Research Paper
Pulp and paper
Hossein Jalali Torshizi; Abdollah Aabedi Bafraajerd; Reza Shidpour
Abstract
DOR:98.1000/1735-0913.1398.34.1.66.1.1578.32 Providing some paradox properties of paper products at the same is of utmost challenging issues of papermakers, e.g., attaining proper strength together with high water absorbency in hygienic papers. Because higher bonding resulted in lesser accessibility ...
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DOR:98.1000/1735-0913.1398.34.1.66.1.1578.32 Providing some paradox properties of paper products at the same is of utmost challenging issues of papermakers, e.g., attaining proper strength together with high water absorbency in hygienic papers. Because higher bonding resulted in lesser accessibility to the hydrophilic functional group. Therefore, hydrogel as an ever-increasing material in bulk cellulosic diapers were surficial coated on paper and compared with distillated water saturated papers. The prepared chitosan-acrylic acid (AA) hydrogel converted into nanoparticles by ultrasonic homogenizer and the nano scaled particles approved by Dynamic Light scattering (DLS). SEM images and paper caliper revealed the nanohydrogel coating layer. All papers water uptake coated with 1, 1.5 and 2% nanohydrogel increased significantly up to 50% compared to the untreated sample. Burst and dry tensile strengths along with water uptake improved, with no toleration in tear strength. Increased fiber bonding due to plenty of carboxylic acid in AA together with hydroxyl and amine groups in chitosan, along with nanohydrogel film formation as a complementary assembly and constituent with the cellulosic substrate of paper were resulted in strength improvement. Wet tensile strength of paper revealed remarkable increment at 2% coating application, only; without enhancing effects at the lower dosages. Paper opacity, brightness and whiteness stayed almost stable, but due to chitosan yellowish nature, the paper yellowness increased. The coated paper stiffness enhanced compared to untreated paper, but revealed lesser stiffness than water saturated papers. Water treated papers revealed caliper, tensile and burst indices reduction and stiffness rising.
Research Paper
Chemistry of wood
Seyed Hassan Sharifi; Saltanat Archin; Leila Aghanaghifar
Abstract
DOR:98.1000/1735-0913.1398.34.16.66.1.1575.1603 One of the most important sources of environmental pollution is dye from industrial wastewater which is harmful for human health and environment. Therefore, the aim of this study was to evaluate removal of Methylene Blue (MB) dye from aqueous solutions ...
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DOR:98.1000/1735-0913.1398.34.16.66.1.1575.1603 One of the most important sources of environmental pollution is dye from industrial wastewater which is harmful for human health and environment. Therefore, the aim of this study was to evaluate removal of Methylene Blue (MB) dye from aqueous solutions by straw using ultrasonic wave with response surface methodology. The batch experiment was conducted to evaluate the effect of dye concentration, contact time, adsorbent dosage and pH on dye removal from aqueous solution. Response surface methodology was applied to appraise the effect of these different variables. The dye concentration in the solutions was measured by spectrophotometer at the wavelength of 664 nm. The results showed that the optimum parameter values for maximum color removal efficiency were: dye concentration 20 mg/L, reaction time 8 min, dose of adsorbent 4 g/L and pH=9. The Maximum and minimum dye removal were obtained 92.29 and 47.5 percent, respectively. Analysis of variances test showed that the quadratic model was the best model to explain the interaction of variables. Based on analysis of variance (ANOVA), the coefficient of determination value (R2 =0.9116) was high, showing that the experimental values fitted well with the predicted values. In addition, the statistical analysis of the results indicated that in the range studied, dose of adsorbent and pH had a significant effect on color removal efficiency. The Gibbs free energy and enthalpy data verified its spontaneous and endothermic nature. In addition, survey of pseudo first and second order kinetics models presented that the adsorption process was compatible to pseudo-second order kinetics equation.
Research Paper
Pulp and paper
Bardia Sodeifi; noureddin Nazarnezhad; Seyed Hassan Sharifi
Abstract
DOR:98.1000/1735-0913.1398.34.45.66.1.1576.1610 In this research, the effect of coating with Polycaprolactone (PCL), nanocrystalline Cellulose (NCC) and zinc oxide Nanoparticle (ZnO NP) and their blend were investigated on the mechanical and optical properties. First, coating materials with specific ...
