mpa pressures) to produce test boards measuring 20×20×0.7 cm in dimensions. Results from measurement of mechanical properties of the samples have shown that with increasing the amount of polyester fibers (carpet fibers and polish fibers), tensile modulus of elasticity of wood plastic composites decreases and increases his flexural modulus of elasticity. Also by increasing amount carpet fibers, the tensile, flexural strengths of wood plastic composites-carpet fibers increases and the maximum of flexural strength is in a sample that contained 20 wt% carpet fibers. But about the plush fiber, 10 wt% of it is efficient for increasing the flexural and tensile strengths of wood plastic composites-plush fibers. Then on the composites contained the optimal polyester (polish fiber 10% and carpet fibers 20%) for increasing the mechanical strength, TGA and DSC testes for experience the thermal behavior of the composites were analyzed. Thermal analyses results have shown that with addition of polyester in the wood composite plastic, are reduced the percentage of crystallization, temperature of crystallization and the temperature of stability and degradation thermal of the composite.Morphologic study by Scanning Electron Microscopy indicates that with the increasing percentage of polyester fibers, is more denser and smoother the integration between the fracture surface of the composite material.
Physics and Mechanical Wood
Ali Kazemi tabrizi; Amir Nourbakhsh; Javad Sepidehdam
Abstract
In this study, the effect of fish waste powder, base material polyethylene , and also the quantity of coupling agent (MAPE) on physical and mechanical properties of wood-plastic composite were studied. For this purpose, wood powder at 40% was mixed with 60% of HDPE. Fish waste in three levels (5, 10 ...
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In this study, the effect of fish waste powder, base material polyethylene , and also the quantity of coupling agent (MAPE) on physical and mechanical properties of wood-plastic composite were studied. For this purpose, wood powder at 40% was mixed with 60% of HDPE. Fish waste in three levels (5, 10 and 15%) mixed into wood powder and coupling agent on three levels (0, 2 and 4) of HDPE in a blender at 180 °C and a speed rotating of 50 rpm, and samples were made with using of injection molding for standard tests. The mechanical properties: tensile and bending strength, bending and tensile modulus were investigated according of ASTM standards. This result suggests that increasing the amount of fish powder waste to 10%, increased bending strength while other strengths diminished. The amounts of all strengths were increased by increasing in percentage of coupling agent to 4%.The results shows that fish waste was suitable as a new material for wood plastics composites.
Composite wood products
mahdi abasyan; asghar omidvar; mahdi mashkour; zinat farhadi
Abstract
This study seeks to investigate the possibility of producing polypropylene composite- cotton stalk flour with various percentages of cotton stalk flour. Determining the best treatment in terms of physical and mechanical properties and exploring the effect of using cotton stalks in the production of the ...
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This study seeks to investigate the possibility of producing polypropylene composite- cotton stalk flour with various percentages of cotton stalk flour. Determining the best treatment in terms of physical and mechanical properties and exploring the effect of using cotton stalks in the production of the composites were among the major objectives of this study. Six treatments consisting of Polypropylene, 40, 55 and 70 percent level of cotton stalks and two fillers (cotton stalks with and without barks) were developed. Maleic anhydride modified polypropylene (3% wt) was applied to each treatment. The mixing and granulation of the plastic and cotton silk flour was carried out using twin screw extruder model 4815. After preparing and shearing of samples, the mechanical properties of composites including tensile strength, rupture modulus and elasticity modulus were calculated in accordance with D-6109 and ASTM D-7031 standards. In addition, water absorption and thickness swelling tests were performed according to D-570-98 standard. The results showed that an increase in the flour of cotton stalk reduced the tensile strength and rupture modulus on the one hand, and increased the bending elasticity modulus on the other hand. In terms of the performance of the filler, there was a significant difference between values of rupture modulus and elasticity modulus at 95% level whereas this difference was not significant for tensile strength. Moreover, this difference was significant for values of water absorption and thickness swelling. The maximum tensile strength belonged to T4 with 40 percent of cotton stalk bark fibers.
taherh Gholipour; Hossein Rangavar; Abolfazl Kargarfard
Abstract
In this study, physical and mechanical properties of wood-plastic composite made of Canola stem flour and polypropylene were investigated. Variable factors were four levels of canola stem flour (25, 50, 75 and 100 percent based on the dry weight of the wood flour) with and without pit. The control samples ...
