Pulp and paper
Jafar Ebrahimpour Kasmani; Ahmad Samariha; Alireza Khakifirooz
Abstract
Background and objectives: Waste paper recycling has grown as an industry in Iran and the world and offers many benefits to the environment and humans. Municipal waste is also reused after recycling processes. Cardboard recycling industry has great environmental and economic importance and with the lack ...
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Background and objectives: Waste paper recycling has grown as an industry in Iran and the world and offers many benefits to the environment and humans. Municipal waste is also reused after recycling processes. Cardboard recycling industry has great environmental and economic importance and with the lack of wood resources and high demand for paper products, it plays an important role in the development of paper-related industries. However, recycling can be associated with a reduction in the optical properties of the paper. The use of nanoparticles in the paper industry is also expanding day by day. Nanosilica is one of the most important nanoparticles used as a retention aid in the paper industry. In order to reduce the consumption of long fibers and obtain the desired optical properties, the use of nanosilica alone or in combination with other materials such as cationic starch and cationic polyacrylamide is investigated. The purpose of this research is to compare the effect of separate and combined use of nanosilica additives, cationic polyacrylamide, cationic starch and long fibers on the optical properties of white liner paper pulp.Methodology: In this study, white paper pulp with a brightness of at least 78% and a gloss of at least 45% was used to prepare handmade papers. Long fiber chemical paper pulp from coniferous kraft imported from Russia with a brightness of 89% was used in the laboratory. Nanosilica powder (NanoSiO2) produced by Degussa, Germany, cationic polyacrylamide with Farinret K325 brand, produced by Degussa, Germany, and cationic starch from LyckebyAmylex, Slovakia, were used. Independent treatments include the addition of 10% refined long fibers paper pulp, 6% nanosilica, 1.5% cationic starch and 0.15% cationicpolyacrylamide and combined treatments include 6% nanosilica and 1.5% cationic starch and 6% nanosilica and 0.15% cationic polyacrylamide. Then 127 g.m-2 handmade papers were prepared and their optical and microscopic properties were evaluated.Results: The results showed that by adding 10% of long fibers, the brightness decreased and by using 6% of nanosilica, the maximum brightness was obtained. Meanwhile, the whiteness of papers with 6% nanosilica was minimum and maximum with 0.15% cationic polyacrylamide. Opacity showed its highest value with the combination of 6% nanosilica and 0.15% cationic polyacrylamide. Also, by increasing the amount of polyacrylamide and cationic starch, individually or in combination with nanosilica, the opacity increased. The light absorption coefficient was the lowest in papers with 6% nanosilica and the light scattering coefficient was the highest in papers containing 6% nanosilica and 0.15% cationic polyacrylamide. A colorimeter was used to measure the color components and the results showed that the additives had an effect on the brightness and whiteness of the papers. Also, changes in the color spectrum and the amount of color change were also observed. Additives increased the darkness and changes in different colors.Conclusion: The use of nanosilica separately and in combination with starch and cationic polyacrylamide increases the brightness of papers. Also, the use of cationic polyacrylamide separately and in combination with nanosilica leads to an increase in the whiteness and opacity of papers. The brightness factor of the papers, which is representative of the L* component, decreased with the exception of the addition of 10% long fibers and 6% nanosilica. The amount of overall color change with ∆E* was the lowest in samples containing 1.5% cationic starch and the highest in samples containing 0.15% cationic polyacrylamide. The use of some treatments can lead to a decrease in the optical properties and a decrease in the printability quality of the white liner. To solve this problem, mechanical paper pulp that has been decolorized or coated on the surface of the paper can be used. The presence of nano-silica particles in the structure of the paper improves the bond surface and reduces the prosity, which results in the reduction of surface roughness and less light refraction, and increases the light reflection and brightness of the paper.
Pulp and paper
Jafar Ebrahimpour Kasmani; Ahmad Samariha; Alireza Khakifirooz
Abstract
This research was conducted with the aim of investigating the effect of two-layer coating of nano-polyurethane and nano-clay on the mechanical and physical properties of packaging cardboard with brown layer. For this purpose, brown layer cardboard with grammage of 127 was prepared and tested. To coat ...