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DOR:98.1000/1735-0913.1398.34.45.66.1.1576.1610 In this research, the effect of coating with Polycaprolactone (PCL), nanocrystalline Cellulose (NCC) and zinc oxide Nanoparticle (ZnO NP) and their blend were investigated on the mechanical and optical properties. First, coating materials with specific condition (PCL 10%, NCC 4 and 6%, ZnO 3%) were coated on the papers. The coating materials weight on the papers was (2.2- 2.7 g/m2). The results showed that the mechanical properties (Tensile strength index, Burst strength index and Tear strength index) of the coated papers were enhanced with addition of NCC. The ternary blend of these coating materials had the best mechanical properties than the neat paper. With addition of NCC the brightness were enhanced and the opacity were reduced. Also, the color properties were improved with addition of NCC and ZnO and the effect of ZnO was more remarkable than NCC but, in ternary blend of materials, the color properties were improved with increasing the amount of NCC.
Research Paper
Management and Economics wood
Seyed Mahmoud Miri Tari; asghar tarmian; Mohammad Azadfallah; Abdolkhani Ali; Davood Efhamisisi
Abstract
DOR:98.1000/1735-0913.1398.34.45.66.1.1575.1575 Mold growth resistance of Polyurethane and Diotrol coatings containing natural (Thyme essential oil) and synthetic (IPBC) fungicides in both free and microencapsulated forms was studied. Polymethyl methacrylate (PMMA) microcapsules were prepared using solvent ...
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DOR:98.1000/1735-0913.1398.34.45.66.1.1575.1575 Mold growth resistance of Polyurethane and Diotrol coatings containing natural (Thyme essential oil) and synthetic (IPBC) fungicides in both free and microencapsulated forms was studied. Polymethyl methacrylate (PMMA) microcapsules were prepared using solvent evaporation method by means of oil emulsion formation in water. Mold growth resistance against Aspergillus niger was determined by Filter Paper Disc method before and after aging process according to ASTM D 5590 Standard. Adhesion strength and surface roughness of coated samples were also measured. Results revealed that biocide-free coatings cannot provide adequate protection against mold growth, and addition of biocides, especially IPBC, significantly improved the mold growth resistance. Even after the aging process, microencapsulated biocides were able to provide better protection against mold growth due to controlled-release mechanism and shielding-effect of polymeric shell. Although the surface roughness of polyurethane coating was increased by using of biocides in both forms, especially microencapsulated ones, its adhesion strength reduced.
Research Paper
Composite wood products
Moein Dehghan; Ali Ahmadi ladjimi; Habib Dahmardeh
Abstract
DOR:98.1000/1735-0913.1398.34.63.66.1.1575.1610 In the present research the biodegradability Properties of poly-lactic acid-canola stem flour composites in three levels of 25, 35, and 45% canola stem flour made by compression molding technique were studied . In order to study the biocompatibility behavior ...
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DOR:98.1000/1735-0913.1398.34.63.66.1.1575.1610 In the present research the biodegradability Properties of poly-lactic acid-canola stem flour composites in three levels of 25, 35, and 45% canola stem flour made by compression molding technique were studied . In order to study the biocompatibility behavior of the composite, three methods of biological degradation were used for Trametes versicolor and Gloeophyllum trabeum fungi, long-term water absorption and composites burial in the soil for 4 months. The results of statistical analyzes showed that the amount of composites weight loss increased against the degradation by fungi and burial in the soil by increasing the amount of rapeseed canola stem flour while pure poly-lactic acid had a very high durability against these factors. In addition, there was no effect on the weight loss of samples in the long run leach test so that the weight of composites and poly- lactic acid samples was constantly increasing and there was no effect on weight and thickness loss. The growth of myceliums fungi was clearly detectable and detectable in reviewing the images of electron microscopy from the fracture properties of composites, unlike poly-lactic acid so that fungi crossed their polymer into rapeseed shoot flour and reduced the weight of the composites. The results of the FTIR spectroscopy on poly-lactic acid prepared before and after exposure to the Gloeophyllum trabeum fungus confirmed the validity of the above results. According to the results of this study, poly-lactic acid, as a biodegradable polymer, has been shown to be very durable against degradation by natural biological agents.
