Document Type : Research Paper

Authors

1 PhD student, Conservation of Historical and Cultural Properties, Faculty of conservation, Art University of Isfahan, Isfahan, Iran,

2 Assistant Professor, Conservation of Historical and Cultural Properties, Faculty of conservation, Art University of Isfahan, Isfahan, Iran.

3 Associate Professor, Faculty of Chemistry, Isfahan University of technology, Isfahan, Iran.

Abstract

The aim of this study was to evaluate the effect of cellulose nanofiber treatment on discoloration of historical papers. In this study, two types of cellulose nanofiber suspensions with a concentration of 1% by weight with water and ethanol were prepared. After treatment, the prepared samples were subjected to moist-heat aging according to TAPPI T 544 sp-03 standard and colorimetric, pH, ATR-FTIR spectroscopy and SEM microscopy were performed before and after aging. Examination of ATR-FTIR spectra obtained from the samples showed that the application of cellulose nanofiber treatment does not cause damage to the paper structure. After application of two treatments with cellulose nanofibers, the color of the samples became brighter, but after accelerated aging, the brightness of the samples decreased.The darkening of the color of the samples was caused by their exposure to accelerated aging conditions and the treatment of cellulose nanofibers did not cause discoloration. The pH of the samples increased after application of both types of cellulose nanofiber treatments, but after accelerated aging, the pH decreased slightly.
 

Highlights

-Ardelean, E., Nicu, R., Asandei, D., Bobu, E., 2009. Carboxymethyl chitosan as consolidation agent for old documents on paper support. Eur. J. Sci. Theol, 4(1): 67-75.

-Area, M.C. and Cheradame, H., 2011. Paper aging and degradation: recent findings and research methods. BioResources, 6(4): 5307-5337.

-Aliniyay Lakani, S., Afra, E., 2011. Nanofiber Cellulose and its Application in Improving Paper Properties. First National Conference on Nanomaterials and Nanotechnology, Islamic Azad University of Shahrood.

 Baglioni, P., Giorgi, R., 2006. Soft and hard nanomaterials forrestoration and conservation of cultural heritage. Soft. Matter, 2(3): 293–303.

-Bansa, H., Ishii, R., 1997. The effect of different strengthening methods on different kinds of paper. Restaurator, 2(4): 51- 72.

-Carter, H., 1996. The Chemistry of paper preservation: part 2, the yellowing of paper and conservation bleaching. J. Chem. Educ, 11(2): 1068-1073.

-Cocca, M., D’Arienzo, L., D’Orazio, L., 2011. Effects of Different Artificial Agings on Structure and Properties of Whatman Paper Samples. International Scholarly Research Network ISRN Materials Science. Article ID 863083.

-Ciolacu, D., Popa, V., 2011. Amorphous cellulose structure and characterization. Cellulose chemistry and technology, 45(2): 13-24.

-Cheng, S., Huang, A., Wang, S., Zhang, Q., 2016. Effect of different heat treatment temperatures on thechemical composition and structure of Chinese firwood. BioResources, 11(2): 4006-4016.

-Dreyfuss-Deseigne, R., 2017. Nanocellulose Films in Art Conservation. Paper Conservation, 18(1): 18-29.

-Dreyfuss-Deseigne, R., 2017. A New Mending Material: Nanocellulose Film. Journal of Paper Conservation, 18(1): 36-37.

-Feller, R., Wilt, M., 1993. Evaluation of cellulose ethers for conservation. United States of America: The Getty Conservation Institute press.

-Ghorbani, M., Samanian, K., Afsharpour, M., Sabet Jazari, A., 2018. Inhibition Behavior of the Cellulose Nanofibers and Hydroxypropyl Cellulose Bio-Nanocomposite A gainst Colour Changes as a Coating on the Paper Documents. Journal of Color Science and Technology, 12(2): 147-158.

-Ghorbani, M., Samanian, K., Afsharpour, M., Sabet Jazari, A., 2017. Introducing and Comparing Methods for Consolidation of Paper records and Suggesting the Use of Cellulose Nano-Fibers for Conservation of such records. GANJINE-YE ASNAD, 26(4): 110-131.

-Hadilam, M., Afra, E., Yousefi, H., Ghasemian, A., 2012. Investigate Resistive and barrier against moisture behavior of cellulose paper containing Nanofiber cellulose. First National Conference on Nanotechnology and its Applications in Agriculture and Natural Resources. University of Tehran – Karaj, Faculty of Agriculture and Natural Resources.

-Havlinova, B., Brezova, V., Minarikova, J., Ceppan, M., 2002. Investigations of paper aging a search for archive paper. Journal of materials science, 37(4): 303-308.