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This research was conducted with the aim of investigating the effect of two-layer coating of nano-polyurethane and nano-clay on the mechanical and physical properties of packaging cardboard with brown layer. For this purpose, brown layer cardboard with grammage of 127 was prepared and tested. To coat the surface of the cardboard, it was first coated with nano-polyurethane and sprayed by a coating nozzle. Then the surface of the brown layer cardboard was covered with nano-clay to improve the performance of the coating material of the first treatment. Nano-clay coating was performed by a laboratory coating machine called barcoter. The coated cardboards were restrained and dried in the room for one day to stabilize the coating material on their surface. Then the samples were placed inside the freezer for 2 and 4 months and their properties were measured. The results showed that coating reduced water absorption. In the coated and frozen samples, an increase in thickness, smoothness of the surface and a decrease in water absorption and resistance properties compared to non-frozen control samples have been observed. Double coated samples showed very few pores. The thickness, smoothness of the surface and resistance to tearing in the machine cross direction of the double coated brown cardboard showed an increase of 13.7%, 75% and 3.8%, respectively, compared to the control sample. water absorption, resistance to bursting, resistance to tearing in the machine direction, resistance to tensile in the machine direction, resistance to tensile in the cross machine direction, resistance to ring crush test in the machine direction and resistance to ring crush test in the cross machine direction of the double-coated brown layer cardboard compared to the control sample, showed 107.20, 1.5, 34.3, 25.4, 24.3, and 4.7 percent decrease respectively.
Jafar Ebrahimpour Kasmani; Ahmad Samariha; Saeed Mahdavi
Abstract
This study was carried out to compare the individual and combined effects of nanolignocelluloses (NLC), cationic polyacrylamide (CPAM), cationic starch (CS) and imported chemical long fiber (LF) in the manufacture of recycle liner and fluting paper for packaging. Individual treatments of OCC were included ...
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This study was carried out to compare the individual and combined effects of nanolignocelluloses (NLC), cationic polyacrylamide (CPAM), cationic starch (CS) and imported chemical long fiber (LF) in the manufacture of recycle liner and fluting paper for packaging. Individual treatments of OCC were included 15% LF, 6% NLC, 1.5% CS and 0.15% CPAM as addetives. Combined treatments were included 6% NLC and 1.5% CS, 6% NLC and 0.15% CPAM. Handsheets were made with grammage of 127 g/m2 by application the mentioned treatments. Finally, the physical, mechanical properties and microscopic structure of handsheet were investigated. The results showed that addition of LF and NLC caused the density of handsheets decreased compared to the control. The individual and combined treatments led to increasing the tensile and burst strength of handsheet. Also, the tear strength of handsheet increased compared to the control except for the combined treatment of NLC and CS. FE-SEM images showed pores relative reduction in handsheet that prepared from combination treatments. It showed negative effect on water drainage. The addition of 6% NLC and 0.15% CPAM to OCC pulp resulted in the highest crush strengths as RCT and CMT compared to the control. SEM micrographs showed relatively reduced pores in handsheets prepared from combined treatments, which could have negative effect on the dewatering of OCC pulp.
Jafar Ebrahimpour Kasmani; Ahmad Samariha; Alireza Khakifirooz
Abstract
This study aimed to investigate the use of cellulose nanofibers and starch-nano-cellulose and polyacrylamide-nano-cellulose hybrid systems for the replacement of imported long chemical fibers in the production of these papers. In this study, imported long fiber chemical pulp was added to cotton pulp ...
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This study aimed to investigate the use of cellulose nanofibers and starch-nano-cellulose and polyacrylamide-nano-cellulose hybrid systems for the replacement of imported long chemical fibers in the production of these papers. In this study, imported long fiber chemical pulp was added to cotton pulp at 4 levels. Cellulose nanofibers were added to cotton pulp at a 5% level with 1% starch and 0.1% with polyacrylamide. Three levels of cationic starch and three levels of cationic polyacrylamide were also used. From each of the treatments, 60 gm-2 handsheet were made finally the physical, mechanical and optical properties of the paper made from different pulps were compared. The results showed that with increasing nanocellulose individually, compared to imported long fibers, surface smoothness, tensile strength, bursting, tearing of paper increased and air resistance, folding resistance and opacity decreased. Increasing nanocellulose in combination with cationic polyacrylamide increased the paper air resistance and surface area, tensile, burst, tear, and folding strength of the paper compared to imported long fibers, air resistance and opacity. With the increase of nanocellulose in combination with cationic starch, as compared to imported long fibers, surface smoothness, tensile strength, bursting, folding increased but opacity decreased. FE-SEM results also showed that with increasing percentage of cellulose nanofibers, the pores decreased significantly. As a result of the addition of 5% cellulose nanofibers the surface of the paper became smoother and the pores were filled relatively, confirming the results of surface smoothness and air resistance.
Jafar Ebrahimpour Kasmani; Saeed Mahdavi
Abstract
This research was carried out with aim of the effect of nano-clay (NC) content on mechanical, thermogravimetry (TG) and morphological properties of wood plastic composite (WPC) made of medium density fiberboard (MDF) and particleboard (PB) wastes and recycled polypropylene and polyethylene (HDPE). For ...
