Document Type : Research Paper

Authors

1 University of Agricultural Sciences and Natural Resources

2 Associate Prof. Department of Wood and Paper Sciences and Technology, Sari University of Agricultural Sciences and Natural Resources, Sari, Iran

3 Department of Sciences, Sari University of Agricultural Sciences and Natural Resources

Abstract

This research was conducted to determine the optimal conditions for chemical modification of poplar wood with glutaraldehyde and its effect on the physical properties of products. Test samples were prepared according to the standard ASTM-D1037 and impregnated in the laboratory cylinders with Glutaraldehyde at a concentration of 10% by using vacuum-pressure method. Modification reaction was done in two procedure. Heating first in the laboratory cylinder (Hydrothermal) for 4 hour and second in oven for 4 level 4,12,24,48 and 48hours. Weight percent gain of modified by hydrothermal and oven method was measured 2.10, 9.26, 10.02, 11.40 and 14.15% respectively. Chemical modification with glutaraldehyde by hydroxyl group's substitution, reduced the uptake of water and swelling of poplar wood. So that at the end of soaking in water the heating in the oven for 48 hours with minimum water absorption and dimensional changes in the 57.32 and 12.08 respectively, and highest bulking, ASE and ASE′ in 8.31,67 and 35.51% respectively was selected as the optimal level. This improvement compared to other modification levels demonstrates the forming of permanent Cross-linking of acetal that increased by Prolongation of the heating time.

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-Chang, HT., Chang, ST., 2002 Moisture excluding efficiency and dimensional stability of wood improvedby acetylation. Bioresource Technology, 85:201–204.
-Devi, R.R. Ali, I. and Maji,T.K., 2003. Chemical modification of rubber wood with styrene in combination with a cross linker: effect on dimensional stability and strength property. Bioresource Technology, 88(3): 185-188.
-Devi, R.R., Maji, T.K., 2007. Effect of Glycidyl Methacrylate on the Physical Properties of Wood–Polymer Composites. Polymer Composites, 28 (1): 1-5.
-Epmeier, H., Johansson, M., Kliger, R., Westin, M., 2007. Materials properties and their interrelation in chemically modified clear wood of Scots pine. Holzforschung, 61:34–42.
-Hill, C.A.S., 2006. Wood modification: chemical, thermal and other processes. Wiley, Chichester. 239p.
-Hill, C.A.S., Hale, M.D., Ormondroyd, G.A., Kwon J.H. and Forster S.C., 2006. Decay resistance of anhydride-modified Corsican pine sapwood exposed to the brown rot fungus Coniophora puteana. Holzforschung, 60: 625-629.
-Hill, C.A.S., 2008. The reduction in the fiber saturation point of wood due to chemical modification using anhiydride regents: reappraisal. Holzforschung, 62:423-428.
-Jakiela, S., Bratasz, L., Kozlowski, R., 2008. Numerical modeling of moisture movement and related stress field in lime wood subjected to changing climate conditions. Wood Science Technology 42:21–37.
-Jani, M., Rozman, D. and Rahim, S., 2007. Rubber wood-polymer Composites: The Effect of Chemical Impregnation on the Mechanical and Physical Properties. Malaysian Polymer Journal, 2(2): 1-11.
-Li,Y., Liu, Z., Dong, X., Fu, Y. and Liu, Y., 2011. Comparison of decay resistance of wood and wood polymer composite prepared by in- suit polymerization of monomers. 15th International Biodeterioration and Biodegradation Symposium, Vienna, Austria, 19-24 September.
-Li, Y., Dong, X., Lu, Z., Jia, W. and Liu, Y., 2013. Effect of Polymer In Situ Synthesized from Methyl Methacrylate and Styrene on the Morphology, Thermal Behavior, and Durability of Wood. Journal of Applied Polymer Science. 128(1):13- 20.
-Mattos, B., Serrano, L., Gatto, D., Magalhaes, W.L.E. and Labidi, J., 2014. Thermochemical and hygroscopicity properties of pinewood treated by in situ copolymerisation with methacrylate monomers. Thermochimica Acta, 596: 70- 78.
-Mohebby, B., Sanaei, I., 2005. Influences of the hydro-thermal treatment on physical properties of beech wood (Fagus orientalis). The International Research Group on Wood Preservation, IRG Document No. IRG/WP 05-40303.
-Neimsuwan, T., Wang, S., Taylor, AM., Rials, TG., 2008. Statics and kinetics of water vapor sorption of small loblolly pine samples. Wood Science Technology, 42:493–506.
-Ohmae, K., Minato, K., Norimoto, M., 2002. The analysis of dimensional changes due to chemical treatments and water soaking of hinoki (Chamaecyparis obtusa) wood. Holzforschung, 56:98–102.
Papadopoulos, AN., 2005. Moisture adsorption isotherms of two esterified Greek hardwoods. Holz RohWerkst, 63:123–128.
-Ümit,C.,Y., Yildiz, S., and Gezer, E., 2005. Mechanical Properties and Decay Resistance of Wood-Polymer Composites Prepared from Fast Growing Species in Turkey, Bioresouce Technology, 96 (9): 1003-1011.
-Xiao, Z., Xie, Y., Militz,. H, Mai,C., 2009. Modification of wood with glutaraldehyde. In: Proceedings of the4th European conference on wood modification, Stockholm, Sweden.
-Xiao, Z., Xie, Y., Militz, H. Mai, C., 2010. Effect of glutaraldehyde on water related properties of solid wood. Holzforschung, 64:475–482.
-Xie, Y., Callum, A., Hill, S., Xiao, Z., Mai, C., Militz, H., 2011. Dynamic water vapour sorption properties of wood treated with glutaraldehyde, Wood Science Technology, 45:49–61.