-Hajji, L., Boukir, A., Assouik, J., Lakhiari, H., Kerbal, A., Doumenq, P., Carvalho, M., 2015.  Conservation of Moroccan manuscript papers aged 150, 200 and 800years. Analysis by infrared spectroscopy (ATR-FTIR), X-ray diffraction (XRD), and scanning electron microscopy energy dispersive spectrometry (SEM–EDS). Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 136(4): 1038-1046.

-Holik, H., 2006. Handbook of paper and board, John Wiley & Sons, 32p.

-Konuklar, M., Sacak, M., 2011. A new method for paper conservation: triple mixture of methyl
cellulose, carboxymethyl cellulose and nano-micro calcium hydroxide particles. Hacettepe journal of
biology and chemistry, 39 (2): 403-411.

-Klemm, D., Kramer, F., Moritz, S., Lindstrom, T., Ankerfors, M., Gray, D., Dorris, A., 2011. Nanocelluloses: A new familyof nature-based materials. Angew. Chem. Int. Ed. 50(4): 5438-5466.

-Lopez-Suevos, F., Eyholzer, C., Bordeanu, N.and Richter, K., 2010. DMA analysis and wood bonding of PVAc latex reinforced with cellulose nanofibrils. Cellulose, 17 (2): 387-398.

-Łojewska, J., Miśkowiec, P., Łojewski, T., Proniewicz, L., 2005. Cellulose oxidative and hydrolytic degradation: In situ FTIR approach. Polymer degradation and stability, 88(3): 512-520.

-Mirehki, F., Shakeri, A., 2013. Preparation and Characterization of Microcrystalline Cellulose (MCC) from Kenaf and Cotton Stem. 4(2): 23-32.

-Pinto, R., Neves, M., Neto, C., Trindade, T., 2012. Composites ofcellulose & metal nanoparticles, nanocomposites: new trends& developments. Chapter 4, 73-96p.

-Sequeira, S., Casanova, C., Cabrita, E., 2006. Deacidification of paper using dispersions of Ca (OH)2
nanoparticles in isopropanol. Study of efficiency. Journal of Cultural Heritage, 7 (2): 264-272.

-Standard test methods for Paper, board and pulp- Determination of pH of aqueous extracts- Part 1: Cold extraction. Standard national organization of Iran. 3568-1, 2007.

-Standard Test Method for Effect of moist heat on properties of paper and board, TAPPI T 544 sp-03, 2003.

-Volke, L., Ahn, K., Hahner, U., Gindl‑Altmutter, W., Potthast, A., 2017. Nano meets the sheet: adhesive-free application of nanocellulosic suspensions in paper conservation. Heritage science, 5(23): 2-17.

-Xu, Sh., Girouard, N., Schueneman, G., Shofner, M.L. and Meredith, J.C., 2013. Mechanical and thermal properties of waterborne epoxy composites containing cellulose nanocrystals. Polymer Journal, 54 (24): 6589- 6598.

-Zervos, S. Alexopoulou, I.,­ 2015. Paper conservation methods: a literature review. Cellulose, 22(5): 2859-2897.

 

