Abas Fakhryan; Hossein Hosseinkhani; Fardad Golbabaei; Mohammad mehdi Brazandeh
Abstract
In this Investigation chemical, physical, morphology, pulp and paper making characteristics of Populus costanzo were studied. The average dry and critical specific gravity was found to be 0.39and 0.36 and the fiber morphology including fiber length , diameter ,lumen and thickness ...
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In this Investigation chemical, physical, morphology, pulp and paper making characteristics of Populus costanzo were studied. The average dry and critical specific gravity was found to be 0.39and 0.36 and the fiber morphology including fiber length , diameter ,lumen and thickness of cell wall 1.14 mm,28.84 µm, 28 µm ,and 2.92 µm was determined respectively. The average chemical composition including cellulose 50.74%, lignin 19.18%, Ext. 1.22% and Ash 1.65% were measured. In order to cook and pulping, Kraft process was used. The maximum yield and kappa number of Populus costanzo at 1 hour cooking time, 150°c cooking temperature and 12% effective alkali condition obtained at 61.91% and 54.83 respectively and the minimum yield and kappa number at 3 hour cooking time, 170°c cooking temperature and 16% effective alkali condition obtained at 45.63% and 13.42 respectively.
Pulp and paper
Abdolrahim Mohebalian; Ahmad Jahan latibari; Ajang Tajdini; Shadman Pourmosa
Abstract
In this research, the influence of two temperatures (60 and 90°C) and three dosages of sodium hydroxide (5, 7.5 and 10%, based on the dry weight) on hornbeam wood chips alkaline pre-hydrolysis and soda pulping was studied. Soda pulping of both pre-hydrolyzed and control chips were conducted applying ...
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In this research, the influence of two temperatures (60 and 90°C) and three dosages of sodium hydroxide (5, 7.5 and 10%, based on the dry weight) on hornbeam wood chips alkaline pre-hydrolysis and soda pulping was studied. Soda pulping of both pre-hydrolyzed and control chips were conducted applying constant pulping variables. The effect of pre-hydrolysis on hemicelluloses removal and sodium hydroxide consumption and pulp characteristic including total yield, reject, pulp freeness, kappa number, and pulp strengths were measured and statically analyzed. In case the effect of variable on measured property was statistically significant, then Duncan multiple range grouping of the measured property was arranged. The result revealed that pre-hydrolysis removed almost 4.2% (based on dry wood) of hemicelluloses of the wood and pre-hydrolysis demonstrated easier soda pulping delignification, due to weakening the lignin-carbohydrate bonds and both total yield, reject and kappa number were reduced. Tensile strength index of the pulp produced using pre-hydrolyzed chips war lower and as the dosage of sodium hydroxide increases, the tensile strength index was reduced initiated from the removal of hemicelluloses which is also lower than control pulp, Tear strength index of the soda pulp from pre-hydrolyzed chips was mildly reduced which is anticipated to be the consequence of fiber weakening and fiber breaking during cooked chips defibration. The effect of pre-hydrolysis variables on tear strength was not statistically significant. Based on the result of this study, hornbeam wood can be a potential source of bio-refining based on lignocellulosic material.
Pulp and paper
Farhad Zeinaly; Ali Kazemi Tabrizi; yashar Einollahi; Faraz Asadi Malek Jahan
Abstract
The first act to ameliorate bleaching process is the major elimination of lignin. Actually, the use of oxygen delignification stage before bleaching process is the essential stage in improving bleaching process and reducing process emission. In this study, the effect of conducting oxygen-delignifying ...
