Document Type : Research Paper

Authors

1 Associate Prof., Islamic Azad University of Chalous, Iran

2 Graduated in Wood and Paper Technology, Islamic Azad University of Chalous, Iran

Abstract

The objective of this research was accomplished on the effects of total chlorine free (TCF) and elemental chlorine free (ECF) bleaching on optical and mechanical properties of bagasse soda pulps. For this purpose, some unbleached bagasse soda pulps were randomly selected from Ahvaz Pars industry. Then these pulps were bleached with one, two and three P, OP, OPY, O(Ep)P, EHP and O(Ep)H bleaching stages by using oxygen(O) hydrogen peroxide(P), alkali extraction with hydrogen peroxide(Ep), sodium hypochlorite(H) and sodium dithionite(Y). The hand sheets with 70 gr/m2 were prepared from above-mentioned of pulps, and then the optical and mechanical properties were measured and compared according by using TAPPI standard test methods. The results showed that brightness, greenness, tear (except EHP stages), tensile, burst, breaking length strengths and folds were increased and opacity and a* factor were decreased by ECF and TCF bleaching stages. The effects of TCF bleaching stages were more sensible than ECF bleaching stages in improve of bagasse soda properties, too. In general, role of three OPY and O(Ep)H stages and two OP bleaching stages were better than EH(control) stage and unbleached bagasse soda pulps mill in improve of brightness and its paper strengths, too.

Keywords

Main Subjects

-Barzan A., S. Soraki, 2002. Procedure of experimental for pulp and paper, Mazandaran Wood and Paper Industries, Sari, Iran, 111-121, (in Persian).
-Buchert, J., Tenkanen, M., Kantelinen, A., and Viikari, L., 1994. Application of xylanases in the pulp and paper industry, Bioresource Technology, 50(1): 65-72
-Bajpai, P., 1998. Biotechnology for environmental protection in pulp and paper industry. Springer. Germany, Pp: 91-107.
-Costa, M.M., and Colodette, J.L., 2007. The impact of kappa number composition on eucalyptus kraft pulp bleachability. Brazilian Journal of Chemical Engineering, 24(1): 61-71.
-EK, M., 1992. Some aspects on the mechanisms of  photo-yellowing of high- yield pulps ,Royal institute of technology, Stockholm, Sweden, Ph.D Thesis.
-Cater, Henry A., 1996. The Chemistry of paper preservation, Journal of Chemical Education, 73 (11), 1068-1073.
-Forsskahl I .,H. Tylli and Olkkonen, C., (2000), Participation of carbohydrate – derived chromospheres in the yellowing of high – yield and TCF pulps , Journal of pulp and paper science Vol . 26 , No 7 .
-Hashemi, S.R., 2015. Investigation on TCF bleaching of Tobacco stalk soda pulp , Iranian j. of wood and paper sci. and technology 29(4), 619-628.
-Hedjazi, S.,A. Jahan Latibari, R. Patt., 2007. Investigation on TCF bleaching of wheat straw soda pulp, Journal of the Natural Res., 59(4), 935-951.
-Jeffries, T.W., and Viikari, L., 1996. Enzymes for pulp and paper processing. American chemical society. Washington, DC, 326p.
-Luiss, A.J., and Jackson, 2002. Textbook of pulping technology, McGraw-Hill, New York, NY, 126-132.
-Mirshokraie S.A.., 2003. Pulp and paper technology, Aeeizh publication, Tehran, Iran, 209-210p, (Translated in Persian).
-Mirshokraie S.A. and Abdolkhani A.,2005. Effects of metallic ions on brightness CMP pulp of hardwoods in north of Iran, Iranian journal national resourse,58 (2), (in Persian).
-Paullsson M. , Lucian A. and Arthur J., 2001. Potoyellowing of untreated chemi-thermo-mechanical pulp under argon, ambient and oxygen atmosphere, Journal of wood chemistry and technology, 21 (4).
-Tran A.V., 2003, Thermal yellowing of hard wood kraft pulp bleaching with a chlorine dioxide based sequence , Journal of pulp and paper science , Vol . 28 , No.4 .
-Technical Association of Pulp and Paper Industry, 2009. Standard Test Methods. Tappi Press, Atlanta, GA. USA.
-Vaysi, R., 2015. A study on the possibility of extraction, identification and removal of metallic ions and resins in bleached bagasse pulp by ECF stages , Iranian j. of wood and paper sci. and technology 30(1), 72-84.
-Vaysi, R., Behrooze, R.  and Khaj-e-Ali, E., 2016. The effect of ECF bleaching on optical and mechanical of bagasse soda pulp, , Iranian j. of wood and paper sci. and technology 30(2), 349-361.
-Xu E .C., 2002, H2o2 bleaching of mechanical pulps , Journal of pulp and paper science , Vol. 28 , No. 1.