Document Type : Research Paper

Authors

1 Assistant professor, Wood and Paper Science and Technology, Karaj Branch, Islamic Azad University, Karaj, Iran,

2 M.Sc., Wood and Paper Science and Technology, Karaj Branch, Islamic Azad University, Karaj, Iran

Abstract

In this study, Cationic Pulp Fiber (CPF) was prepared using three levels of 0, 2, 4% (3-chloro-2-hydroxy propyl) trimethyl ammonium chloridein and three temperatures of 40, 60 and 80 °C. Then the CPF fibers were blended with virgin pulp fibers to make handsheets.The results showed that the effect of temperature, CHTMA and CHTMA*temperature interaction on cationizing the fibers was statistically significant. Maximum absorption of cationic CHTMA on pulp fibers with the average of 53.33%was obtained by application of 2% CHTMA at 60 °C temperature. The mixture of 70% long  fibers , 30% short fibers, 1% cationized pulp fiber, 5% PCC and three levels of C-PAM (0, 0.05 and 0.1%) was used to prepare handsheets. Freeness of blended pulp and mechanical properties of produced paper such as tensile index, tear index and burst index was determined. Statistical analysis of results showed that the effect of applied treatments was statistically significant. The highest freeness and mechanical properties obtained in different conditions were as follow;  freeness (669 mlCSF): CPF 1%, C-PAM 0.05%, PCC 5%; tensile index (15.25 N.m/g): CPF 1%, C-PAM 0.1%, PCC 5%; tear index (12.3 mN.m2/g): CPF 1%, C-PAM 0.1%, PCC 5%; burst index (0.68 kPa.m2/g): CPF 1%, C-PAM 0.05%, PCC 5%.

Keywords

 
 
- Barcus R.L.  and Bjorkquist D.W., 1997. Fibers and pulps for papermaking based on chemical combination of poly(acrylate-co-itaconate), polyol and cellulosic fiber, Patent 5698074, 17 page.
- Besemer A.C., Wilhelmine Verwilligen A.M.Y., Thiewes H.J.  and Van Brussel-Verraest D.L. 2005. Cationic fiber, Patent 6849156 B2, 8 Page.
- Garcia J., Cadena E.M, Vidal T. and Torres A.L. 2008. Determination of zeta potential and cationic demand of bleached pulps, V CONGRESO IBEROAMERICANO DE INVESTIGACION EN CELULOSA Y PAPEL, 13 Page.
- Harding R.C.G and Gess J.M. 1985. Method for preparation of cationic cellulose, Patent 4505775, 14 page.
- Hauser P.J., Brent Smith C. and Hashem M.M., 2004. Ionic crosslinking of cotton, AUTEX Research Journal, VOL 4, No 2, 95-100 p.p.
- Hashimoto K., Suzuki K. and Kamaya Y. 2004. Wet-end properties of cationic graft terpolymerized polyacrylamides, J Wood Sci, 50:271-274 p.p.
- Khosravani A., Jahan Latibari A., Mirshokraei S.A., Rahmaninia M. and Nazhad M.M, 2010. Studying the effect of cationic Starch-Anionic nanosilica system on retention and drainage, Bioresources, 5(2), 939-950 p.p.
- Liimatainen H., Kokko S., Roueu P. and Niinimak J. 2006. Effect of PCC filler on dewatering of fiber suspension, TAPPI JOURNAL, Vol 5, No:11, 11-17 p.p.
- Miyanishi T. and Shigeru M. 1997. Optimizing flocculation and drainage for microparticle system by controlling zeta potential, TAPPI JOURNAL, Vol 80, No 1, 262-270 p.p.
- Matsushita Y. Iwatsuki A. and Yasuda S. 2004. Application of cationic polymer prepared from sulfuric acid lignin as a retention aid for usual rosin sizes to neutral papermaking, J Wood Sci, 50:540-544 p.p.
-Nazari, A. Montazeri M. and Rahimi M.K. 2009. Completing both antimicrobial and bleach white cotton clothes and cationic nanoparticles of titanium dioxide using butane tetra carboxylic acid, Journal of Polymer Science and Technology, the twenty-second year, No. 1, pp. 41-51.
- Sood Y.V., Tyagi R. Tyagi S. Pande P.C. and Tondo R. 2010. Surface charge of different papermaking raw material and its influence on paper properties, Journal of Scientific and Industrial Research, Vol 69, 300-304 p.p.
- Technical Association of Pulp and Paper Industriy, 2008. Standard test methods, Tappi Press, Atlanta, GA, USA.
- Wei X. FENG Hai-Li and QIAN Xue-ren, 2008. Preparation and application of cationized pulp fiber as a papermaking wet–end additive, Journal of Forestry Research, 19(3), 235-238 p.p.