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The first act to ameliorate bleaching process is the major elimination of lignin. Actually, the use of oxygen delignification stage before bleaching process is the essential stage in improving bleaching process and reducing process emission. In this study, the effect of conducting oxygen-delignifying process under different process condition, on chemical, physical, mechanical and optical properties of kenaf bast kraft pulp was investigated. The kenaf bast kraft pulp with the kappa number of 22, 1154 ml/g viscosity, and 38% ISO brightness was prepared. Oxygen-delignifying treatments were carried out with three different temperatures of 90, 100 and 110°C, and two oxygen pressures of 5 and 7 bars, with and without magnesium sulfate addition. Results indicated that oxygen delignification treatment led to intense decrease in pulp kappa number, while the pulp viscosity did not change significantly. Results of measuring delignified pulp viscosity showed that the magnesium sulfate addition caused to prevention of pulp viscosity downfall. The increase in reaction temperature had a significant effect on the process improvement, but raising the oxygen pressure did not have a meaningful effect on the process. Also, the pulp brightness was increased about 7%.
Pulp and paper
Farhad Zeinaly; Ahmad Reza Saraeian; Mohammadhadi Aryaei monfared; Ali Kazemi Tabrizi
Abstract
In conducting environmentally friendly processes for pulp production, first step is to reduce the effluent pollution load in each stage, and because the bleaching process is the most polluting stage in the production of pulp, improving it is one of the most important matters. The first act to ameliorate ...
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In conducting environmentally friendly processes for pulp production, first step is to reduce the effluent pollution load in each stage, and because the bleaching process is the most polluting stage in the production of pulp, improving it is one of the most important matters. The first act to ameliorate bleaching process of chemical pulps is the reduction of colored materials, mostly lignin, which enter to the bleaching section. Thus, the use of oxygen delignification stage after pulping and before bleaching process is the key stage in improving process and cleaner production. In this study, the effect of conducting oxygen-delignifying treatment by two kinds of machines, and under different process condition, on chemical, physical, mechanical and optical properties of bagasse soda pulp was investigated. The bagasse soda pulp with the kappa number of 20, 955 ml/g viscosity, and 37% ISO brightness was prepared from Pars Hafttapeh Company. Oxygen-delignifying treatments were carried out with three different temperatures of 90, 100 and 110°C, and two oxygen pressures of 5 and 7 bars, with and without magnesium sulfate addition, by two kinds of machines. Results indicated that oxygen delignification treatment led to intense decrease in pulp kappa number, while the pulp viscosity did not change. Results of measuring delignified pulp viscosity showed that the magnesium sulfate addition caused to prevention of pulp viscosity downfall. The increase in reaction temperature had a significant effect on the process improvement, but raising the oxygen pressure did not have a meaningful effect on the process. The pulp brightness was increased about 4-6%. And also, due to the need of shorter time in order to reach the reaction temperature in the Iranian made machine, pulp delignifying by this machine was a little lower than Quantum machine.
Pulp and paper
Hosein Valayi; Ahmad Jahan Latibari
Abstract
Strength properties and the yield of soda and soda-ethanol pulps produced using hornbeam, beech and poplar woods were investigated. Soda pulps were produced applying 20% active alkali and the soda-ethanol pulps were made using 10% active alkali and 50% ethanol. The pulping temperature was constant at ...
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Strength properties and the yield of soda and soda-ethanol pulps produced using hornbeam, beech and poplar woods were investigated. Soda pulps were produced applying 20% active alkali and the soda-ethanol pulps were made using 10% active alkali and 50% ethanol. The pulping temperature was constant at 175 C and the soda pulping time was selected at 120 minutes and the soda-ethanol pulping times were 120 and 180 minutes. The highest accepted pulping yield at 58.54% was reached using soda pulping on poplar wood and the lowest yield (49.29%) was related to soda-ethanol pulp produced from beech wood applying 180 minutes pulping time. The accepted yield of soda-ethanol pulping was low, but the kappa numbers of these pulps were almost 20 units lower than soda pulps. The strength properties of soda-ethanol pulps were superior to soda pulps and the difference was statistically significant at 99% confidence level. The results of this study indicated that the delignification of soda-ethanol pulping process is faster than soda pulping from the selected hardwoods especially poplar wood.