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In this study, physical and mechanical properties of wood-plastic composite made of Canola stem flour and polypropylene were investigated. Variable factors were four levels of canola stem flour (25, 50, 75 and 100 percent based on the dry weight of the wood flour) with and without pit. The control samples were made of only wood flour and polypropylene. Physical and mechanical properties including screw withdrawal strength perpendicular on the surface, flexural strength, modulus of elasticity, water absorption and thickness swelling after 2 and 24 hours immersion in water were measured in accordance with EN standards. Results showed that increasing the mixing ratio of canola stem flour to wood flour up to 25% resulted in increase in screw withdrawal strength perpendicular to the surface. Increasing this factor up to 50% led to increase in MOR and MOE. Thereafter, any increase in the mixture, decreased mechanical strengths. Increasing the mixing ratio of canola stem flour to wood flour resulted in increase in water absorption and thickness swelling after 2 and 24 hrs. The specimens without pit showed lowest amount of water absorption and thickness swelling levels and highest mechanical properties (screw withdrawal resistance, flexural strength and modulus of elasticity).
Amir Lashgari; Ayob Eshghi; Abolfazl Karegarfard; Ajang Tajedini
Abstract
In this research, the effect of nanoclay-particles on physical and mechanical properties of composites made using almond shell powder-polypropylene was studied. For this purpose, almond shell powder and nanoclay were used in three levels of 30%, 35% and 40% for almond and 0%, 2.5% and 5% for ...
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In this research, the effect of nanoclay-particles on physical and mechanical properties of composites made using almond shell powder-polypropylene was studied. For this purpose, almond shell powder and nanoclay were used in three levels of 30%, 35% and 40% for almond and 0%, 2.5% and 5% for nanoclay. In addition, 2% of Maleic Anhydride Polypropylene was added to all compositions. Then, wood-plastic nano-composite was formed using counter-rotating twin screw extruder and injection molding machine. Mechanical test including tensile, flexural, impact resistance, hardness and physical properties including water Absorption and Thickness Swelling after 2h and 24h immersion in water were measured. In addition X-Ray Diffraction (XRD) experiment was carried out to reveal how clay nano-particles are distributed across the manufactured composites and Scanning Electron Microscope (SEM) was also performed to investigate fracture surfaces. The results indicated that the presence of nano-clay did not influence the flexural and tensile elasticity modulus, and the presence of nano-clay reduced tensile and flexural resistance. The hardness and density of composites were higher than pure plastic and the impact resistance of all composites was lower than pure plastic. The presence of nano-clay did not significantly effect the physical properties of the composites (p< 0.05).The diffraction model of X-ray showed that nano-composite forms intercalation interlayer structure and the results of morphological investigation revealed that the samples containing 2.5 percent nano-clay and 35 percent of almond shell have the highest array of intercalation and the best transmittance.
Elham Marzban Moridani; Mohammad Talaeipour; Amir houman Hemmasi; esmaeil Ghasemi; Mehdei Kalagar
Abstract
In this research, the mechanical properties of composite produced from recycled polymers (polyethylene and polypropylene) and paper mill sludge from two different sources (waste water sludge (s) and sludge on the DAF) were examined. Three levels of paper sludge (15, 30 and 45 wt %) were used to produce ...
