Document Type : Research Paper

Authors

1 Department of Wood and Paper Science and Technology, Karaj Branch, Islamic Azad University, Karaj

2 Associated Professor of Wood and Paper Science and Technology, Karaj Branch, Islamic Azad University, Karaj

3 Prof., Payame Noor University, Tehran, I.R. Iran.

4 Assistant Professor, Wood and Paper Science and Technology, Karaj Branch, Islamic Azad University, Karaj, Iran.

Abstract

Soda - oxygen pulping of old corrugated container to produce totally chlorine free bleached pulp was investigated. In order to reach the optimum delignification condition; four levels of sodium hydroxide (9, 11, 13, and 15 %), three cooking times (90, 120, and 150 minutes) and two cooking temperatures (120, and 150 ºC) at 6 bar oxygen pressure were studied. Yield and kappa number of pulps were measured. Results showed that the pulp obtained applying 9% sodium hydroxide, 150 minute delignification time and 150 ºC delignification temperature which produced the pulp with the yield and kappa number of 72.44% and 24.72 respectively was suitable for further bleaching. Strength of selected pulp including burst strength, tensile strength, and tear strength indices were measured as 2.27 kPa.m2/g, 29.19 Nm/g and 10.24 mN.m2/g respectively. The pulp was bleached applying 3% H2O2 and 2% NaOH to reach the final brightness of 57.97% ISO.

Keywords

-  آزاد فر، م، ع. 1388. ارتقای ویژگی‏های کیفی الیاف کارتن‏های کهنه  (OCC) از طریق تیمار‏های لیگنین‏زدا. پایان نامه کارشناسی ارشد دانشکده منابع طبیعی و علوم دریایی نور، دانشگاه تربیت مدرس. 76 ص.
-  اسموک، گری.۱٣٨٢. فن آوری خمیر و کاغذ. میرشکرایی، ا. تهران، انتشارات آییژ.٥۰٢ ص.
- حجازی،س. 1384. کاربرد فرایند خمیرکاغذسازی سولفیت قلیایی – آنتراکینون (AS/AQ) و توالی‏های رنگ‌بری کاملاً بدون کلر  (TCF). رساله دکترا دانشکده منابع طبیعی دانشگاه تهران .
330 ص.
- حجازی،س. جهان لتیباری، ا. پات، ر. کروزاخیار،ا. پارساپژوه، د. چیرنر، ا. 1385. بررسی رنگ‌بری خمیر کاغذ سودا از کاه گندم با روش کاملاً بدون کلر (TCF). فصلنامه منابع طبیعی ایران. دوره 59، شماره4. صفحات؛ 951-935.
- جهان لتیباری، ا.، خسروانی، ا . و رحمانی نیا، م . ۱٣٨۶. فناوری بازیافت کاغذ  (تالیف و ترجمه). تهران، انتشارات آرویج. 540 ص.
- Bisner, H.M, Campbell, R., McKean, W.T.  (1993). Bleached Kraft Pulp from OCC, Progress in Paper Recycling, Available in www.sciencedirect.com.
- De Ruvo, J.,  (1986). Upgrading of Pulp from Corrugated Containers by Oxygen Delignification; TAPPI J. 35 (6):100-103
- Economou A.M., Economides D.G., (1999).Upgrading Recovered Papers with Low Mechanical Pulp Content to High Brightness Products by TCF Bleaching, Progress in Paper Recycling, Available in www.sciencedirect.com.
- Jahan Latibari, A., Hedjazi, S, Patt, R., Kordsachia, O. and Tschirner, U.  (2006). Totally Cholorine Free  (TCF). Bleaching of Wheat Straw Soda/Anthraquinone Pulp. Cellulose Chemistry and Technology. Vol 40. P:413-420.
- Patt, R. and Mielisch, H-J. (1997) "Application of a Catalyst in TCF Pulp Bleaching", Proceedings of 5th Brazilian Symposium on the Chemistry of  Lignins and other Wood Components. Curitiba , Brazil , 4458. 
- Saijonkari-Pahkala, K.  (2001). Nonwood Plants As Raw Material for Pulp and Paper. Agricultural and Food Science in Finland. Vol.10. Supplement1.
- United States Patent . Oxygen Delignification Of Old Corrugated Containers . Patent Number 5,486,268 .  (1996).
- Zanuttini, M.  and McDonough, T.  (2002) “Upgrading of OCC Pulp by Medium - Consistency Ozone Treatment” 2002 – Pulping Conferecne, São Paulo – Brazil.