Identification and Comparison of the Phenolic Chemical Components in Populus nigra and Populus deltoides wood by GC-MS Methods

Vaysi, Ramin

doi:10.22092/ijwpr.2024.364731.1767

Document Type : Research Paper

Author

Ramin Vaysi

Associate Prof., Dept. of Wood and Paper Science and Technology, Islamic Azad University of Chalous, Chalous, Iran

https://doi.org/10.22092/ijwpr.2024.364731.1767

Abstract

Background and aim: As a result of population growth, paper and wood products consumption has increased, and restrictions on using forest wood raw materials initiated the utilization poplar trees as fast-growing spices. The aim of this study was to focus on identification and comparison of the phenolic chemical components in poplar woods (Populus nigra and Populus deltoides).
Materials and methods: In this study, three trees from each poplar tree were randomly felled in plantation near Nowshar, Iran. Then three discs were cut from each log. At first, wood was grounded and then wood flour extractive were measured using TAPPI standard procedure. Wood flour was extracted by acetone and extractives residue was added to BSTFA reactor and samples were kept in constant temperature bath at 70^oC for an hour. The extractive samples were then analyzed by GC/MS. The compounds were identified using GC diagram which shows abundance and retention time of each compound, and calculation of quartz index and Adams table.
Results: The result of GC-MS showed that there exist 68 and 105 compounds in wood of Populus nigra and Populus detoides, respectively. di-Limonene (30.26%), bis (2-ethylhexyl) phthalate (10.07%), Gamma-Sitosterol (1.06%), Hexadecanoic acid (2.0%), gamma-Terpinene (4.02%) and 4-Hydroxy-Benzoic acid (3.62%) were the most important ‎ compounds in wood of Populus detoides. There were the Limonene (25.62%), Anymol (5.29%), gamma-Terpinene (3.38%), 1, 2-Benzandicarboxylic acid (2.00%) and bis (2-ethylhexyl) phthalate (0.68%) as the most important ‎ compounds in wood of Populus nigra.
Conclusion: The gas chromatographs showed that Limonene, Benzene methanol, alpha-Terpineol, beta-Bisabolene, Hexadecanoic acid and bis (2-ethylhexyl) phthalate were the 7 common compounds in the wood of Populus nigra and Populus deltoides. These compounds can play an important role in the durability and consumption of these woods.

Keywords

Main Subjects

Chemistry of wood

References

-Aminpour, T., 2009. Opportunities and Risks for poplar farming, the second congress of poplar planting potentials, Forest and Rangeland Research Institute. Pp: 381-386. (In Persian).

-Azadfar, D., 2006. Genetic polymorphism of Peroxidase enzymes in poplar genes. Sari Agricultural Sciences and Natural Resources University, Report of Research Plan, Pp: 21-33. (In Persian).

-Ashrafi, S., 2011. Identification and comparison of chemical components in wood and bark of planted elder pine and plane tree by GC-MS methods, graduated of master science, Islamic Azad University of Chalous Branch, 92-93, (in Persian).

-Barzan A. and Soraki, S., 2002. Procedure of experimental for pulp and paper, Mazandaran Wood and Paper Industries, Sari, Iran, 111-121, (in Persian).

-Balaban, M., 2001. The extractives and structural in wood and bark of oak, J. of Holzforshug, 55, 478-486.

-Holmbom, B., 1977. Improve gas chromatographic analysis of fatty and resin acid mixtures with special reference to tall oil. J. of oil chemistry, 54,284-243.

-Hossieni, S.V., 1991. Chromatography methods, Center of edition, Tehran, Pp, 29-38, (in Persian).

-Hosseini, S. Kh., 2009. Identification of extractives chemical components in Iranian walnut by GC/MS methods, J. of Agriculture Science, Tehran, Iran, 12(4), 126-132, (in Persian).