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In this research, the mechanical properties of composite produced from recycled polymers (polyethylene and polypropylene) and paper mill sludge from two different sources (waste water sludge (s) and sludge on the DAF) were examined. Three levels of paper sludge (15, 30 and 45 wt %) were used to produce composites. Haake machine was used to blend materials and to produce standard samples, injection molding system was utilized. The mechanical properties including bending (strength and modulus) and impact strength were measured. The results showed that composites containing PP polymer and waste water sludge have higher mechanical properties than PE polymer and sludge on the DAF. The addition of both types of sludge as filler, results in enhancement of tensile properties compare to pure polymer. In the case, the higher content of sludge on the DAF was used, tensile strength of the composite decreased. Adding both types of sludge as filler, impact strength was lower than pure polymer. It was shown that composites containing sludge on the DAF have lower impact property than waste water sludge.
Roholah Mohebi; Aghang Tajedini; Ahmad Jahan-Latibari; Amir Nourbakhsh
Abstract
The influence of different contents (0, 5 and 10% W/W)of silica and poplar wood powder ( 30 ,40 and 50% W/W of total weight of composite) on strength properties of Polypropylene/Wood powder/Silica composite was evaluated. Various components of composite was melt mixed using two screw counter retating ...
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The influence of different contents (0, 5 and 10% W/W)of silica and poplar wood powder ( 30 ,40 and 50% W/W of total weight of composite) on strength properties of Polypropylene/Wood powder/Silica composite was evaluated. Various components of composite was melt mixed using two screw counter retating extruder, followed by cooling and granulizing. Composite granules were injected into test samples. The results of strength properties measurements revealed that almost all strength values were improved. At higher content of silica, The MOR increased from 47.9 to 53.3 MPa, MOE from 2625 to 4517 MPa and MOE in tensile increased from initial value of 4525MPa (without silica) to 6884MPa (10% silica in composite). Marginal increase in tensile strength and Izod Impact strength was observed, but the hardness of the composite was improved from 66 to73.77 shoreD. At higher silica content, the density of the composite was higher, as expected.
Sina Modirrahmati; Ahmad Jahan-Latibari; Mansor Minaei
Abstract
The influence of nanoclay addition on the strength properties of HDPE/ Wheat straw powder Composite was investigated. Composites compounds were produced using 73%HDPE, 25% wheat straw powder and 2% MAPE and three amounts of nanoclay (1, 2, and 3% of composite compound). First, HDPE and nanoclay was melt- ...
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The influence of nanoclay addition on the strength properties of HDPE/ Wheat straw powder Composite was investigated. Composites compounds were produced using 73%HDPE, 25% wheat straw powder and 2% MAPE and three amounts of nanoclay (1, 2, and 3% of composite compound). First, HDPE and nanoclay was melt- mixed and after cooling, the extrudate was milled to fine granules. This granules were then melt compounded with pre-weighted amount of wheat straw powder and MAPE followed by injection moulding to produce test specimens. The flexural, tensile and impact strength were measured. The results showed that the addition of nanoclay to the composite improved flexural strength and modulus, tensile strength and modulus. However the notched Izod strength was reduced.
Sina Modirahmati; Ahmad Jahan Latibari; Amir Nourbakhsh; Mehran Roohnia; Mansor Minaei
Abstract
The impact of nanoclay addition on the properties of polypropylene/ OCC fibers/ nanoclay Composite was investigated. Composites were prepared using 67% polypropylene, 30% OCC fiber, 3% MAPP and three dosages (2.5, 5, 7.5% based on total weight of PP/OCC/MAPP) of nanoclay. Premix- ...
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The impact of nanoclay addition on the properties of polypropylene/ OCC fibers/ nanoclay Composite was investigated. Composites were prepared using 67% polypropylene, 30% OCC fiber, 3% MAPP and three dosages (2.5, 5, 7.5% based on total weight of PP/OCC/MAPP) of nanoclay. Premix- melting of nanoclay and polypropylene was used to add nanoclay to the composite mixture. Pre-mixed nanoclay/ polypropylene was melt-mixed with OCC fibers and MAPP and then test samples were made using this compound. The results revealed that addition of nanoclay to polypropylene/OCC fiber composite reduced flexural strength , tensile strength and notched Izod impact strength, but the flexural modulus and tensile modulus of final composite were improved significantly. The influence of nanoclay addition on flexural strength and tensile modulus of composite was statistically significant at 99% level whereas its effect on tensile strength was statistically significant at 95%. However, the effect of nanoclay on both flexural modulus of elasticity and impact strength was not statistically significant. The addition of nanoclay to the composite reduces the bonding between polypropylene and OCC fibers. In the case of notched Izod strength, nanoclay particles generated stress concentration point within the composite structure initiating easier failure. Water absorption after 2 and 24 hours immersion was reduced.