Pulp and paper
Farzaneh Shiralizadeh; Sahab Hejazi; Mohammad Ahmadi
Abstract
In this research, rice straw was used as raw material. Potassium hydroxide was combined with monoethanolamine (MEA) as liquor. In another processes NaOH/Na2So3, KOH/K2So3 and KOH 14% was used as references pulp. The results showed that using pure MEA(15%) produced the highest yield and the highest kappa ...
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In this research, rice straw was used as raw material. Potassium hydroxide was combined with monoethanolamine (MEA) as liquor. In another processes NaOH/Na2So3, KOH/K2So3 and KOH 14% was used as references pulp. The results showed that using pure MEA(15%) produced the highest yield and the highest kappa number. By using potassium hydroxide as a additive agent in MEA pulping, the amount of reject, yield and kappa number was decreased and the lowest yield and the lowest kappa number relevant to MEA(15%) combined with KOH (40%). In addition, in KOH pulping observed that, with increasing concentration of MEA, as additive agent, the amount of total yield increased but the kappa number and reject content was decreased. Results showed that the highest tensile index and tear index were relevant to MEA (15%) combined with KOH (20%) and the highest burs index relevant to NaOH/Na2SO3 treatment. According to the optical properties, it was found that the highest brightness was achieved in K2SO3/KOH. The highest opacity relevant to the KOH14% .The result shows that MEA process in combined with Potassium hydroxide can be done success fully on rice straw and properties of pulp production, specially in aspect of mechanical strength, in term of combination is superior than soda and Potassium hydroxide process
Pulp and paper
Seyed_Pedram Hashemi; Asghar Tabei; Seyyed Peyman Hashemi
Abstract
In this study the effect of different values of peroxide in three levels 3%, 4%, 5% and sodium hydroxide in two levels 2%, 3%, on bleaching of tobacco stalks ( Nicotiana tabacum L. 'PVH 19') soda pulp was investigated. Tobacco stalks were soda pulped using 22% alkali in 170°C for 100 minutes. Produced ...
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In this study the effect of different values of peroxide in three levels 3%, 4%, 5% and sodium hydroxide in two levels 2%, 3%, on bleaching of tobacco stalks ( Nicotiana tabacum L. 'PVH 19') soda pulp was investigated. Tobacco stalks were soda pulped using 22% alkali in 170°C for 100 minutes. Produced pulp had 37.1 % yield and kappa number 62. Bleaching process included two stages: chelating and alkali peroxide bleaching. Results indicated that brightness increased and kappa number decreased by increasing sodium hydroxide and peroxide Hydrogen level.The data related to 3% caustic soda and 5% peroxide treatment without chelating stage, indicated that initial chelating stage significantly affected on the brightness, kappa number and yield of the bleached pulp, and this treatment had the lowest brightness and the highest kappa number and yield among all treatments. Finally, 3% caustic soda-5% peroxide treatment with initial chelating stage had the highest brightness (44.50%) and the lowest yield (83.20%), was selected as the best treatment.
Pulp and paper
Lila Karami motaghi; Hossein Hosseinkhani; Fardad Golbabaei
Abstract
In this study pulp and hand sheets paper characteristics of Salix nigra wood kraft and soda pulp and paper were investigated. Average density of dry and bulk density wood were determined 0.35 and 150 kg/m3 and average fiber dimension consist of fiber length, fiber diameter were measured, 1100 and 30 ...
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In this study pulp and hand sheets paper characteristics of Salix nigra wood kraft and soda pulp and paper were investigated. Average density of dry and bulk density wood were determined 0.35 and 150 kg/m3 and average fiber dimension consist of fiber length, fiber diameter were measured, 1100 and 30 µm, respectively. The chemical composition were determined as cellulose 42%, lignin 28% and extractive 4%. In order to coocking and pulping, Kraft (Sulfate) and soda process were used. For comparison of fiber dimensions, physical properties and chemical composition of the mean and standard deviation, yields of pulp in the form of a factorial randomized complete block design test, the strength properties of handsheets table ANOVA and for group means of the Duncan were used. All paper strengths of two hour cooking show better results than one hour cooking times, and all paper strengths of 22% alkaline show better result than 18%, also all paper strengths of 100% mixture show better result than 25% mixture (100% mixture only contain kraft pulpof salix nigra). The results of hand sheet strength indicated that Kraft pulp of salix nigra wood will provide a suitable to mix with short fiber hard wood pulp.