Research Paper
Composite wood products
masoudreza habibi
Abstract
DOR:98.1000/1735-0913.1398.34.74.66.1.1578.1576 In this study, the effect of piling storage method of Bagasse was studied on the physical and mechanical properties of particleboard. Wet depitted Bagasse was used. In this study, Bagasse storage conditions included two moisture content (45% and 55%) and ...
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DOR:98.1000/1735-0913.1398.34.74.66.1.1578.1576 In this study, the effect of piling storage method of Bagasse was studied on the physical and mechanical properties of particleboard. Wet depitted Bagasse was used. In this study, Bagasse storage conditions included two moisture content (45% and 55%) and 4 storage times (1.5, 3, 4.5, 6 months). At the first, Bagasse chemical properties (pH, acid and alkaline buffering capacity) were determined. Then particleboards were fabricated. The physical and mechanical properties of the boards were measured and statistically analyzed. The results showed that at lower Bagasse moisture content, the sample pH and alkaline buffering capacity were decreased and acid buffering capacity increased. Also board bending properties (modulus of rupture and modulus of elasticity) and thickness swelling after 2 and 24 hours immersion in the water were reduced. Bagasse chemical properties tend to be acidic up to storage time of 3 month and the minimum of board bending properties and internal bond were obtained in this storage time. The physical properties of boards were improved with increasing of storage time.
Research Paper
Pulp and paper
Mohaddeseh Ramezanpour-Charvadeh; Hamid reza Rodi; Hossein Jalali-Torshizi; Hamidreza Ghomi marzdashti
Abstract
DOR:98.1000/1735-0913.1398.34.76.66.1.9.1578 A need for control of pathogenic microorganisms in contaminated environments has motivated to prepare the products including antibacterial papers resisting against growth of such creatures. Different methods and materials have been used to make these papers. ...
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DOR:98.1000/1735-0913.1398.34.76.66.1.9.1578 A need for control of pathogenic microorganisms in contaminated environments has motivated to prepare the products including antibacterial papers resisting against growth of such creatures. Different methods and materials have been used to make these papers. The purpose of current research is to fabricate silver nanoparticle by means of plasma method and investigate the effect of adding it to the Kraft pulp on the properties of resulting papers. To do this, silver nanoparticles have been fabricated in optimized conditions of 1 kHz frequency, 2 A current and 4 kV voltage, using an instrument developed in Laser and Plasma Research Institute, Shahid Beheshti University. The DLS test confirmed the average size of silver particles at nano scale ( 41.2 nm). Then, the prepared silver nanoparticles were added by levels of 0, 25, 50 and 75 ppm to the Kraft pulp accompanying by cationic polyacrylamide (CPAM) as a retention aid to about 0.05 based on oven dry of fibers. The results of paper properties evaluation (having basis weight 60±3 g/m2) have shown that addition of silver nanoparticles synthesized by plasma method lead to loss of paper strength characteristics. The paper brightness has also exhibited a meaningful decrease. However, the paper opacity and antibacterial property develop significantly in the consumption levels higher than 50 ppm.
Research Paper
Physics and Mechanical Wood
Parastoo Majdabadifarahani; Mehran Roohnia; amir lashgari
Abstract
DOR:98.1000/1735-0913.1398.34.87.66.1.1585.1588 This study deals with the possibility of evaluation and estimating the wood density in Quercus castaneifolia and Fagus orientalis. Wood samples were prepared and cut firstly in 4×20×30 cm (thickness×width×length). Then their density ...
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DOR:98.1000/1735-0913.1398.34.87.66.1.1585.1588 This study deals with the possibility of evaluation and estimating the wood density in Quercus castaneifolia and Fagus orientalis. Wood samples were prepared and cut firstly in 4×20×30 cm (thickness×width×length). Then their density was calculated after 72 hours of conditioning in an oven at 60°C temperature. In thermography process, the temporal temperature was monitored in 1st, 5th, 10, 20, 30, 45 and 60th minutes of cooling (monitoring steps). Investigating the effects of shape factor and dimension on thermographic density evaluation errors, the specimens were cut down in two more steps to 3×20×30 cm and 2×15×20 cm and the course of thermography experiments was repeated. The relationships of shape factor, density and the ratio of density to the shape factor with the logarithmic cooling rate were evaluated separately. Results showed that density without considering the shape factor variations was not sufficiently correlated to the cooling rate. But the ratios of the density to their proper shape factors were promising for the density evaluations from the cooling rates. However, it is suggested to revise this non-destructive method using a larger variety of the wood specimens and species.
