Document Type : Research Paper

Authors

1 Faculty of Natural Resources, University of Tehran

2 Associate Professorو Department of Wood and Paper Sciences and Technology, Faculty of Natural Resources, University of Tehran, Shahid Chamran Blvd., 31585-4314, Karaj, Iran

3 Professor, Department of Wood and Paper Sciences and Technology, Faculty of Natural Resources, University of Tehran, Shahid Chamran Blvd., 31585-4314, Karaj, Iran

4 Associate Professor, Department of Wood and Paper Sciences and Technology, Faculty of Natural Resources, University of Tehran

Abstract

DOR:98.1000/1735-0913.1398.34.124.66.1.9.1580
Rice straw rice is one of the most important lignocellulose wastes in Iran and the world. In this research, rice straw as renewable lignocellulosic materials were used to produce nano-structural lignocellulosic aerogel. For this purpose, rice straw powder was first pre-treated in sodium hydroxide aqueous alkali solution and resulting gel form mixture was transformed into physically bonded lignocellulosic porous and ultra-lightweight aerogel through consecutive processes including freezing-thawing, solvent exchange and freeze-drying. The product properties including apparent density and total porosity were determined, and other physical and chemical properties were evaluated by SEM, FTIR, XRD, nitrogen absorption (BET) and DSC methods. The results showed that a significant amount of the rice straw compounds dissolved in aqueous alkali solution and removed during the subsequent stages of aerogel production. The resulting aerogel showed a nano dimensional structure composed of particles and interconnected nanofibers, which had a great chemical and physical difference from the original rice straw.

