Document Type : Research Paper

Authors

1 M.Sc. Student, Dept. of Pulp and Paper Sciences and Industries, Gorgan University of Agricultural Sciences and Natural Resources, Iran,

2 Associate Prof., Dept. of Wood and Paper Sciences and Industries, Gorgan University of Agricultural Sciences and Natural Resources, Iran

3 Assistant Prof., of Wood and Paper Sciences and Industries, Gorgan University of Agricultural Sciences and Natural Resources, Iran

Abstract

In the present study the effects of hot water pre-extraction and alkaline catalyzed were evaluated on soda-aq pulping of kenaf whole stem. In this respect, following kenaf chips pre-extraction at various temperature and time conditions, pulp preparation were carried out on oven-dried weight loss levels of 8.5, 11.5 and 14.5 % of the samples, and the reference untreated kenaf chips performed by using Soda-AQ at 3 levels of H-factors ( 983, 1408 and 1832 hours). Results indicated that kenaf chips weight losses increased while the pre-extracted pH decreased as pre-extraction temperature and time increased. The required H-factor for achieving certain level of weight loss was reduced by adding small amounts of alkali (0.15 % on oven dried kenaf) on hot water extraction stage. The Pulp yields were reduced by increasing cooking H-factor and extracted weight loss. Averages comparison indicated that significant differences were observed, at 95% confidence, between the pulp yield and kappa number from reference pulp and pre-extracted pulp samples at levels of about 8.5, 11.5 and 14.5 %, and pulp yields and their kappa number were higher in reference pulps than pre-extracted samples. In addition, pulp yield average was higher in pre-extracted samples by alkaline catalyzed than pre-extracted samples by hot water, however, no significant differences were observed between their kappa number average. Meanwhile, to obtain a certain (similar) kappa number, pre-extracted kenaf chips in comparison with reference untreated kenaf chips require lower H-factor.

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-Al-Dajani, W. W. and Tschirner, U. W., 2008. Pre-extraction of hemicelluloses and subsequent kraft pulping, Part 1: alkaline extraction. TAPPI JOURNAL, 7(6): 3-8
-Amidon, T. E., Bolton, T. S., Francis, R. C., and Gratien, K.,2006. Effect of Hot Water Pre-Extraction on Alkaline Pulping of Hardwoods. In TAPPI Engineering, Pulping, & Environmental Conferenc. November 5-8 (p. 156)
-Mendes, C. V. T., Carvalho, M. G. V. S., Baptista, C. M. S. G., Rocha, J. M. S., Soares, B. I. G., and Sousa, G. D. A., 2009. Valorisation of hardwood hemicelluloses in the kraft pulping process by using an integrated biorefinery concept. Food and Bioproducts Processing, 94: 1-11
            -Testova, L., 2006. Hemicelluloses Extraction from Birch Wood Prior to Kraft Cooking: Extraction Optimisation and Pulp Properties Investigation. MSc Thesis, Department of Chemical Engineering and Geosciences, Division of Chemical Thechnology, Lulea University of Technology, Sweden
-Van Walsum, G. P., 2009. Acid Hydrolysis of Hemicellulose in Green Liquor Pre-Pulping Extract of Mixed Northern Hardwoods. Appl Biochem Biotechnol, 153: 127-138 (Humana Press)
-Yoon, S. H., Macewan, K. and van Heiningen, A., 2008. Hot-water pre-extraction from Loblolly Pine (Pinus taeda) in an integrated forest products biorefinery.TAPPI JOURNAL, 7(6): 27-32
-Yoon, S. H. and van Heiningen, A., 2008. Kraft pulping and papermaking properties of hot-water pre-extracted Loblolly Pine in an integrated forest products biorefinery. TAPPI JOURNAL, 7(7): 22-27