Research Paper
Pulp and paper
somayeh heydari; Ahmad Reza Saraeyan; Mohammad Reza Dehghani Firouzabadi; Alireza Shakeri; babak shokri
Abstract
DOR:98.1000/1735-0913.1398.34.100.66.1.9.1604 In this study, EVOH was coated on paper made of CMP pulp by extrusion method in order to improve the paper's barrier properties of oxygen transmission. Ethylene vinyl alcohol (EVOH) shows poor moisture resistance despite less gas permeability. Then, dimethoxydimethylsilane ...
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DOR:98.1000/1735-0913.1398.34.100.66.1.9.1604 In this study, EVOH was coated on paper made of CMP pulp by extrusion method in order to improve the paper's barrier properties of oxygen transmission. Ethylene vinyl alcohol (EVOH) shows poor moisture resistance despite less gas permeability. Then, dimethoxydimethylsilane was deposited using Plasma Enhanced Chemical Vapor Deposition on EVOH film as the hydrophobic layer. A random factorial experiment was designed with three factors at three levels including time (6-8-10 min), pressure (30-0400-500 m Torr), and radio frequency power (50-70-90 W). The contact angle, oxygen transmission rate, tensile strength, and strain energy were measured to obtain the optimum condition. Expert Design method using response surface was used to optimize the condition coating Dimethoxydimethylsilane in order to improve the hydrophobic properties, reduce OTR, increase tensile strength and strain energy. Based on this method the optimum condition was suggested as: time 6 min, pressure 499.99 m Torr and power 50W. Keywords: Extrusion , Contact angle, Oxygen transmission rate, Response Surface methodology.
Research Paper
Pulp and paper
Zohreh Taheri; Hamidreza Rodi; Hossein Jalali-Torshizi; Reza Shidpour
Abstract
DOR:98.1000/1735-0913.1398.34.112.66.1.1578.1610 Nowadays, the barrier property against water take up of different packaging papers which mostly prepared from recycled fibers is of highly significance for paper manufacturers. In current study, the effect of AKD sizing agent has been examined on the properties ...
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DOR:98.1000/1735-0913.1398.34.112.66.1.1578.1610 Nowadays, the barrier property against water take up of different packaging papers which mostly prepared from recycled fibers is of highly significance for paper manufacturers. In current study, the effect of AKD sizing agent has been examined on the properties of papers made from recycled fibers of Atrak pulp and paper industries. Sizing of pulp suspension using AKD was conducted at levels of 0, 0.5, 1 and 1.5 % based on oven dry (OD) pulp in neutral pH (7), according to the TAPPI standard methods. Then, by preparation of handsheets with basis weight of about 60±3 g/m2, their Cobb test (60 second) and different characteristics were evaluated. According to the statistical analysis of the results, up to 1 % AKD consumption amount based on OD pulp exhibited for optimum level in internal sizing of these recycled fibers. In such AKD level, water take up of size-free papers revealed 174±7.4 g/m2, decreased to the value of about 24±1.7 g/m2 in AKD-treated papers. Further, contact angle of water droplet with the paper surface increased from 35.2º to 109.1º. Applying 1 % of AKD, paper tensile index increased to 33.2±1.01 N.m/g by 2.4 unit compared to the base paper. Apparently, such phenomena can be attributed to the AKD potential in creating hydrogen bonds which concurrent to the development of paper water repellency, resulted in improving bonding-ability of paper network. Additionally, AKD treatment led to in meaningful increase of paper opacity. This can also be attributed to the increase in filler retention in fibers network, which influences the development of light scattering from the paper surface.
Research Paper
Chemical conversion
Atefe Rahimi; Ali Abdolkhani; Yahya Hamzeh; Sahab Hedjazi
Abstract
DOR:98.1000/1735-0913.1398.34.124.66.1.9.1580 Rice straw rice is one of the most important lignocellulose wastes in Iran and the world. In this research, rice straw as renewable lignocellulosic materials were used to produce nano-structural lignocellulosic aerogel. For this purpose, rice straw powder ...