-Jalili, A., 2008. Strategy of sustainable supply of lignocellulosic materials in Iran, The Research Institute of Forests and Rangelands. Pp: 321-332. (In Persian)

-Khazraie, L., 2006. Separating and identification of lipophilic compounds in wood and bark extractives in beech by GC-MS methods, Thesis of master science, Payame- noor Univ. Tehran, Pp: 1.

-Kiaei, M., 2016. The relationship between extractive components and density of Persian Ironwood, Journal of Lignocellulose 5(1), 59-65.

-Mirshokraei, S.A., 2002. Wood chemistry. Aieg edition.Tehran, press. 194 p. (Translated in Persian)

-Meszaros, E., Jakab, E. and Varhegyi, G., 2006. TG/MS, Py-GC/MS and THM-GC/MS study of the composition and thermal behavior of extractive components of Robinia pseudoacacia, J. of Analytical and Applied Pyrolysis, 79: 61-70.

-Mohamadzadeh, K., 2013. The socio-economic development of the plantation of poplar and providing the solutions, MSC thesis, natural resources faculty. University of Tehran 112p. (In Persian)

-Parsapajouh, D., 1993. Atlas of Iranian northern woods. Tehran Univ. Press, 48 and 106 p. (In Persion).

-Rahmani, H. and Abdolkhani, A., 2010. Characterization and removal of resins from mixed tropical hardwoods. Iranian J. of Wood and Paper Industries, 1(1), 45-46, (in Persian).

-Technical Association of Pulp and Paper Industry (TAPPI), 2009. Standard Test Methods. Tappi Press, Atlanta, GA. USA.

-Torkman, J., 1992. Analyzing of bark extractives in fives species of Iranian hard woods trees, Thesis of master science, Tarbiat Modares Univ. Tehran, Pp: 1-2.

-Tunalier, Z.K., 2003. Wood essential oils of Junipers foetidissima willd. J. of Holzforshug, 57, 140-144.

-Vaysi, R., 2017. A study on the possibility of identification and comparison of metallic ions and chemical components in wood and bark of oak by atomic adsorption and GC-MS, Iranian J. of Wood and Paper Sci. and Technology 32(2), 275-286. (in Persian).

-Vaysi, R., 2013. Identification and comparison of chemical components in sweet locust and false acacia wood extractions by GC-MS methods, Iranian J. of Wood and Paper Sci. and Technology 28(4), 755-762. (in Persian).

-Vaysi, R. and Kord, B., 2013. The effects of H₂O₂ bleaching and DTPA spraying on the brightness stability of hornbeam CMP pulp following accelerated irradiation aging, BioResource Journal 8(2), 1909-1917.

-Vaysi, R., 2011. Identification of the extractives chemical compounds in newsprints by GC-MS methods, Asian journal of chemistry, 23(11), 5155-5156.

-Vaysi, R., 2019. A study on the possibility of identification and comparison of metallic ions and chemical components in wood of persuan maple and caucasian maple wood by atomic absorption and GC-MS methods, Iranian J. of Wood and Paper Sci. and Technology 34(3), 361-371, (in Persian).

-Vaysi, R. and Habib Porian, M.H., 2022. A study on the possibility of identification and comparison of organic chemical components in wood and bark of hornbeam and iron wood trees by GC-MS methods, Iranian J. of Wood and Paper Sci. and Technology 37(2), 150-165, (in Persian).

-Xiao, B., sun, X.F. and sun, R.C., 2001. Extraction and characterization of lipophilic extractives from rice straw chemical composition, J. of wood chemistry and technology, 21: 397-411.

Iranian Journal of Wood and Paper Science Research

Identification and Comparison of the Phenolic Chemical Components in Populus nigra and Populus deltoides wood by GC-MS Methods

References

References

Volume 39, Issue 2 - Serial Number 87
June 2024
Pages 121-132

Identification and Comparison of the Phenolic Chemical Components in Populus nigra and Populus deltoides wood by GC-MS Methods

References

References

Volume 39, Issue 2 - Serial Number 87June 2024Pages 121-132

Volume 39, Issue 2 - Serial Number 87
June 2024
Pages 121-132