Document Type : Research Paper

Authors

1 Wood and Paper Science and Technology Department, Natural Resources Faculty, Tarbiat Modarres University, Noor, Mazandaran, Iran.

2 Assistant Professor, Tarbiat Modares University

3 Wood and Paper Science and Technology Department, Natural Resources Faculty, Tarbiat Modarres University, Noor, Mazandaran, Iran

Abstract

As the papermaking fibers contain negative charge, therefore some polymer additives used in the pulp slurry, possess counter-ions (cationic polyeletrolyte). Meanwhile, due to increase of electrical conductivity (EC) in the suspension, the performance of many polyelectrolytes encounter some problems. Hence, according to the efforts for the water system closure, less raw water consumption, and therefore higher EC of the pulp suspension, how the performance of polyelectrolyte-based additives such as cationic starch-anionic nanosilica is adversely affected. In this due, the effectiveness of EC on the performance of the mentioned additive combination was investigated. The results confirmed that the EC negatively affected the performance of the wet-end additive system; although the amount of effectiveness was dependent on the type of the pulp property. Such that for low polyelectrolyte dosage and high EC, in certain properties, the positive effect of this additive system was not significant anymore. But, in the case of some other properties such as internal bond and freeness, despite of the negative effects of high EC, the performance of cationic starch-anionic nanosilica system was significantly remarkable.

Keywords

-Cao, Q. and Bachmann, M., 2013. Polyelectrolyte adsorption on an oppositely charged spherical polyelectrolyte brush. Soft Matter, 9(20): 5087-5098.
-Gess, J.M., 1998. Retention of Fines and Fillers During Papermaking. TAPPI Press, Atlanta, 357p.
-Hamzeh, Y., 2014. Water and Wastewater Management in Pulp and Paper Industries. Iranian Student Book Agency, 456p.
-Horvath, A.E., Lindström, T. and Laine, J., 2006. On the indirect polyelectrolyte titration of cellulosic fibers. Conditions for charge stoichiometry and comparison with ESCA. Langmuir, 22(2): 824-830.
-Hubbe, M.A., 2005. Microparticle programs for drainage and retention: 1-36. In: Rodriguez, J.M., (Ed.). Micro and Nanoparticles in Papermaking. TAPPI Press, Atlanta, 197p.
-Khosravani, A., Latibari, A.J., Mirshokraei, S.A., Rahmaninia, M. and Mohammad Nazhad, M., 2010. Studying the effect of cationic starch-anionic nanosilica system on retention and drainage. BioResources,5(2): 939-950.
-Khosravani, A. and Rahmaninia, M., 2013. The potential of nanosilica–cationic starch wet end system for applying higher filler content in fine paper. BioResources, 8(2): 2234-2245.
-Mehranfar, A.H., Khosravani, A. and Rahmaninia, M., 2017. The effect of cationic starch degree of substitution on nanoparticle system performance in old corrugated containers recycling. Journal of Forest and Wood Products, 70(1):147-155.
-Rahmaninia, M. and Khosravani, A., 2015. Improving the paper recycling process of old corrugated container wastes.  Cellulose Chemistry and Technology, 49(2): 203-208.
-Sabazoodkhiz, R., Rahmaninia M. and Ramezani, O., 2017. Interaction of chitosan biopolymer with silica nano-particle as a novel retention/drainage and reinforcement aid in recycled cellulosic fibers, Cellulose, 24: 3433–3444.
-Samoshina, Y., Nylander, T., Shubin, V., Bauer, R. and Eskilsson, K., 2005. Equilibrium aspects of polycation adsorption on silica surface: how the adsorbed layer responds to changes in bulk solution. Langmuir, 21(13): 5872-5881.
-Thorn, I. and Au, C.O., 2009. Applications of Wet-End Paper Chemistry. Springer, Netherlands, 226p.
-Wagberg, L., 2000. Polyelectrolyte adsorption onto cellulose fibres-A review. Nordic Pulp & Paper Research Journal, 15(5): 586-597.
-Wågberg, L., Winter, L., Ödberg, L. and Lindström, T., 1987. On the charge stoichiometry upon adsorption of a cationic polyelectrolyte on cellulosic materials. Colloids and surfaces, 27(1-3): 163-173.
-Wang, F. and Hubbe, M.A., 2002. Charge properties of fibers in the paper mill environment. 1. Effect of electrical conductivity. Journal of Pulp and Paper Science, 28(10): 347-353.
-Yousefhashemi, S.M., Khosravani, A., Yousefi, H., 2019. Isolation of lignocellulose nanofiber from recycled old corrugated container and its interaction with cationic starch-nanosilica combination to make paperboard. Cellulose, 26: 7207-7221.