Modification of Nano-zeolite Clinoptilolite by iron oxide Magnetic Nanoparticles for green acid 20 Dye Removal from Aqueous Solution

Taghizadeh, Fatemeh; Asadpour, Ghasem; Sharifi, Seyed Hassan

doi:10.22092/ijwpr.2021.352131.1642

Document Type : Research Paper

Authors

Wood and Paper Science Department, Faculty of Natural Resources, Sari Agricultural Sciences and Natural Resource University Sari, Iran

https://doi.org/10.22092/ijwpr.2021.352131.1642

Abstract

Industrial wastewater is one of the major environmental pollutants. Many industries effluents, including leather industry, printing, plastics, paper, food industry, cosmetics and industries like these use dyes for dyeing their products and consequently the output wastewaters contain industrial dyes. In this study, Nano zeolite Clinoptilolite modified by Fe₃O₄ magnetic nanoparticles was used to remove acid green 20 dye in a batch system. In batch absorption studies of acid green 20 dye with Nano zeolite-Fe3O4, the effect of factors such as pH, initial dye concentration, the amount of absorbent and sorption time was investigated on absorption efficiency in order to determine the optimal conditions for dye removal. In this study, the surface response method (RSM) using Box-Behnken design (BBD) was used to optimize the absorption of acid green 20. The results indicated that Nano zeolite-Fe₃O₄ is successfully absorbed the acid green 20 dye and has the ability to remove 99.47% of dye from 100 ml of the solution acid green 20 with the concentration of 50 mg/ l in optimal conditions of pH=3, time of 90 minutes and absorbent dose of 0.8 g/l. also, Freundlich and pseudo -second order models had the best fitting with the absorption process as isothermal and kinetic models, respectively. The results showed that the nanocomposite was significantly able to remove the acid green 20 dye from aqueous solutions in a short time. Therefore, it can be used as an effective absorbent to remove dye.

Keywords

20.1001.1.17350913.1400.36.2.1.1

References

-Afkhami, A. and Moosavi, R., 2010. Adsorptive removal of Congo red, a carcinogenic textile dye, from aqueous solutions by maghemite nanoparticles, J. Hazard. Mater,174: 398-403.

-Badeenezhad, A., Azhdarpoor, A., Bahrami, Sh. and Yousefinejad, S.,. 2018. Removal of methylene blue dye from aqueous solutions by natural clinoptilolite and clinoptilolite modified by iron oxide nanoparticles, Molecular Simulation, DOI: 10.1080/08927022.2018.1564077.

-Birjandi, N., Younesi, H. and Bahramifar, N., 2015. Comparison of the Efficiency of Alum and Polyaluminium Chloride for Removal of Paper Mill Wastewater Pollution, Enviromental Sciences, 13(1): 67-74.

-Boroghani, M., Mirnia, S.Kh., Vahhabi, J. and Ahmadi, S.J., 2014. Investigation of Nanozeolite Effects on Soil Erosion Decreasing using FEL3 Rainfall Simulator, Journal of Watershed Management, 5(9): 95-106.

-Bodaghifard, M.A. and Alimohammadi, E., 2017. Synthesis of sulfamic acid functionalized-magnetic nanoparticles andapplication as a retrievable and efficient catalyst for the green synthesisof 1,4-dihydropyridine and 2,3-dihydroquinazoline derivatives, Journal of Applied Research in Chemistry, 1(12): 121-134.

-Buntic, A., Pavlovic, M., Mihajlovski, K., Randjelovic, M., Rajic, N., Antonovic, D., Siler- Marinkovic, S. and Dimitrijevic-Brankovic, S., 2013. Removal of a Cationic Dye from Aqueous Solution by Microwave Activated Clinoptilolite—Response Surface Methodology Approach, Water Air Soil Pollut, DOI: 10.1007/s11270-013-1816-6.

-Calıskan, Y., Harbeck, S. and Bektas, N., 2018. Adsorptive Removal of Basic Yellow Dye Using Bigadiç Zeolites: FTIR Analysis, Kinetics, and Isotherms Modeling, Environmental Progress & Sustainable Energy, 38 (S1). DOI 10.1002/ep.12969.

-Crini, G., 2011. Non-conventional low-cost adsorbents for dye removal: a review, Bioresource Technology, 97(9): 1061-1085.

-Ebrahimi Barisa, R. and Tavakoli, H.R., 2013. environmental pollutants in pulp and paper industries and their control methods, The Second National Conference on Planning and Environmental Protection, https://civilica.com/doc/232177.

