Chemistry of wood
Seyed Hassan Sharifi; Saltanat Archin; Leila Aghanaghifar
Abstract
DOR:98.1000/1735-0913.1398.34.16.66.1.1575.1603 One of the most important sources of environmental pollution is dye from industrial wastewater which is harmful for human health and environment. Therefore, the aim of this study was to evaluate removal of Methylene Blue (MB) dye from aqueous solutions ...
Read More
DOR:98.1000/1735-0913.1398.34.16.66.1.1575.1603 One of the most important sources of environmental pollution is dye from industrial wastewater which is harmful for human health and environment. Therefore, the aim of this study was to evaluate removal of Methylene Blue (MB) dye from aqueous solutions by straw using ultrasonic wave with response surface methodology. The batch experiment was conducted to evaluate the effect of dye concentration, contact time, adsorbent dosage and pH on dye removal from aqueous solution. Response surface methodology was applied to appraise the effect of these different variables. The dye concentration in the solutions was measured by spectrophotometer at the wavelength of 664 nm. The results showed that the optimum parameter values for maximum color removal efficiency were: dye concentration 20 mg/L, reaction time 8 min, dose of adsorbent 4 g/L and pH=9. The Maximum and minimum dye removal were obtained 92.29 and 47.5 percent, respectively. Analysis of variances test showed that the quadratic model was the best model to explain the interaction of variables. Based on analysis of variance (ANOVA), the coefficient of determination value (R2 =0.9116) was high, showing that the experimental values fitted well with the predicted values. In addition, the statistical analysis of the results indicated that in the range studied, dose of adsorbent and pH had a significant effect on color removal efficiency. The Gibbs free energy and enthalpy data verified its spontaneous and endothermic nature. In addition, survey of pseudo first and second order kinetics models presented that the adsorption process was compatible to pseudo-second order kinetics equation.
Pulp and paper
somayeh heydari; Ahmad Reza Saraeyan; Mohammad Reza Dehghani Firouzabadi; Alireza Shakeri; babak shokri
Abstract
DOR:98.1000/1735-0913.1398.34.100.66.1.9.1604 In this study, EVOH was coated on paper made of CMP pulp by extrusion method in order to improve the paper's barrier properties of oxygen transmission. Ethylene vinyl alcohol (EVOH) shows poor moisture resistance despite less gas permeability. Then, dimethoxydimethylsilane ...
Read More
DOR:98.1000/1735-0913.1398.34.100.66.1.9.1604 In this study, EVOH was coated on paper made of CMP pulp by extrusion method in order to improve the paper's barrier properties of oxygen transmission. Ethylene vinyl alcohol (EVOH) shows poor moisture resistance despite less gas permeability. Then, dimethoxydimethylsilane was deposited using Plasma Enhanced Chemical Vapor Deposition on EVOH film as the hydrophobic layer. A random factorial experiment was designed with three factors at three levels including time (6-8-10 min), pressure (30-0400-500 m Torr), and radio frequency power (50-70-90 W). The contact angle, oxygen transmission rate, tensile strength, and strain energy were measured to obtain the optimum condition. Expert Design method using response surface was used to optimize the condition coating Dimethoxydimethylsilane in order to improve the hydrophobic properties, reduce OTR, increase tensile strength and strain energy. Based on this method the optimum condition was suggested as: time 6 min, pressure 499.99 m Torr and power 50W. Keywords: Extrusion , Contact angle, Oxygen transmission rate, Response Surface methodology.
Pulp and paper
Hamed Sharifi tasco; yahya hamzeh; shademan pourmousa
Abstract
In this study dispersed deinked pulp (DIP) of Latif Company which includes a mixture of straw printers, mixed office waste (MOW) and mechanical recycle paper was used to investigate the effect of bleaching variables on pulp and paper properties. Six variables of bleaching process including the amount ...
Read More
In this study dispersed deinked pulp (DIP) of Latif Company which includes a mixture of straw printers, mixed office waste (MOW) and mechanical recycle paper was used to investigate the effect of bleaching variables on pulp and paper properties. Six variables of bleaching process including the amount of hydrogen peroxide, sodium hydroxide, and sodium silicate, bleaching time, bleaching temperature and final pH were optimized in order to improve wet and dry tensile index of handsheet. Design Expert software was used for analyzing and modeling. Results in from of the central composite design (CCD) were investigated and response surface methodology (RSM) was modeled and analyzed. Optimized wet and dry tensile were obtained by appling 1.55% hydrogen peroxide, 1.55% sodium hydroxide and 1.55% silicate, 90 minutes bleaching time, 83 0C bleaching temperature, and final pH equal to 8.5. The result showed that bleaching variables affect significantly the optical properties sample as well as mechanical strength of paper, and also dry and wet tensile strengths can be improved by optimization of bleaching condition.
Composite wood products
Sajad Akbari; Morteza Nazeryan; Saeid reza Farokhpayam; Babak Nosrati sheshkal
Abstract
In this study the possibility of using canola stalks mixed with poplar wood in the manufacture of particleboard was investigated. Weight ratio of canola particle to poplar particles at five levels (98, 93/75, 87/50, 81/25, 77%), the weight ratio of the urea-formaldehyde/melamine formaldehyde resin as ...
Read More
In this study the possibility of using canola stalks mixed with poplar wood in the manufacture of particleboard was investigated. Weight ratio of canola particle to poplar particles at five levels (98, 93/75, 87/50, 81/25, 77%), the weight ratio of the urea-formaldehyde/melamine formaldehyde resin as a adhesive at five levels (23, 18/75, 12/50, 6/25, 2%) and moisture content of matt at five levels (10, 12, 15, 18, 20%) were selected as production variables. Mechanical properties of boards consist of MOR, MOE and IB was tested. According to the results, with increasing the canola stalks/poplar particle ratio MOR and MOE of the boards decreased, but all of the values obtained from treatments were higher than standard. Interaction effect analysis of variables showed that the increasing the ratio of melamine formaldehyde/urea formaldehyde resin decreased the bending strength, while the increasing the moisture of mat increased MOR and MOE. IB values of all treatments are lower than the standard. According to the results of response surface methodology (RSM) and interaction effect between studied variables on the mechanical properties of the panels, the best situation for producing the panels was selected as: weight ratio of 84/32 for canola/poplar particle, ratio of 6/25 for UF/MF resin and moisture content of 12% for mattress.
