Document Type : Research Paper

Authors

1 M.Sc., wood and Paper, Young Researchers and Elite Club, Chalous Branch, Islamic Azad University, Chalous, Iran.

2 Assistant professor in Science & Wood Industry & Paper Group, Zabol University, Iran.

3 Assistant Prof., Department of Paper and Packaging Technology, Faculty of Chemistry and Petrochemical Engineering, Standard Research Institute (SRI), Karaj

Abstract

This study with aim of investigation the effect of Nano SiO2 on the physical, mechanical and morphological properties of hybrid Nano composite from polypropylene-wood flour was done. For this purpose, wood flour at 60% weight ratio with polypropylene in extrusion were mixed and Nano SiO2 with 0, 1, 3 and 5% as variable agent were used. Also 4% of MAPP in all compounds as a coupling agent was used. Then Nano composites were manufactured by using injection molding techniques. Then mechanical tests such as tensile and bending and physical tests such as water absorption and thickness swelling in short time according to the ASTM standard was done on the samples. Also To determine how to dispersion of nanoparticles in polymeric matrix was used of Scanning Electron Microscope (SEM). Results showed that increase of SiO2 Nano particles, has positive effect on the mechanical properties and caused the improve them. With Increase in the amount of SiO2 Nano particles the water absorption in Nano composites were increased, but this process for thickness swelling was decrease.

Keywords

Main Subjects

-Abdolali Sarbandi, M., Bolhasani, M., Bilba, K., and Ashjary, R., 2010. Investigation of the effect Nanosilica and eucalyptus fiber on MOR of fiber-cement composite products. International Congress of wood and paper industries, Chalous, p. 103.
-Albala, R., Olmos, D., Aznar, A.J., Baselga, J., and González-Benito, J., 2004. Fluorescent labels to study thermal transition in epoxy/silica composites. Journal of Colloid Interface Science,277: 71 – 78.
-Ashori, A., 2008. Wood-plastic composites as promising green-composites for automotive industries. Bioresources Technol 99: 4661-4667.
 
-ASTM. 2006. Evaluating Mechanical and Physical properties of wood plastic composites products. American Society for Testing and Materials.
-Chen, X., You, B., Zhou, S., and Wu, L., 2003. Surface and Interface Characterization of Polyester-based Polyurethane/Nano-silica Composites. Surf. Interf. Anal, 35: 369–374.
-Deka, B, K., and Maji, T, K., 2012. Effect of SiO2 and Nano clay on the properties of wood polymer Nano composite. Polymer. Bull. (10): 60-75.
-Dominkovics, Z., Danyadi, L., and puka'nszky, B., 2007. Surface modification of wood flour and its effect on the properties of pp/wood composites. Composites Part A, 38(8), 1893-1901.
-Hossienzadeh, S., Ghorbani, M., and Beparva, P., 2013. Effect of colloidal silica nanoparticles produced from rice husk on dimensional stability and water absorption of poplar wood (Populus deltoides). Iranian Journal of Wood and Paper Science Research, 31 (4): 763-773.
-Kord, B., 2007. Review on application of Nano clay particles to production of wood-polymer Nano composite and those intelligibles. Article collection of Nano technology application congress in science and industries, P. 15.
-Kord, B., 2008. Investigation physical, mechanical and morphological properties of PP-wood flour-Nano filler hybrid composite. Ph.D rescript, Islamic Azad University, Science and Research Branch, Tehran, Iran. P. 504.
-Nourbakhsh, A. Ashori, A. R. 2009. Influence of Nanoclay and Coupling Agent on the Physical and Mechanical Properties of Polypropylene/Bagasse Nanocomposite. Journal of Applied Polymer Science,February, 112(3): 1386-1390.
-Parvinzadeh gashti, M., Moradiyan, S., Rashydi, A, S., and Yazdanshenas, M, A., 2012a. Morphological and thermal properties of polyethylene terephthalate Nano composites containing hydrophilic and hydrophobia Nano silica. Advanced materials in engineering, 31(2): 23-37. 
-Parvinzadeh gashti, M., Moradiyan, S., Rashydi, A, S., and Yazdanshenas, M, A., 2012b. Effect of type of Nano silica on the properties of polyethylene terephthalate-silica Nano composites. Journal of sciences and polymer technology, (3): 203-219.
-Simon de dios, A., and Diaz-Garcia, M, E., 2010. Anal. Chim. P. 666. 
-Song, G. J., 1996. Polymeric Nano-metered composites. Mater Rap (4):57-60.
-Tian, X., Zhang, X., Liu, W., Zhang, J., Ruan, C., and Cui, P., 2006. Preparation and Properties of Poly (ethylene terephthalate)–Silica Nanocomposites. J. Macromol. Sci. Phys, 45: 507-513,  
-Valeria Ramos, D., Helson da costa, M., Vera Soares, L.P., and Regina Nascimento, S.V., 2005. Modification of epoxy resin: a comparison of different types of elastomer. Polymer Testing, 24: 387-394.    
-Wu C, Xu T., and Yang, W., 2005. Synthesis and characterizations of novel, positively charged poly (methyl acrylate)–SiO2 Nano composites. Eur Polym J (41):1901–1908.
-Xanthos, M., 2005. Functional fillers for plantics, Wiley, Weinheim. P.700. 
-Xu, X., Jayaraman, K., Morin, C., and Pecqueux, N., 2008. Life cycle assessment of wood-fiber-reinforced polypropylene composites. J Mater Process Technol (198): 168-177.
-Yang, Y., and Gu, H., 2007. Preparation and Properties of Deep Dye Fibers from Poly (ethylene terephthalate)/SiO2 Nanocomposites by In Situ Polymerization. J. Appl. Polym. Sci, 105: 2363–2369,
-Zheng Y., Zheng Y., and Ning, R., 2003. Effects of Nanoparticles SiO2 on the performance of Nanocom- properties. Mater Lett (57):2940–2944.