Document Type : Research Paper

Author

Associate Professor, Islamic Azad University of Chalous Branch, Chalous,Iran

Abstract

The aim of study was accomplished on identification and comparison of chemical compounds in wood and bark of oak. For this purpose, the samples were chosen randomly from oak in Nowshahr forest region. Then, flour and ash were provided from heart wood, sap wood and bark of oak by TAPPI standards. For measured metallic ions, first the mineral compound of ash dissolved by 65% nitric acid and for it's identified by atomic adsorption method. The results showed that Fe, Zn and Cu ions in wood of oak were more than its bark and its Mn ion was lower. Then extractives were separated from wood flour by acetone and extractives residue transferred to glassy vial and was added BSTFA reactor to it. After samples prepared, its were injected by GC/MS for analyze. Identification of compounds was done by retention time of each compound, calculation of quartz index and Adams table. The result of GC-MS showed that there are 10, 42 and10 compounds in heart wood, sap wood and bark of oak, respectively. Comparison of chromatograms showed that Decan, Dodecan, Tetradecane and Bis(2-ethylhexyl)phthalate were exists as 4 common components in bark, sap wood and heart wood of oak and Silicic acid and 1,2-Benzenedicarboxylic acid were exists as 2 common components in bark and sap wood of oak. These compounds can very important in durability and consumption its.

Keywords

Main Subjects

- Ashrafi S., 2011. Identification and comparison of chemical components in wood and bark of planted elder pine and plane tree by GC-MS methods, graduated of master science, Islamic Azad University of Chalous Branch,92-93 , (in Persian).
- Barzan A., Soraki, S., 2002. Procedure of experimental for pulp and paper, Mazandaran Wood and Paper Industries, Sari, Iran, 111-121, (in Persian).
- Balaban, M., 2001. The extractives and its structural in wood and bark of oak, Journal of Holz forshung, 55(1), 478-486.
- Holmbom, B., 1977.  Improve gas chromatographic analysis of fatty and resin acid mixtures with special reference to tall oil. JAM oil chemistry, 54(1),284-243.
- Hossieni, S.V., 1991. Chromatography methods, Center of edition, Tehran, Pp:29-38, (in Persian).
- Hosseini, S. Kh., 2009. Identification of extractives chemical components in Iranian walnut by GC/MS methods, Journal of Agriculture Science, Tehran, Iran, 12(4), 126-132, (in Persian).
- Khazraie, L., 2006. Separating and Identification of lipophilic compounds in wood and bark extractives in beech by GC-MS methods, Thesis of master science, Payame- noor Univ.  Tehran, Pp:1.
- Mirshokraei, S.A.,2002. Wood chemistry. Aieg edition.Tehran, press. 194 p. (Translated in Persian)
- Meszaros, E., Jakab, E. and Varhegyi, G., 2006. TG/MS, Py-GC/MS and THM-GC/MS study of the composition and thermal behavior of extractive components of Robinia pseudoacacia, J. Anal. Appl. Pyrolysis 79: 61-70.
- Parsapajouh, D., 1993. Atlas of Iranian northern woods. Tehran Univ. Press, 48 and 106 p.(In Persion).
- Rahmani,H. and Abdolkhani,A.,2010. Characterization and removal of resins from mixed tropical hardwoods, Iranian Journal of Wood and Paper Industries, 1(1), 45-46, (in Persian).
- Technical Association of Pulp and Paper Industry (TAPPI), 2009. Standard Test Methods, Tappi Press, Atlanta, GA. USA.
- Torkman, J., 1992. Analyzing of bark extractives in fives species of Iranian hard woods trees, Thesis of master science, Tarbiat Modares Univ.  Tehran, Pp:1-2.
- Tunalier, Z. K., 2003. Wood essential oils of Junipers foetidissima willd,  Forshung, 57(1),140-144.
- Vaysi, R., 2010. Identification and comparison the extractives chemical components in natural and planted cypress tree by GC-MS methods, Journal of sciences and techniques in natural resources, Chalous, Iran, 4(1), 79-80. (In Persian).
- Vaysi, R., 2013. Identification and comparison of chemical components in sweet locust and false acacia wood extractions by GC-MS methods, Iranian J. of Wood and Paper Sci. and Technology 28(4), 755-762 , (in Persian).
- Vaysi,R., 2011. Identification of the extractives chemical compounds in newsprints by GC-MS methods, Asian journal of chemistry,23(11),5155-5156.
- Xiao, B., Sun, X.F., and Sun, R.C., 2001. Extraction and characterization of lipophilic extractives from rice straw chemical composition, Journal of wood chemistry and technology, 21(1), 397-411.