Sasan َAbangah; Ahmad Jahan Latibari; Seyad Javad Sepideh dam; Mehran Roohnia; Mohammad ali Hossein
Abstract
The influence of reinforcing fibers (old corrugated container fibers called OCC) and addition of foaming agents (Azodicarbinamide and sodium bicarbonate) on density, strength properties and dimensional stability of OCC fiber/polypropylene composite were investigated. Conten of reinforcing fibers constant ...
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The influence of reinforcing fibers (old corrugated container fibers called OCC) and addition of foaming agents (Azodicarbinamide and sodium bicarbonate) on density, strength properties and dimensional stability of OCC fiber/polypropylene composite were investigated. Conten of reinforcing fibers constant at 20% and the content of either foaming agent varied as 3, 5 and 7%. Strength properties including MOR, MOE, maximum tensile strength and modulus as well as izod impact strength were measured. Water absorption after 2 and 24 hours soaking in distilled water at 23±2 ºC were measured. Foaming agent decomposition caused some chemical residues in composite and the diffusion and penetration of polymer into the fibers structure led to increase in the density from 839.2 kg/m3 for pure polypropylene to 919.2 - 947.9kg/m3 for the composite, MOR and MOE also increased by the addition of foaming agent and the reinforcing fiber. The effect of 5 or 7% sodium bicarbonate was statistically significant and it improved the properties of the composite. Similar results were obtained for tensile strength and the modulus. Reinforcing fibers and foaming agent caused higher impact strength of the composite. Water absorption of the composites was higher than pure polypropylene.
Mohammad Tasoji; Amir Nourbakhsh; Abolfazl Kargarfard; Hossein Hosseinkhani
Abstract
Physical and mechanical properties wood-plastic composites produced from wheat and rice straw particles, nano-clay, polypropylene and MAPP were investigated. The amount of polypropylene and lignocellulosic materials were selected as 60 wt% and 40 wt% respectively. The Nano-clay was added in three levels ...
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Physical and mechanical properties wood-plastic composites produced from wheat and rice straw particles, nano-clay, polypropylene and MAPP were investigated. The amount of polypropylene and lignocellulosic materials were selected as 60 wt% and 40 wt% respectively. The Nano-clay was added in three levels 0, 2 and 4 wt% and the amount of coupling agent was fixed and set to 2 wt% for all treatments except for the control. The control samples were made from polypropylene and lignocellulosic materials with neither nanoclay nor coupling agent was used. The results showed that the tensile and flexural strengths were decreased by the addition of nanoparticles. For tensile and flexural modulus, adding 2 wt% of nanoclay led to an increase in both moduli. However there was a decrease in both moduli when 4 wt% nanoclay was added. The impact strength decreased adding nanoclay. There was a decrease in 24 hour water absorption when 2 wt% of nanoclay was added but an increase was observed in 4 wt% of nanoclay level. According to the mechanical and physical properties of all the treatments, the samples made of rice straw showed better results compare to wheat straw samples due to their high amount of silica and its compatibility with nanoclay. SEM test was performed.
Hassan Ziaei Tabari; Amir Nourbakhsh; Habibollah Khademi Eslam; behzad baziyar
Abstract
The aim of this study was to investigate the potential of using reed flour and different contents of montmorillonite (nanoclay) nanoparticles on the physical and tensile properties of polypropylener/reed flour/nano clay composite. The amount of coupling agent and reed flour was constant at 5% and 40%, ...