Abas Fakhryan
Abstract
In this study, pulp and handsheets characteristics of radiata pine wood kraft pulp was evaluated. The ratiata pine wood was collected from Chamestan Noor Research Station. Average dry and basic specific gravity of wood were determined as 0.342 and 0.308 g/cm3 and average fiber (tracheid) dimension ...
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In this study, pulp and handsheets characteristics of radiata pine wood kraft pulp was evaluated. The ratiata pine wood was collected from Chamestan Noor Research Station. Average dry and basic specific gravity of wood were determined as 0.342 and 0.308 g/cm3 and average fiber (tracheid) dimension including fiber length, fiber diameter, lumen diameter and cell wall thickness were measured as 2460, 40.35, 33.17 and 3.59 µm, respectively. The chemical composition was determined as holocellulose 72.07%, alfa cellulose 43.41%, lignin 29.95%, ash 0.50 % and extractive as 1.75%. Kraft (Sulfate) process was applied for cooking and pulping the wood. A factorial randomized complete block design test was conducted to compare the fiber dimensions, physical properties, chemical composition and the yield of the pulp. To examine strength properties of handsheets, ANOVA statistical analysis was used and for grouping the means Duncan test were applied. The minimum and maximum yield and kappa number of these pulps were measured at 40.33%, 50.43% and 33.89, 60.22, respectively. The results of handsheet strength measurement indicated that radiata pine wood kraft pulp provides suitable substitute for imported long fiber pulp to be mixed with short fiber hardwood pulp.
Pulp and paper
Maryam Rostaei; Rabi Behroz; Saeid Mahdavi
Abstract
This research was performed to improve the properties of the pulp made of Aspen Deltoides, using antraquinone(AQ) catalizer. Neutral sulfite semichemical (NSSC) method in three efficiency levels of 55, 60, and 65% was applied. Cooking situations was selected as: Specific Temperature (175˚ C) , Time ...
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This research was performed to improve the properties of the pulp made of Aspen Deltoides, using antraquinone(AQ) catalizer. Neutral sulfite semichemical (NSSC) method in three efficiency levels of 55, 60, and 65% was applied. Cooking situations was selected as: Specific Temperature (175˚ C) , Time (Variable) , Specific Percentage of Chemicals 14% and Anthraquinone 0.1% . In all stages of cooking, weight ratio of sodium sulfide to sodium bicarbonate was set as 4.5/1. The ratio of cooking liquid to chips was 5/1. The results indicated that AQ causes an increase in efficiency and a significant decrease in Kappa. Researches also indicated that by the use of AQ, strength indexes of the paper such as strength of burst, tearing, tensile, Ring Crush Test and Corrugating Medium Test increases. Optical experiments on hand sheets following addition of AQ, indicated increase in brightness and decrease in opacity.
Pulp and paper
Mohammad taghi Asdolah zadeh; Hossein Resalti; Ali Ghasemian
Abstract
In the present study the effects of hot water pre-extraction and alkaline catalyzed were evaluated on soda-aq pulping of kenaf whole stem. In this respect, following kenaf chips pre-extraction at various temperature and time conditions, pulp preparation were carried out on oven-dried weight loss levels ...
