Authors

1 MS.c. ,Wood and Paper Science and Technology Department ,Karaj Branch, Islamic Azad University, Karaj, Iran

2 Prof., Department of Wood and Paper Science and Technology, Karaj Branch, Islamic Azad University Karaj Branch, Karaj, Iran,

3 Associate Professor, Wood and Paper Science Dept. Research Institute of Forests and Rangelands

4 Assistant Professor, Wood and Paper Science and Technology, Karaj Branch, Islamic Azad University, Karaj, Ira

Abstract

The impact of  nanoclay  addition on the properties of  polypropylene/ OCC fibers/ nanoclay Composite was investigated. Composites were prepared using 67% polypropylene, 30% OCC fiber, 3% MAPP and three dosages (2.5, 5, 7.5% based on total weight of PP/OCC/MAPP) of  nanoclay. Premix- melting of nanoclay and polypropylene was used to add nanoclay to the composite mixture. Pre-mixed nanoclay/ polypropylene  was melt-mixed with OCC fibers and MAPP and then test samples were made using this compound. The results revealed that addition of nanoclay to polypropylene/OCC fiber composite reduced flexural strength , tensile strength and notched Izod impact strength, but the flexural modulus and tensile modulus of final composite were improved significantly. The influence of nanoclay addition on flexural strength and tensile modulus of composite  was statistically significant at 99% level whereas its effect on tensile strength was statistically significant at 95%. However, the effect of nanoclay on both flexural modulus of elasticity and impact strength was not statistically significant. The addition of nanoclay to the composite reduces the bonding between polypropylene and OCC fibers. In the case of notched Izod strength, nanoclay particles generated stress concentration point within the composite structure initiating easier failure. Water absorption after 2 and 24 hours immersion was reduced.

Keywords

- نوربخش، الف.، دوست حسینی، ک.، کارگر فرد، الف.، گلبابایی، ف. و حاجی حسنی، ر.، 1387. بررسی تولید WPC با استفاده از ضایعات کاغذ باطله OCC به روش ریزش کیک. مجله پژوهشی تحقیقات علوم چوب و کاغذ ایران. جلد23. شماره 2. صفحه 91-101.
- نوربخش، الف.، حسین زاده، ع.، جهان لتیباری، الف.، کارگر فرد، الف. و ککتا، وی.، 1383. مقایسه اثر مواد لیگنوسلولزی در سطوح مختلف انیدرید مالئیک پلی‌پروپیلن (MAPP) در چندسازه الیاف و آرد چوب/ پلی‌پروپیلن. مجله پژوهشی تحقیقات علوم چوب و کاغذ ایران. جلد 19. شماره 1. صفحات 49-68.
-ASTM annual book of  standard; Testing methods .2007, Philadelphia, PA .U.S.A
-Ashori.A. and Nourbakhsh.A, 2010. Preparation and characterization of polypropylene /wood flour/nanoclay composites.Eur . J .Wood Prod
-Caraschi,C. J.and A. Lopes. 2002. Woodflour as reinforcement of polypropylene. Material Research , 5(4):405-409
-Chowdhury,F.H, M.V, Hoosur., S. Jeelani ,2006. Studies on the flexural and thermomechanical properties of woven carbon/nanoclay-epoxy laminates . Material Science and Engineering A(421),298-306
-Faruk.O. and Matuana.L, 2008 Nanoclay reinforced HDPE as a matrix for wood-plastic composites, Composites Science and Technology 68, 2073-2077.
-Han.G, Lei .Y, Wu.Q, Kojima.Y, Suzuki.S, 2008 ,Bambo-Fiber filled hight density polyethylene composites:effect of coupling treatment and nanoclay J. Polym  Environ 16:123-130.
-Lei .Y, Wu.Q, Clemons.C.M, Yao.F, Xu.Y; 2007 .Influnce of nanoclay on properties of HDPE/wood composites, J. of  Applied  Polymer  Sience ,  Vol.106,3958-3966                                                              
-Mali, J.; p. Sarsama.; L. S. Lindberg.; S. M.Kortelainen.; J. Peltonen.; M. Vikki.; T. Koto.;S. Tiisala. 2003. Wood fiber-plastic composites,110-117
-Sanadi, A. R.; J. F. Hunt.; D. F. Caulfield.; G.  Kovacs volgyi.; B. Destree,2001. Hight  fiber-low matrix composites: Kenaf fiber/polypropylene. The sixth international conference on wood-fiber composites. Forest  Product  Society. PP:121-124
-Simon,M.W.;Stafford, K.T., Li,Q,2008.Nanoclay reinforcement  of  liquid silicone rubber. J. Inorg. Organomet. Polym.18:364 - 373
-Wang,H.,C,Zheng.,M,Elkovitch.,L.J,Lee and K.W,Koelling ,2001,  Processing and properties of polymeric nanocomposites,Polymer Engineering Science 41(11) , 236-246pp
-Wan,L.,K,Wang.,L,Chen., Y,Zhang., C,He.2005. Preperation , morphology and thermal/mechanical properties of epoxy/nanoclay composites.270-282