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The aim of this study was to investigate the potential of using reed flour and different contents of montmorillonite (nanoclay) nanoparticles on the physical and tensile properties of polypropylener/reed flour/nano clay composite. The amount of coupling agent and reed flour was constant at 5% and 40%, respectively and nanoclay content, adjusted at four levels of 0, 1, 3 and 5% were considered. The materials were mixed in an internal mixer and the samples were prepared by injection molding method. The specimens were tested in accordance with EN ISO 527 standard test method for tensile properties (tensile strength and module) and elongation at break. Physical properties such as water absorption and thickness swelling were measured. The results of tensile moduli and strengths, elongation at break and physical properties (water absorption) showed improvement by the addition of nanoclay up to 3%.
Babak Mirzaei; Mehdi Tajvidi
Abstract
Stress relaxation behavior of milled newsprint/HDPE composite containing coupling agent was studied. Composites containing 25 and 50% filler in weight were produced, and were compared to neat polymer. Melt blending followed by injection molding was the manufacturing process. Results showed that incorporating ...
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Stress relaxation behavior of milled newsprint/HDPE composite containing coupling agent was studied. Composites containing 25 and 50% filler in weight were produced, and were compared to neat polymer. Melt blending followed by injection molding was the manufacturing process. Results showed that incorporating filler to polymer increases the flexural strength and modulus. It was observed that higher stress is needed to maintain higher strain levels. Furthermore, comparing the stress ratio patterns revealed that the difference among relaxation of different samples develops over time. Power law computed parameters showed that higher strain level results in higher stress relaxation amplitude (A) and lower time exponent (t). It was also found that, almost complete linear relationship could be established between strain level and parameter A, and the effect of strain level on parameter A is more pronounced at higher filler contents.
Amir Nourbakhsh
Abstract
To improve the mechanical properties of wood plastics composites, four lignocellulosic materials (bagasse, rice straw, wheat straw and poplar wood powder) was used as the reinforcing material. The amount of nano-clay at different levels (0, 3 and 6%) were examined on the performance of wood plastic composites. ...
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To improve the mechanical properties of wood plastics composites, four lignocellulosic materials (bagasse, rice straw, wheat straw and poplar wood powder) was used as the reinforcing material. The amount of nano-clay at different levels (0, 3 and 6%) were examined on the performance of wood plastic composites. Tensile, flexural and impact properties were measured in accordance with ASTM standard test methods. Scanning electron microscope imaging (SEM) and transmission electron microscope imaging (TEM) were performed to interpret the results. The applocation of bagasse and poplar wood powder compared with wheat and rice straws increased the strength of wood plastics composites. Using 3% nanoclay particles increased the strength properties to the maximum values. Imaging the morphology of nanoclay by X-ray diffraction and electron microscopy showed the distribution of nanoclay particles in polymer structure. With increasing the amount of nanoclay to 3%, the distance between layers increased.
Pulp and paper
Babak Mirzaei; Kazem Dos hosseini; Esmaeil Ghasemi; Yahya Hamzeh
Abstract
In this study two types of paper sludge, prepared by Mazandaran wood and paper company and Latif papermaking company along with wood flour utilized as plastic filler in polypropylene and high density polyethylene based composites. Weight percentage ratio of coupling agent, polymer and filler were kept ...
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In this study two types of paper sludge, prepared by Mazandaran wood and paper company and Latif papermaking company along with wood flour utilized as plastic filler in polypropylene and high density polyethylene based composites. Weight percentage ratio of coupling agent, polymer and filler were kept constant 2%, 38%, and 60% in all formulations, respectively and composites were prepared by varied ratios of paper sludge and wood flour include 0: 60, 40: 20, 20: 40, and 60:0. Density, water absorption and thickness swelling of injection molded composites then measured. The results indicated the gradual substitution of wood flour by paper sludge increases the density of composites, and improves their water absorption and thickness swelling. The ratio of paper sludge to wood flour had statistically significant difference on all these properties, but the paper sludge type showed statistical difference just on the density of composites. Further to that, polypropylene based composites demonstrated lower density, water absorption and thickness swelling compared to high density polyethylene based ones.