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In the present study the effects of hot water pre-extraction and alkaline catalyzed were evaluated on soda-aq pulping of kenaf whole stem. In this respect, following kenaf chips pre-extraction at various temperature and time conditions, pulp preparation were carried out on oven-dried weight loss levels of 8.5, 11.5 and 14.5 % of the samples, and the reference untreated kenaf chips performed by using Soda-AQ at 3 levels of H-factors ( 983, 1408 and 1832 hours). Results indicated that kenaf chips weight losses increased while the pre-extracted pH decreased as pre-extraction temperature and time increased. The required H-factor for achieving certain level of weight loss was reduced by adding small amounts of alkali (0.15 % on oven dried kenaf) on hot water extraction stage. The Pulp yields were reduced by increasing cooking H-factor and extracted weight loss. Averages comparison indicated that significant differences were observed, at 95% confidence, between the pulp yield and kappa number from reference pulp and pre-extracted pulp samples at levels of about 8.5, 11.5 and 14.5 %, and pulp yields and their kappa number were higher in reference pulps than pre-extracted samples. In addition, pulp yield average was higher in pre-extracted samples by alkaline catalyzed than pre-extracted samples by hot water, however, no significant differences were observed between their kappa number average. Meanwhile, to obtain a certain (similar) kappa number, pre-extracted kenaf chips in comparison with reference untreated kenaf chips require lower H-factor.
Pulp and paper
Davod Efhami; Mohammad reza Dehghani
Abstract
In this work effect of initial alkali charge were investigated on the yield and kappa number of soda beech pulp and alkali consumption pattern. The results indicated that, the regression models are useful for studying the relations between yield, kappa number and alkali consumption. Soda cooking was ...
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In this work effect of initial alkali charge were investigated on the yield and kappa number of soda beech pulp and alkali consumption pattern. The results indicated that, the regression models are useful for studying the relations between yield, kappa number and alkali consumption. Soda cooking was performed in 30, 40, 50, 60 and 70 gr.lit-1 initial alkali concentration and five different cooking times. The chips dimensions were in the range of 3-5 cm length, 1-2 cm width and 0.05 cm thickness. The results showed that increasing of alkali charge decreased the time of cooking in the same yield or kappa number. Deligninifaction decreased significantly in kappa number lower than 30. In the same kappa number, increased alkali charge gave a lower yield. The alkali consumption was regularly decreased with increasing of initial alkali charge from 30 to 70 gr/lit, but alkali charge consumption pattern varied in less and more than 30 kappa numbers.
Pulp and paper
Somayeh Ghasemi; Ahmad reza Saraeyan
Abstract
Comparative study of pulp yield of sap wood and heart wood of Populus deltoides under both Kraft and soda cooking process have been showed that the heart wood pulp has a lower yield than that of sap wood pulp. Yield of heart wood and sap wood soda pulps was 4 percentages higher than Kraft pulp. Contrary ...
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Comparative study of pulp yield of sap wood and heart wood of Populus deltoides under both Kraft and soda cooking process have been showed that the heart wood pulp has a lower yield than that of sap wood pulp. Yield of heart wood and sap wood soda pulps was 4 percentages higher than Kraft pulp. Contrary to yield, residual lignin content (Kappa number) is more in heart wood pulp than sap wood pulp in both processes. Kappa numbers of heart wood and sap wood Kraft pulps were about 34% lower than soda pulps. The results showed that in spite of lower yield of heart wood than sap wood, the residual lignin of heart wood pulp was more than sap wood pulp. The higher delignification efficiency of Kraft cooking is related to cooking liquor compositions, especially Na2S
Pulp and paper
Abbas Fakhryan roghani; Fardad Golbabaei; Hossein Hosseinkhani; Kamyar Salehi; Saeed Mahdavi; Sabrineh Mohsseni tavakoli
Abstract
In this reseach, chemical, anatomical and pulping properties of 12 years old Populus.triplo of adapting plan and quantity properties of this tree from karaj research station were investigated.The average of fiber length ,diameter ,lumen and thickness of cell wall 1.27 mm ,31.88 um, 23.54 um and 4.22 ...
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In this reseach, chemical, anatomical and pulping properties of 12 years old Populus.triplo of adapting plan and quantity properties of this tree from karaj research station were investigated.The average of fiber length ,diameter ,lumen and thickness of cell wall 1.27 mm ,31.88 um, 23.54 um and 4.22 um and cellulose ,lignin , Ext. and ash %53.74 , %22.87 , %1.8 and %1.5 were measured respectively.The yield and kappa number of pulps between 41.152% - 48% and 18.06 – 25.28 were measured.In 14% and 18% effective alcoholli, tearh index 9.307 mNm²/gr and 10.147 mNm²/gr were obtained.