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This research was carried out with aim of the effect of nano-clay (NC) content on mechanical, thermogravimetry (TG) and morphological properties of wood plastic composite (WPC) made of medium density fiberboard (MDF) and particleboard (PB) wastes and recycled polypropylene and polyethylene (HDPE). For this purpose, wastes of MDF and PB at 50 wt.% , recycled PP and HDPE at 50 wt.%, maleic anhydride grafted with polymers at a constant level of 3 wt.% and nanoclay at three different levels 3, 6, and 9 wt.% were blended by two-wire extruder. Afterward, standard test pieces were made using an injection molding machine and their mechanical properties and TGA were investigated. Scanning electron microscope (SEM) was applied to investigate the quality of nanoclay particles dispersion in the matrice as well as how the lignocellulosic and polymers are bonded at the surface of bonding. The results showed that tensile and flexural strength and their modulus of HDPE and PB composite significantly were increased by adding NC up to 3 wt.%, but the strengths were dropped in WPC's by increasing of NC content at 6 and 9 wt.%. The notched impact strength of WPC has been totally decreased by NC addition that indicates more fracture surface on WPC's. SEM micrographs revealed that porosity and cavities in WPC's especially were decreased at 9 wt.% NC, whereas it is clear an inappropriate dispersion and aggregation of NC in WPC. The thermal stability of WPC's was slightly improved at 3 wt.% NC and the residual after combustion increased compared to the control.
Pulp and paper
Yaghob Mamizadeh; Jafar Ebrahimpour Kasmani
Abstract
In textile industry the bellow comb fibers are located in a range in terms of their length and diameter that it can be used as proper raw material especially in paper dough industries; therefore, present study tries to consider improvement of durable paper's properties made of cellulosic nanofibers. ...
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In textile industry the bellow comb fibers are located in a range in terms of their length and diameter that it can be used as proper raw material especially in paper dough industries; therefore, present study tries to consider improvement of durable paper's properties made of cellulosic nanofibers. In this consideration, the below comb fiber of pulp and paper imported chemical pulp are prepared from a company that is producing durable papers and they were transferred to laboratory. Cellulosic nanofiber has been prepared from Nano Novin Polymer Co., and it has been consumed at 4 levels of 0, 0.3, 0.6 and 0.6%. After mixing pulp with cellulosic nanofiber at determined percentages, the handmade 90 g.m-1 papers were made and eventually physical and mechanical properties of these papers were evaluated. The results showed that enhancement of cellulosic nanofibers till 0.9% has led to enhancement of tensile strength, bursting resistance, tearing strength and folding strength comparing to control sample up to 22.7, 38.9, 7.7 and 384% respectively. Increasing the amount of cellulosic nanofibers up to 0.9% the surface smoothness has increased up to 7.9% comparing to control; moreover, water absorption and pores were reduced as 69 and 7.9% respectively. The SEM results showed that enhancement of cellulosic nanofiber percentage has led to reduction of pores.
Pulp and paper
Jafar Ebrahimpoor kasmani; Amir mohssen Nazeri; Ali Ashryeh
Abstract
In this investigation , effects of different humidity and heat on quality of Corrugated board , was studied , and optimum treatment indicated Variables in this Paper was : Corrugator speed (50,100,150m/min) ,wraping angle of the paper around preheaters ...
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In this investigation , effects of different humidity and heat on quality of Corrugated board , was studied , and optimum treatment indicated Variables in this Paper was : Corrugator speed (50,100,150m/min) ,wraping angle of the paper around preheaters (90,180,300 degree) and moisture of paper (6.5%,7%,8.5%). Papers that treated for this purpose was included : 125gsm kraft liner ,127 gsm medium paper and 140gsm test liner paper. A flut type of 3ply Corugated board was selected for this study.Moisture of paper was measured in 3 places : Paper on roll stand before single facer , paper after singlefacer preheater and paper before incoming doublefacer in hot plate unit. Also temprature was measured in corrugator rolls ,hot Plates in double facer and final Board after Exiting of the Machine.
Results show that , warp of final board decreased in speed 50 and 100m/min ,moisture 7% and 1800 wraping angle of the paper around preheater.
That means lower speeds and higher wraping angles cause to more heat on corrugated board and decreasing in warp content resulted.It should be noted that lower humidity more than 7% and increase wraping angle more than 180 degree cause to over drying and intensive moisture decrease in final board that cause to reverse warp in final board.
Jafar Ebrahimpour Kasmani; Amir mohssen Nazeri; Ahmad Samariha
Abstract
Abstract: Fiber external fibrillation is one of the refining effects in conventional refining which is accompanied with a variety with other effects such as internal fibrillation. The objective of the present study was to investigate the effect of fiber external fibrillation on paper properties. Softwood ...