Keywords

-Ardelean, E., Nicu, R., Asandei, D., Bobu, E., 2009. Carboxymethyl chitosan as consolidation agent for old documents on paper support. Eur. J. Sci. Theol, 4(1): 67-75.
-Area, M.C. and Cheradame, H., 2011. Paper aging and degradation: recent findings and research methods. BioResources, 6(4): 5307-5337.
-Aliniyay Lakani, S., Afra, E., 2011. Nanofiber Cellulose and its Application in Improving Paper Properties. First National Conference on Nanomaterials and Nanotechnology, Islamic Azad University of Shahrood.
 Baglioni, P., Giorgi, R., 2006. Soft and hard nanomaterials forrestoration and conservation of cultural heritage. Soft. Matter, 2(3): 293–303.
-Bansa, H., Ishii, R., 1997. The effect of different strengthening methods on different kinds of paper. Restaurator, 2(4): 51- 72.
-Carter, H., 1996. The Chemistry of paper preservation: part 2, the yellowing of paper and conservation bleaching. J. Chem. Educ, 11(2): 1068-1073.
-Cocca, M., D’Arienzo, L., D’Orazio, L., 2011. Effects of Different Artificial Agings on Structure and Properties of Whatman Paper Samples. International Scholarly Research Network ISRN Materials Science. Article ID 863083.
-Ciolacu, D., Popa, V., 2011. Amorphous cellulose structure and characterization. Cellulose chemistry and technology, 45(2): 13-24.
-Cheng, S., Huang, A., Wang, S., Zhang, Q., 2016. Effect of different heat treatment temperatures on thechemical composition and structure of Chinese firwood. BioResources, 11(2): 4006-4016.
-Dreyfuss-Deseigne, R., 2017. Nanocellulose Films in Art Conservation. Paper Conservation, 18(1): 18-29.
-Dreyfuss-Deseigne, R., 2017. A New Mending Material: Nanocellulose Film. Journal of Paper Conservation, 18(1): 36-37.
-Feller, R., Wilt, M., 1993. Evaluation of cellulose ethers for conservation. United States of America: The Getty Conservation Institute press.
-Ghorbani, M., Samanian, K., Afsharpour, M., Sabet Jazari, A., 2018. Inhibition Behavior of the Cellulose Nanofibers and Hydroxypropyl Cellulose Bio-Nanocomposite A gainst Colour Changes as a Coating on the Paper Documents. Journal of Color Science and Technology, 12(2): 147-158.
-Ghorbani, M., Samanian, K., Afsharpour, M., Sabet Jazari, A., 2017. Introducing and Comparing Methods for Consolidation of Paper records and Suggesting the Use of Cellulose Nano-Fibers for Conservation of such records. GANJINE-YE ASNAD, 26(4): 110-131.
-Hadilam, M., Afra, E., Yousefi, H., Ghasemian, A., 2012. Investigate Resistive and barrier against moisture behavior of cellulose paper containing Nanofiber cellulose. First National Conference on Nanotechnology and its Applications in Agriculture and Natural Resources. University of Tehran – Karaj, Faculty of Agriculture and Natural Resources.
-Havlinova, B., Brezova, V., Minarikova, J., Ceppan, M., 2002. Investigations of paper aging a search for archive paper. Journal of materials science, 37(4): 303-308.
-Hajji, L., Boukir, A., Assouik, J., Lakhiari, H., Kerbal, A., Doumenq, P., Carvalho, M., 2015.  Conservation of Moroccan manuscript papers aged 150, 200 and 800years. Analysis by infrared spectroscopy (ATR-FTIR), X-ray diffraction (XRD), and scanning electron microscopy energy dispersive spectrometry (SEM–EDS). Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 136(4): 1038-1046.
-Holik, H., 2006. Handbook of paper and board, John Wiley & Sons, 32p.
-Konuklar, M., Sacak, M., 2011. A new method for paper conservation: triple mixture of methyl
cellulose, carboxymethyl cellulose and nano-micro calcium hydroxide particles. Hacettepe journal of
biology and chemistry, 39 (2): 403-411.
-Klemm, D., Kramer, F., Moritz, S., Lindstrom, T., Ankerfors, M., Gray, D., Dorris, A., 2011. Nanocelluloses: A new familyof nature-based materials. Angew. Chem. Int. Ed. 50(4): 5438-5466.
-Lopez-Suevos, F., Eyholzer, C., Bordeanu, N.and Richter, K., 2010. DMA analysis and wood bonding of PVAc latex reinforced with cellulose nanofibrils. Cellulose, 17 (2): 387-398.
-Łojewska, J., Miśkowiec, P., Łojewski, T., Proniewicz, L., 2005. Cellulose oxidative and hydrolytic degradation: In situ FTIR approach. Polymer degradation and stability, 88(3): 512-520.
-Mirehki, F., Shakeri, A., 2013. Preparation and Characterization of Microcrystalline Cellulose (MCC) from Kenaf and Cotton Stem. 4(2): 23-32.
-Pinto, R., Neves, M., Neto, C., Trindade, T., 2012. Composites ofcellulose & metal nanoparticles, nanocomposites: new trends& developments. Chapter 4, 73-96p.
-Sequeira, S., Casanova, C., Cabrita, E., 2006. Deacidification of paper using dispersions of Ca (OH)2
nanoparticles in isopropanol. Study of efficiency. Journal of Cultural Heritage, 7 (2): 264-272.
-Standard test methods for Paper, board and pulp- Determination of pH of aqueous extracts- Part 1: Cold extraction. Standard national organization of Iran. 3568-1, 2007.
-Standard Test Method for Effect of moist heat on properties of paper and board, TAPPI T 544 sp-03, 2003.
-Volke, L., Ahn, K., Hahner, U., Gindl‑Altmutter, W., Potthast, A., 2017. Nano meets the sheet: adhesive-free application of nanocellulosic suspensions in paper conservation. Heritage science, 5(23): 2-17.
-Xu, Sh., Girouard, N., Schueneman, G., Shofner, M.L. and Meredith, J.C., 2013. Mechanical and thermal properties of waterborne epoxy composites containing cellulose nanocrystals. Polymer Journal, 54 (24): 6589- 6598.
-Zervos, S. Alexopoulou, I.,­ 2015. Paper conservation methods: a literature review. Cellulose, 22(5): 2859-2897.