Pulp and paper
Said mohammad Mazhari mosavi; Saeed Mahdavi; Syed zyaldin Hosseini; Hossein Resalti; Hossein Usefi
Abstract
This research is aimed to study the possibility of rapeseed straw (Hayolla401) pulping and its paper characteristics, using Soda-AQ process. The average fiber length was found 1.04 millimeter and the average fiber diameter, lumen and thickness were found 28.00, 19.09, and 4.91 micrometer, respectively. ...
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This research is aimed to study the possibility of rapeseed straw (Hayolla401) pulping and its paper characteristics, using Soda-AQ process. The average fiber length was found 1.04 millimeter and the average fiber diameter, lumen and thickness were found 28.00, 19.09, and 4.91 micrometer, respectively. Cellulose, lignin, extractive material (acetone solved) and ash were measured 41.66, 16.00, 1.63, and3.46 percent, respectively. Cooking condition was determined as follow: Soda as 16, 18, and 20 percent on the basis of rapeseed dry straw, temperature was set at 175 and 185 Cº, cooking time was set at 40 and 70 minutes, and straw to liquid ratio was set at 1/8. The amount of anthraquinone added to cooking liquor was 0.2%, based on rapeseed dry straw. Using severe cooking factors caused reduction of yield and Kappa number in both methods. Refining was performed on selected pulps in order to reach 35025 (ml,CSF) freeness. The 60 gr/m² hand sheets were made in order to determine mechanical strength and physical properties. Average thickness, density and bulk is measured at 86.4µ, 0.69gr/cm³ and 1.44cm³/gr respectively. Average tear index, burst index, breaking length and tensile indexare measured at 4.6 mN.m²/gr, 3.5 kpa.m²/gr, 7.4km and 72.6Nm/g respectively.
The results showed that however screen yield of rapeseed straw pulp is low but kappa number and mechanical properties of pulp is suitable,compared with the other agriculture residues, so Rapeseed pulp can be used in paper making industries.
Pulp and paper
Mohammadreza Dehghani Firouzabadi; Afshin Tvasoli; Saeed Mahdavi
Abstract
We studied the possibility of replacing imported long fiber pulp (ILFP) with kenaf bast fiber soda pulp (KBFSP) to improve the quality of paper made with bagasse soda pulp (BSP). To do so, we produced BSP with kappa number 13.5 similar to that prepared by Pars Paper Mill. We also produced KBFSP with ...
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We studied the possibility of replacing imported long fiber pulp (ILFP) with kenaf bast fiber soda pulp (KBFSP) to improve the quality of paper made with bagasse soda pulp (BSP). To do so, we produced BSP with kappa number 13.5 similar to that prepared by Pars Paper Mill. We also produced KBFSP with kappa number 21.6 similar to the unbleached imported ILFP. The yield percent for BSP and KBFSP were respectively 48.9 and 55.6 %. The maximum pulping temperature was 165 °C; alkaline was 20% based on sodium hydroxide and ratio of liquor to dry weight of the raw material was 8:1. All the three pulps were beaten up to a freeness degree of 400 ml, CSF. Amounts of 0, 10, 20 and 30 percent ILFP and KBFSP were mixed with 100, 90, 80 and 70 percent BSP to produce hand sheets. In all cases of KBFSP mixing with BSP, the thickness of the generated hand sheets were higher than those produced through mixing ILFP with BSP while the density was lower. The difference in burst strength and breaking length of a mixture of 30% KBFSP with 70% BSP in the hand sheets were non-significant as compared with those of ILFP and BSP. Tear strength and opacity of mixing 30% KBFSP with 70% BSP were significantly higher than those of the ILFP and BSP with the same mixing ratio. We suggest that KBFSP provides a suitable replacement for ILFP to improve physical and strength properties of paper made with BSP.
