Document Type : Research Paper

Authors

1 Department of wood and paper science and technology, Karaj Branch, Islamic Azad University, Karaj, Iran

2 Professor, Pulp and Paper Specialist, Wood and Paper Science and Technology Department, Karaj Branch, Islamic Azad University, Karaj, Iran

3 Deapartment of wood and paper science and technology, Kraj Branch, Islamic Azad University, Karaj, Iran

Abstract

In this research, the influence of two temperatures (60 and 90°C) and three dosages of sodium hydroxide (5, 7.5 and 10%, based on the dry weight) on hornbeam wood chips alkaline pre-hydrolysis and soda pulping was studied. Soda pulping of both pre-hydrolyzed and control chips were conducted applying constant pulping variables. The effect of pre-hydrolysis on hemicelluloses removal and sodium hydroxide consumption and pulp characteristic including total yield, reject, pulp freeness, kappa number, and pulp strengths were measured and statically analyzed. In case the effect of variable on measured property was statistically significant, then Duncan multiple range grouping of the measured property was arranged. The result revealed that pre-hydrolysis removed almost 4.2% (based on dry wood) of hemicelluloses of the wood and pre-hydrolysis demonstrated easier soda pulping delignification, due to weakening the lignin-carbohydrate bonds and both total yield, reject and kappa number were reduced. Tensile strength index of the pulp produced using pre-hydrolyzed chips war lower and as the dosage of sodium hydroxide increases, the tensile strength index was reduced initiated from the removal of hemicelluloses which is also lower than control pulp, Tear strength index of the soda pulp from pre-hydrolyzed chips was mildly reduced which is anticipated to be the consequence of fiber weakening and fiber breaking during cooked chips defibration. The effect of pre-hydrolysis variables on tear strength was not statistically significant. Based on the result of this study, hornbeam wood can be a potential source of bio-refining based on lignocellulosic material.

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-Garrote‚ G. and Parajo‚ J.C, 2002. Non-isothermal autohydrolysis of eucalyptus wood. Wood Sci.‚ ‚ 36‚111-123.
-Garcia, J.C., Zamudio, M.A.M., Perez, A., Feria, M.J., Gomide, J.L., Colodette, J.L. and Lopez, F., 2011: Soda/AQ pulping of Paulownia wood after hydrolysis treatment. BioResources, 6(2): 971-986.
-Jahan, M.S. and Rahman, M.M., 2012: Effect of pre-treatment on the soda-anthraquinone pulping of corn stalks and Sacchariun spantaneus (kash). Carbohydrate Polymer, 88:583-566.
-Jeong T.-S., Um B.-H., Kim J.-S. and Oh K.-K.‚ 2010.Optimizing dilute-acid pretreatment of rapeseed straw foe extraction of hemicellulose. Appl. Biochem Biotechnol‚161 : 22-33
-Li H., Saeed A. , Jahan M.S. , Ni Y. and Van Heiningen A.‚ 2010.Hemicellulose removal from hardwood chips in the pre-hydrolysis step of Kraft-Based dissolving pulp production process. Journal of wood chemistry and technology‚30 : 48-60
-Liu W.,Yuan Z., Mao C. and Li K.‚ 2011.Removal of Hemicellulose by NaoOH pre-extraction from aspen chips prior to mechanical pulping. BioResources‚6(3) : 3469-3480
-Ormsby, R., Kastner, J.R. and Miller, J., 2012. Hemicellulose hydrolysis using solid acid catalysts generated from biochar. Catalysis Today 190: 89-97.
-Tappi standards and suggested methods, 2008: Tappi press, Atlanta, GA. USA.
-Travaini, R., Martin-Juarez, J., Lorenzo-Hernando, A. and Bolado-Rodriguez, S., 2016. Ozonolysis: An advantageous pretreatment for lignocellulosic biomass revisited. Bioresource Technology 199:2-12.
-Vena, P.F., Gorgens, J.F. and Rypstra, T., 2010. Hemicelluloses extraction from giant bomboo prior to kraft and soda/AQ pulping to produce paper pulps, value-added biopolymer and bioethanol. Cellulose Chemistry and Technology 44(4-6):153-163.
-Watson, S. L., Hutto, D., Genco, J. M., Van Walsum, G. and Van Heiningen A.‚ 2010. Pre-extraction of Hemicellulose from hardwood chips using an alkaline wood pulping solution followed by kraft pulping of the extracted wood chips. Ind. Eng. Chem. Res‚49: 12638-12645
-Yoon S.-H. and Sefik M. and Van Heiningen A.‚ 2011. Near-neutral pre-extraction of hemicellulose and subsequent Kraft pulping of southern mixed hardwoods. TAPPI Journal‚ January 2011‚ Jan: 7-15