-Ghanbari, D., Salavati-Niasari, M. and Ghasemi-kooch, M., 2014. A sonochemical method for synthesis of Fe3O4 nanoparticles and thermal stable PVA-based magnetic nanocomposite, Journal of Industrial and Engineering Chemistry. 20(6): 3970-3974.

-Lee, J.W., Choi, S.P., Thiruvenk, R., shim, W.G. and Moon, H., 2006. Evaluation of the performance of adsorption and coagulation processes for the maximum removal of reactive dyes, Dyes and pigment, 69: 196-203.

-Majid, Z., AbdulRazak, A. and Noori, W., 2019. Modiﬁcation of Zeolite by Magnetic Nanoparticles for Organic Dye Removal. Arabian Journal for Science and Engineering, doi:10.1007/s 13369-019-03788-9.

-Malakootian, M. and Dehdari rad A., 2015. Performance Evaluation of Photo-Fenton Process in Removal of Acid Green 20 Dye from Wastewater of Textile Industries, Journal of Rafsanjan University of Medical Sciences, 10(14): 827-840.

-Naddafi, K. and Gholami, M., 2013. Removal of Reactive Red 120 from aqueous solutions using surface modified natural zeolite, Iran. J. Health & Environ, 7(3): 277-288.

-Oubagaranadin, J.U.K., Sathyamurthy, N. and Murthy, Z., 2007. Evaluation of Fuller's earth for the adsorption of mercury from aqueous solutions: A comparative study with activated carbon. Journal of hazardous materials, 142: 165-174.

-Rahmani, A.R., Asgari, Gh., Barjasteh Askari, F., Samadi, M.T. and Godini, K., 2012. Investigation of the Catalytic Ozonation Performance Using Copper Coated Zeolite in the Removal of Reactive Red 198 From Aqueous Solutions, Scientific Journal of Ilam University of Medical Sciences, 21: 215-225.

-Salmani, M.H., Rahmanian, R., Danaie, S. and Soltaninzadh, Z., 2015. Evaluation of Adsorption Process in Dye Removal from Industrial Wastewater, TB, 14 (3): 60-72.

-Samadi, M.T., Saghi, M.H., Ghadiri, K., Hadi, M. and Beikmohammadi, M., 2010. Performance of Simple NanoZeolite Y and Modified NanoZeolite Y in Phosphor Removal from Aqueous Solutions, Iran. J .Health & Environ, 3(1): 27-36.

-Shojaei, S., Ahmadi, J., Davoodabadi, M., Mehdizadeh, B. and Pirkamali, M., 2019. Removal of crystal violet using nanozeolite-x from aqueous solution: Central composite design optimization study, J. Water Environ. Nanotechnol, 4(1): 40-47.

-Sun, S., Murry, C.B., Weller, D., Folks, L. and Moser A., 2000. Monodisperse FePt nanoparticles and ferromagnetic FePt nanocrystal superlattices, Scince, 287:1989-1992.

-Yi, X.S., Shi, W.X., Yu, S.L., Li, X.H., Sun, N. and He, C., 2011. Factorial design applied to flux decline of anionic polyacrylamide removal from water by modified polyvinylidene fluoride ultrafiltration membranes, Desalination, 274(1-3): 7-12.

-Zarnegar, Z. and Safari, J., 2011. Application of magnetic nanoparticles in the removal of chemical dye contaminants, Quarterly Journal of Iranian Nanotechnology Association, 7(24): 63-65.

-Zolgharnein, J., Shahmoradi, A. and Ghasemi, JB., 2013. Comparative study of Box–Behnken, central composite, and Doehlert matrix for multivariate optimization of Pb (II) adsorption onto Robinia tree leaves, J Chemometrics; 27(1): 12-20.

Iranian Journal of Wood and Paper Science Research

Modification of Nano-zeolite Clinoptilolite by iron oxide Magnetic Nanoparticles for green acid 20 Dye Removal from Aqueous Solution

References

References

Volume 36, Issue 2 - Serial Number 75
July 2021
Pages 90-104

Modification of Nano-zeolite Clinoptilolite by iron oxide Magnetic Nanoparticles for green acid 20 Dye Removal from Aqueous Solution

References

References

Volume 36, Issue 2 - Serial Number 75July 2021Pages 90-104

Volume 36, Issue 2 - Serial Number 75
July 2021
Pages 90-104