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Main Subjects

- Ashori, A., Babaee, M., Jonoobi, M. and Hamzeh, Y., (2014). Solvent-free acetylation of cellulose nanofibers for improving compatibility and dispersion. Carbohydrate Polymers, 102, 369-375.
- Aulin, C., Netrval, J., Wågberg, L. and Lindström, T., (2010). Aerogels from nanofibrillated cellulose with tunable oleophobicity. Soft Matter, 6(14), 3298-3305.
- Auxenfans, T., Crônier, D., Chabbert, B. and Paës, G., 2017. Understanding the structural and chemical changes of plant biomass following steam explosion pretreatment. Biotechnology for Biofuels, 10(1), 36-52.
- Babaee, M., Hamzeh, Y., Jonoobi, M. and Ashori, A., (2017). Chemical modification of cellulose nanofibers and its impact on their hydrophobicity and dispersibility. Journal of Forest and Wood Products, 67(2), 295-306.
- Bagewadi, Z. K., Mulla, S. I. and Ninnekar, H. Z., (2017). Optimization of laccase production and its application in delignification of biomass. International Journal of Recycling of Organic Waste in Agriculture, 6(4), 351-365.
- Carrillo, F., Colom, X., Sunol, J. J. and Saurina, J., (2004). Structural FTIR analysis and thermal characterisation of lyocell and viscose-type fibres. European Polymer Journal, 40(9), 2229-2234.
- Chen, M., Zhang, X., Zhang, A., Liu, C. and Sun, R., 2016. Direct preparation of green and renewable aerogel materials from crude bagasse. Cellulose, 23(2), 1325-1334.
- Ebrahimian Pirbazari, A., Fakhari Kisom, B. and Ghamangiz Khararoodi, M., 2015. Anionic surfactant-modified rice straw for removal of methylene blue from aqueous solution. Desalination and Water Treatment, 65(3), 1-15.
- Fan, P., Yuan, Y., Ren, J., Yuan, B., He, Q., Xia, G., Chen, F. and Song, R., 2017. Facile and green fabrication of cellulosed based aerogels for lampblack filtration from waste newspaper. Carbohydrate Polymers, 162, 108-114.
- Haghir Madadi, M., Bahramian A.R. and Hadizade Raeisi, H., 2018. Improvement in ablation and thermal properties of ultra-lightweight silicone/cork composites insulator using novolac aerogel. Iranian Journal of Polymer Science and Technology, 30(6), 512-529.
- Hu, S., Gu, J., Jiang, F. and Hsieh, Y. L., 2016. Holistic rice straw nanocellulose and hemicelluloses/lignin composite films. Sustainable Chemistry & Engineering, 4(3), 728-737.
- Huang, Y., Peng, L., Liu, Y., Zhao, G., Chen, J. Y. and Yu, G., 2016. Biobased nano porous active carbon fibers for high-performance supercapacitors. Applied Materials & Interfaces, 8(24), 15205-15215.
- Ibrahim, M. M., El-Zawawy, W. K., Jüttke, Y., Koschella, A. and Heinze, T., (2013). Cellulose and microcrystalline cellulose from rice straw and banana plant waste: preparation and characterization. Cellulose, 20(5), 2403-2416.
- Kettunen, M., Silvennoinen, R. J., Houbenov, Nykänen A., Ruokolainen J., Sainio J., Pore V., Kemell M., Ankerfors M., Lindström T., Ritala M., Ras R. H. A. and Ikkala O., (2011). Photoswitchable superabsorbency based on nanocellulose aerogels. Advanced Functional Materials, 21(3), 510-517.
- Li, F. H., Hu, H. J., Yao, R. S., Wang, H., and Li, M. M., 2012. Structure and saccharification of rice straw pretreated with microwave-assisted dilute lye. Industrial & Engineering Chemistry Research, 51(17): 6270-6274.
- Li, X., Ye, J., Chen, J., Yu, J., Ding, M. and Hong, J., 2015. Dissolution of wheat straw with aqueous NaOH/Urea solution. Fibers and Polymers, 16(11), 2368-2374.
- Li, J., Lu, Y., Yang, D., Sun, Q., Liu, Y. and Zhao, H., (2011). Lignocellulose aerogel from wood-ionic liquid solution (1-allyl-3-methylimidazolium chloride) under freezing and thawing conditions. Biomacromolecules, 12(5), 1860-1867.
- Liao, Q., Su, X., Zhu, W., Hua, W., Qian, Z., Liu, L. and Yao, J., (2016). Flexible and durable cellulose aerogels for highly effective oil/water separation. RSC Advances, 6(68), 63773-63781.
- Long, L.Y., Weng, Y.X. and Wang, Y.Z., 2018. Cellulose aerogels: synthesis, applications, and prospects. Polymers, 10(6), 623-651.
- Lu, Y., Sun, Q., Yang, D., She, X., Yao, X., Zhu, G., Liu, Y., Zhao, H. and Li, J., (2012). Fabrication of mesoporous lignocellulose aerogels from wood via cyclic liquid nitrogen freezing-thawing in ionic liquid solution. Journal of Materials Chemistry, 22(27), 13548-13557.
- Mussana, H., Yang, X., Tessima, M., Han, F., Iqbal, N. and Liu, L., 2018. Preparation of lignocellulose aerogels from cotton stalks in the ionic liquid-based co-solvent system. Industrial Crops and Products, 113, 225-233.
- Nishiwaki-Akine, Y., Kanazawa, S., Uneyama, T., Nitta, K. H., Yamamoto-Ikemoto, R. and Watanabe, T., 2017. Transparent woody film made by dissolution of finely divided Japanese beech in formic acid at room temperature. Sustainable Chemistry & Engineering, 5(12), 11536-11542.
- Pääkkö, M., Vapaavuori, J., Silvennoinen, R., Kosonen, H., Ankerfors, M., Lindström, T., Berglund, L.A., and Ikkala, O. (2008). Long and entangled native cellulose I nanofibers allow flexible aerogels and hierarchically porous templates for functionalities. Soft Matter, 4(12), 2492-2499.
- Pan, X. J. and Sano, Y., (1999). Atmospheric acetic acid pulping of rice straw IV: Physico-chemical characterization of acetic acid lignins from rice straw and woods. Part 1. Physical characteristics. Holzforschung, 53(5), 511-518.
- Rahnama, N., Mamat, S., Shah, U. K. M., Ling, F. H., Rahman, N. A. A. and Ariff, A. B., 2013. Effect of alkali pretreatment of rice straw on cellulase and xylanase production by local Trichoderma harzianum SNRS3 under solid state fermentation. BioResources, 8(2), 2881-2896.
- Sang, L., Luo, D., Xu, S., Wang, X. and Li, X., (2011). Fabrication and evaluation of biomimetic scaffolds by using collagen–alginate fibrillar gels for potential tissue engineering applications. Materials Science and Engineering: C, 31(2), 262-271.
- Singh, R., Tiwari, S., Srivastava, M. and Mina, U., (2013). Effect of combination of microwave and hydrogen peroxide (H2O2) pretreatment on enzymatic saccharification of rice straw. International Journal of Environmental Engineering and Management, 4(5), 529-542.
- Terinte, N., Ibbett, R. and Schuster, K. C., (2011). Overview on native cellulose and microcrystalline cellulose I structure studied by X-ray diffraction (WAXD): Comparison between measurement techniques. Lenzinger Berichte, 89, 118-131.
- Xu, M., Bao, W., Xu, S., Wang, X. and Sun, R., 2015. Porous cellulose aerogels with high mechanical performance and their absorption behaviors. BioResources, 11(1), 8-20.
- Wang, Z., Liu, S., Matsumoto, Y. and Kuga, S., (2012). Cellulose gel and aerogel from LiCl/DMSO solution. Cellulose, 19(2), 393-399.
- Zheng, Q., Zhou, T., Wang, Y., Cao, X., Wu, S., Zhao, M., Wang, H., Xu, M., Xheng, J. and Guan, X., 2018. Pretreatment of wheat straw leads to structural changes and improved enzymatic hydrolysis. Scientific Reports, 8(1), 1321.
- Zhu, Y., Yang, L., Wu, W., Wang, Z. and Jin, Y., 2016. Complete dissolution of ball-milled masson pine using an aqueous sodium hydroxide solvent. BioResources, 11(3), 6017-6025.