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DOR:98.1000/1735-0913.1398.34.124.66.1.9.1580 Rice straw rice is one of the most important lignocellulose wastes in Iran and the world. In this research, rice straw as renewable lignocellulosic materials were used to produce nano-structural lignocellulosic aerogel. For this purpose, rice straw powder was first pre-treated in sodium hydroxide aqueous alkali solution and resulting gel form mixture was transformed into physically bonded lignocellulosic porous and ultra-lightweight aerogel through consecutive processes including freezing-thawing, solvent exchange and freeze-drying. The product properties including apparent density and total porosity were determined, and other physical and chemical properties were evaluated by SEM, FTIR, XRD, nitrogen absorption (BET) and DSC methods. The results showed that a significant amount of the rice straw compounds dissolved in aqueous alkali solution and removed during the subsequent stages of aerogel production. The resulting aerogel showed a nano dimensional structure composed of particles and interconnected nanofibers, which had a great chemical and physical difference from the original rice straw.
Research Paper
amir lashgari; seyyedeh zahra hashemi; BABAK RANJBAR
Abstract
DOR:98.1000/1735-0913.1398.34.134.66.1.1576.1585 Wood is a natural material, human beings have long been in close contact with wood, and psychologically, wooden structures, and any kind of wood-craftsmanship, give people a sense of relaxation. This research was conducted to investigate the relationship ...
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DOR:98.1000/1735-0913.1398.34.134.66.1.1576.1585 Wood is a natural material, human beings have long been in close contact with wood, and psychologically, wooden structures, and any kind of wood-craftsmanship, give people a sense of relaxation. This research was conducted to investigate the relationship between wood color and wood decor at work and living on emotional and psychological reactions of individuals. To this end, 384 people from Karaj city were selected as random sampling method. In this research, a researcher-made questionnaire was used. In inferential statistics, SPSS tests including Kolmogorov-Smirnov test (for data normalization) and correlation test were used. Results of research analyzes, research hypotheses based on the effect of the color of the decor of the place of residence and work on the reactions Psychological and emotional affirmation. Considering the importance of the subject in psychology, in this research, the most recent methods and methods have been used. Keywords: color decoration, psychological responses, emotional reactions, research, SPSS, wood.
Research Paper
Composite wood products
Abbas Tamjidi; Mohamad Mehdi Faezipour; Habibollah Khademi Eslam; Ghanbar Ebrahimi; Kazem DoosthoseinI
Abstract
DOR:98.1000/1735-0913.1398.34.140.66.1.9.1586 In this study, the possibility of three-layered oriented strand board production from hornbeam (Carpinus betulus L.) wood was evaluated. Two levels of press time (6 and 8 minutes) and three levels of press temperature (180˚C, 200˚C and 220˚C) were applied ...
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DOR:98.1000/1735-0913.1398.34.140.66.1.9.1586 In this study, the possibility of three-layered oriented strand board production from hornbeam (Carpinus betulus L.) wood was evaluated. Two levels of press time (6 and 8 minutes) and three levels of press temperature (180˚C, 200˚C and 220˚C) were applied and 12 mm thick laboratory boards were made from hornbeam wood. The strands on the surface layers were aligned in the long direction of the board and the middle layer strands are cross aligned to the surface layers. In all treatments, board targeted density of 0/7 g/cm3 and mat moisture content of 7% and phenol-formaldehyde resin (PF) content of 7% based on the oven dry weight of the strands were kept constant. The mechanical and physical properties of the boards were measured as defined in relevant European standards test methods EN 300. The internal bound (IB) and thickness swelling (TS24) of boards were significantly improved as the press time increased from 6 to 8 minutes. The modulus of rupture (MOR) and internal bound (IB) and thickness swelling (TS24) were significantly improved as the press temperature increased from 180˚C to 220˚C. Overall results showed that the highest MOR and IB and the lowest TS24 were achieved at 8 minutes press time and 220˚C press temperature and all boards made from this mentioned conditions exceed the EN 300 standards for MOR, MOE, IB and TS24.
