Meisam Aliabadi; Eiman Akbaepoor; Ahmad reza Saraeian
Abstract
In this study, the effect of organic complex "sulvy-x" on the optical properties of hornbeam CMP pulp bleached with hydrogen peroxide was investigated. Sulvy-x was used in two sequences silicate-free and silicate containing in hydrogen peroxide bleaching. The brightness of papers increased to 60.52 and ...
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In this study, the effect of organic complex "sulvy-x" on the optical properties of hornbeam CMP pulp bleached with hydrogen peroxide was investigated. Sulvy-x was used in two sequences silicate-free and silicate containing in hydrogen peroxide bleaching. The brightness of papers increased to 60.52 and the yellowness decreased to 22.6 with increasing silicate charges up to 1% . However, at higher levels than 1% , the brightness decreased and the yellowness increased. Without dosage of sodium silicate but using 0.5% of sulvy-x, maximum brightness of 59.3% and minimum yellowness of 23.4 % ISO was achieved. In silicate-containing bleaching, combination of 0.5% sulvy-x and 0.7% sodium silicate resulted the highest brightness (60.28 % ISO) and the lowest yellowness (23 % ISO). Optimum charge of sodium hydroxide and hydrogen peroxide were determined as 2.5% and 5%.The best time for bleaching of hornbeam CMP pulp was 90 minutes in either sequences. With regard to results obtained, utilization of the organic complex of sulvy-x could be a suitable substitution for sodium silicate which produces the pulp with higher brightness and lower yellowness in conventional peroxide bleaching.
Chemistry of wood
Iman Akbarpour; Hossein Resalati
Abstract
This research was accomplished in order to investigate the replacement of organic complex of Glanapone Stab with sodium silicate on optical properties of hardwood CMP pulp bleached by hydrogen peroxide. The highest brightness of 65.5% and the lowest yellowness of 21.6% was attained at silicate-free ...
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This research was accomplished in order to investigate the replacement of organic complex of Glanapone Stab with sodium silicate on optical properties of hardwood CMP pulp bleached by hydrogen peroxide. The highest brightness of 65.5% and the lowest yellowness of 21.6% was attained at silicate-free followed by replacement of 0.7% and 1.5% Glanapone. But the highest opacity 98.2% was gained using 0.5% glanapone. The brightness of paper increased to 68.1% and the yellowness decreased to 20.8. by adding of glanapone consumption from 0.4% to 0.5% in blended with 0.7% sodium silicate. At higher levels than 0.5% glanapone, the brightness of paper decreased and the yellowness increased. Using Higher levels of 1 and 1.5% glanapone in blended with 0.7% sodium silicate resulted the highest opacity 97.9% and 98%, respectively. Increasing of peroxide usage up to 5% at two different states of silicate-free and silicate-containing with glanapone resulted in the paper with higher brightness and lower yellowness and opacity. CMP pulps bleached at 120 minutes resulted the highest brightness of 71.1% and the lowest yellowness of 18.3% at silicate-containing state with glanapone. Maximum opacity of 98.3% and 98% were shown at bleaching time 30 minutes at two states silicate-free and silicate-containing state with glanapone, respectively. In this research with regard to optical properties in relation to paper produced from CMP pulp bleaching at two states silicate-free and silicate-containing with glanapone,it can be said that possibility of producing the paper with similar optical properties or even better using 0.7% or 1.5% at silicate-free is in compared to conventional hydrogen peroxide bleaching. Also, we could produce the paper with higher brightness along with lower yellowness and similar opacity followed by bleaching time of 120 minutes and hydrogen peroxide 5% in combination of 0.7% sodium silicate with 0.5% glanapone in compared to higher consumed values of sodium silicate.