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Abstract: Fiber external fibrillation is one of the refining effects in conventional refining which is accompanied with a variety with other effects such as internal fibrillation. The objective of the present study was to investigate the effect of fiber external fibrillation on paper properties. Softwood kraft pulp and poplar wood CMP pulp produced at Mazandaran Wood and Paper Industries was used. An ultra-fine friction grinder was used to generate the external fibrillation. The results showed that, increasing the fiber external fibrillation increased the density of paper sheets and lower refiner gaps decreased the light scattering coefficient. Increased fiber external fibrillation improved the tensile strength of the paper sheets by about 20% and internal bonding was increased from 33% to 46% compared with unrefined fibers.
Pulp and paper
Ahmad Samariha; Jafar Ebrahimpoor kasmani; Saeed Mahdavi
Abstract
Rapeseed straw was collected from a cultivation farm in the vicinity of Babul, Mazandaran. Average fiber length, width, lumen diameter and cell wall thickness were measured as 860, 27.95, 18.86, and 4.42 µm respectively. Chemical components of rapeseed straw including cellulose, lignin, ash and ...
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Rapeseed straw was collected from a cultivation farm in the vicinity of Babul, Mazandaran. Average fiber length, width, lumen diameter and cell wall thickness were measured as 860, 27.95, 18.86, and 4.42 µm respectively. Chemical components of rapeseed straw including cellulose, lignin, ash and extractives were measured as 44%, 19.21%, 6%, and 13% respectively. Optimum pulping conditions to reach the pulp yield of 66%, were selected applying chemical charge of 20% (based on Na2O), cooking temperature of 170 ºC, and cooking time of 30 min. The pulps were refined to 350 and 400 ml CSF using PFI mill. Statistical analysis showed that mechanical properties of hand sheets with the basis weight of 127 g m-2 made from rapeseed straw NSSC pulp at the freeness of 350 and 400 ml CSF exhibited better properties compared to mixed hardwood NSSC pulp to produce fluting paper.
Jafar Ebrahimpour Kasmani; Mohammad Talaeipoor; Amir homan Hamasi; Ahmad Samariha
Abstract
The strength properties of paper produced from pulp obtained after 1, 2 and 4 weeks treatment of hornbeam chips with the Phanerochaete chrysosporium BKM - 1767 fungus was evaluated and compared with control samples. After preparing fungal specimens, hornbeam chips were exposed to this fungus for one ...
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The strength properties of paper produced from pulp obtained after 1, 2 and 4 weeks treatment of hornbeam chips with the Phanerochaete chrysosporium BKM - 1767 fungus was evaluated and compared with control samples. After preparing fungal specimens, hornbeam chips were exposed to this fungus for one of the three periods of 1, 2 and 4 weeks at 39oC temperature and 65% relative humidity. Then CMP pulp was prepared using treated chips, chemical treatment temperature of 165oC, for either 80 or 90 minutes and sodium sulfite charge of 14, 18 and 22% (based on oven dry weight of the wood). The liquor to chips was constant at 7 to 1. The results showed that the CMP pulping yield from treated chips was lower than control sample and the reduction after treatments for 1, 2 and 4 weeks was almost 1.64, 2.84, 6.20 percent respectively. Also the strength indices of paper such as tensile strength, burst strength, tear strength and folding endurance paper prepared from treated chips were lower than control chips
Pulp and paper
Ahmad Samariha; Jafar Ebrahim poor tasmani; Alireza Khakifiroz
Abstract
This research was performed to investigate the properties of CMP pulp from rape straw. Samples of Colza straw was prepared from a farm located in the vicinity of Babul. Chemo mechanical Pulping process was employed using the 20 % cooking liquor of Mazandaran pulp and paper mill (Sodium Sulphite) based ...
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This research was performed to investigate the properties of CMP pulp from rape straw. Samples of Colza straw was prepared from a farm located in the vicinity of Babul. Chemo mechanical Pulping process was employed using the 20 % cooking liquor of Mazandaran pulp and paper mill (Sodium Sulphite) based on the dry weight of colza straw. Cooking time and temperature were adjusted at 30, 40 and 50 minute and 170 degree centigrade, respectively. Pulps were refined up to 300± 25 CSF by using PFI Mill refiner and 60 g/m2 hand sheets were made from each sample of pulps. The strength indices of hand sheets were measured using TAPPI standards. The results showed that strength indices like Tensile strength, Tear strength, Burst strength, Breaking length and Stiffness increased as the pulp yield decreased.
