Document Type : Research Paper

Authors

1 Department of Wood and Paper Engineering, Savadkooh Branch, Islamic Azad University, Savadkooh, Iran

2 Associate prof., Wood and Forest Products Research Division, Research Institute of Forests and Rangelands, Agricultural Research Education and Extension Organization (AREEO), Tehran, Iran.

Abstract

This research was carried out with aim of the effect of nano-clay (NC) content on mechanical, thermogravimetry (TG) and morphological properties of wood plastic composite (WPC) made of medium density fiberboard (MDF) and particleboard (PB) wastes and recycled polypropylene and polyethylene (HDPE). For this purpose, wastes of MDF and PB at 50 wt.% , recycled PP and HDPE at 50 wt.%, maleic anhydride grafted with polymers at a constant level of 3 wt.% and nanoclay at three different levels 3, 6, and 9 wt.% were blended by two-wire extruder. Afterward, standard test pieces were made using an injection molding machine and their mechanical properties and TGA were investigated. Scanning electron microscope (SEM) was applied to investigate the quality of nanoclay particles dispersion in the matrice as well as how the lignocellulosic and polymers are bonded at the surface of bonding. The results showed that tensile and flexural strength and their modulus of HDPE and PB composite significantly were increased by adding NC up to 3 wt.%, but the strengths were dropped in WPC's by increasing of NC content at 6 and 9 wt.%. The notched impact strength of WPC has been totally decreased by NC addition that indicates more fracture surface on WPC's. SEM micrographs revealed that porosity and cavities in WPC's especially were decreased at 9 wt.% NC, whereas it is clear an inappropriate dispersion and aggregation of NC in WPC. The thermal stability of WPC's was slightly improved at 3 wt.% NC and the residual after combustion increased compared to the control.

Keywords

-Chaharmahali, M. Kazemi-Najafi, S. and Tajvidi, M., 2007. Effect of Blending Method on the Mechanical Properties of Wood-Plastic Composites. Iranian Journal of Polymer Science and Technology, 20(4): 361-367.
-Ghani, M.H.A., and Ahmad, S., 2011. The comparison of water absorption analysis between counterrotating and corotating twin-screw extruders with different antioxidants content in wood plastic composites. Advances in Materials Science and Engineering, vol. 2011, Article ID 406284, 4 pages.
-Golebiewski, J., and Galeski, A., 2007. Thermal stability of nanoclay polypropylene composites by simultaneous DSC and TGA, Compos. Sci. Techn. 67(15-16), 3442-3447. DOI:10.1016/j.compscitech.
-Gozdecki, C., Wilczyński, A., Kociszewski, M. and Zajchowski, S., 2015. Properties of wood–plastic composites made of milled particleboard and polypropylene, European journal of wood and wood products, 73(1): 87-95.
-Gu, R., Kokta, B.V., Michalkova, D., Dimzoski, B., Fortelny, I., Slouf, M., Krulis, Z. 2010. Characteristics of wood–plastic composites reinforced with organo-nanoclays, Journal of Reinforced Plastics and Composites, 29(24): 3566-3586.
-Han, G. Lei, Y. Wu, Q. Kojima, Y. and Suzuki, S., 2008. Bamboo-fiber filled high density polyethylene composites; effect of coupling treatmement nanoclay. Journal of Polymer Environment, 16(2): 123-130.
-Incarnato, L., Scarfato, P., Acierno, D., Milana, M. R., and Feliciani, R., 2003. Influence of recycling and contamination on structure and transport properties of polypropylene, Journal of Applied Polymer Science 89(7), 1768-1778. DOI: 10.1002/app.12168
-Kazemi Najafi, S. Marzenaki, M. and Chaharmahali. M., 2010. Effect of Virgin and Degraded Polypropylene Blends on Properties of Wood Flour-Polypropylene Composites. Journal of Forest and Wood Products (JFWP), 63(1): 47-59.
-Kord, B., Ekrami, M., Roohani, M., 2014. Effect of nanoclay particles content on the mechanical properties of wood flour-polypropylene composites using dynamic mechanic thermal analysis, Iranian Journal of Wood and Paper Industries, 5(2): 15-26.
-Kord, B., Ravanfar, P., Ayrimis, N., 2017. Influence of organically modified nanoclay on thermal and combustion properties of bagasse reinforced HDPE nanocomposites, Journal of Polymers and the Environment, 25(4): 1198-1207.
-Le Baillif, M., and Oksman, K., 2009. The effect of processing on fiber dispersion, fiber length, and thermal degradation of bleached sulfite cellulose fiber polypropylene composites. Journal of Thermoplastic Composite Materials, 22(2): 115-133.
-Madhoushi, M., Chavooshi, A., Ashori, A., Ansell, M.P., and Shakeri, A., 2016. Properties of wood plastic composite panels made from waste sanding dusts and nanoclay, Journal of Composite Materials. 0(0): 1–9.
-Nazerian, M., Dalirzadeh, A., Farokhpayam, S.R., 2014. The effect of old corrugated container (OCC) powder and as urea formaldehyde adhesive filler on properties of medium density fiberboard made from bagasse and waste MDF, Iranian journal of wood and paper science research, 29(3): 452-463.
-Winandy, J.E. Stark, N.M. and Clemons, C.M., 2004. Considerations in recycling of wood-plastic composites. In: Proceedings of Five Global Wood and Natural Fibre Composites Symposium. April 27-28, Kassel, Germany, pp. A6-1- A6-9.
-Yeh, S. and Gupta, R.K., 2010. Nanoclay- Reinforced, Polypropylene-Based Wood–Plastic Composites. Polymer Engineering and Science. 50(10): 2013-2020.