Document Type : Research Paper

Authors

1 , PhD student, Conservation of Historical and Cultural Properties, Faculty of conservation, Art University of Isfahan, Isfahan, Iran.

2 Assistant Professor, Conservation of Historical and Cultural Properties, Faculty of conservation, Art University of Isfahan, Isfahan, Iran.

3 Associate Professor, Faculty of Chemistry, Isfahan University of technology, Isfahan, Iran.

Abstract

In this study, the effect of cellulose nanofibers on the properties of handmade papers produced from hemp and wood pulp fibers was assessed. Also, the nanofiber application as a strength enhancer for restoration of handmade papers was investigated. Firstly, handmade paper samples were prepared. Cellulose nanofibers with weight percentages of 0.5, 1 and 2% were prepared as a suspension in water the samples were treated by the suspensions. Blank and treated samples were tolerated accelerated aging process and then pH, colorimetric and tensile strength tests were performed. Comparison of blank and treated samples results showed that the tensile strength of the both groups of hemp (H) and wood pulp (WP) papers were increased after treatment by cellulose nanofibers. Aging process caused to reduction in tensile strength of treated samples but it was increased in comparison with blank samples before and after aging. The pH of the papers in both groups was in the alkaline range after the treatment and aging. Brightness of papers was increased after the treatment and color changes in the samples were due to their accelerated aging conditions.

Keywords

- Abdolalizadeh, M., Azadi Boyaghchi, M., Mohammadi Achachluei, M., and Bahremandi Poorfard, R., 2016. Study of effects of Tiophanate methyl and Carbendazim fungicides on paper structure by application of Fourier transform infrared spectroscopy. Journal of Research on Archaeometry, 2(1), 55-66.
- Area, M.C. and Cheradame, H., 2011. Paper aging and degradation: recent findings and research methods. BioResources 6(4): 5307-5337.
- Ansari, N., 2008. Principles and theories physical tests on fibers and textile, 1st Ed., Amirkabir University, Tehran, 83p.
- Aliniyay Lakani, S. and Afra, E., 2011. Nanofiber Cellulose and its Application in Improving Paper Properties. First National Conference on Nanomaterials and Nanotechnology, Islamic Azad University of Shahrood.
- Biricik, Y., Sonmez, S. and Ozden, O., 2011. Effects of surface sizing with starch on physical strength properties of paper. Asian Journal of Chemistry, 23(7), 3151-3154.
- Čabalová, I., Kačík, F., Gojný, J., Češek, B., Milichovský, M., Mikala, O., Tribulová, T. and Ďurkovič, J., 2017. Changes in the chemical and physical properties of paper documents due to natural ageing. BioResources, 12(2), 2618-2634.
- Dreyfuss-Deseigne, R., 2017. Nanocellulose Films in Art Conservation. Paper Conservation, 18(1): 18-29.
- Dreyfuss-Deseigne, R., 2017. A New Mending Material: Nanocellulose Film. Journal of Paper Conservation, 18(1): 36-37.
- Emsley, A.M., Heywood, R.J., Ali, M. and Xiao, X., 2000. Degradation of cellulosic insulation in power transformers. Part 4: Effects of ageing on the tensile strength of paper. IEE Proceedings-Science, Measurement and Technology, 147(6), 285-290.
- Ghorbani, M., Samanian, K., Afsharpour, M. and Sabet Jazari, A., 2017. Introducing and Comparing Methods for Consolidation of Paper records and Suggesting the Use of Cellulose Nano-Fibers for Conservation of such records. GANJINE-YE ASNAD, 26(4): 110-131.
- Hadilam, M., Afra, E., Yousefi, H. and Ghasemian, A., 2012. Investigate Resistive and barrier against moisture behavior of cellulose paper containing Nanofiber cellulose. First National Conference on Nanotechnology and its Applications in Agriculture and Natural Resources. University of Tehran – Karaj, Faculty of Agriculture and Natural Resources.
- Hassan, E.A., Hassan, M.L. and Oksman, K., 2011. Improvement of paper sheets properties of bagasse pulp with microfibrillated cellulose isolated from xylanase treated bagasse. Wood and Fiber Science, 43(1): 1-7.
- Hummert, E., Henniges, U. and Potthast, A., 2013. Stabilisation Treatments with Aerosols: Evaluating the Penetration Behaviour of Gelatine and Methylcellulose. Restaurator, 34:134–171.
- Holik, H., 2006. Handbook of paper and board, John Wiley & Sons, 32p.
Jablonský, M., Katuščák, S., Kačik, F. and Kačiková, D., 2011. Changes in newsprint paper during accelerated ageing. Cellulose Chemistry and Technology, 45(5), 405-411.
- Lopez-Suevos, F., Eyholzer, C., Bordeanu, N.and Richter, K., 2010. DMA analysis and wood bonding of PVAc latex reinforced with cellulose nanofibrils. Cellulose, 17 (2): 387-398.
- Rosenau, T., Potthast, A., Krainz, K., Yoneda, Y., Dietz, T., Shields, Z.P.I. and French, A.D., 2011. Chromophores in cellulosics, VI. First isolation and identification of residual chromophores from agedcotton linters, Springer Science Business Media, 18(4): 1623–1633.
- Soltani, Z., Farahmand Borujeni, H. and Abed Esfehani, A., 2016. The impact of additive saffron on
prevention of paper corrosion caused by Iron-Gall ink. Journal of Saffron Research, 4(1), 87-102.
- Standard test methods for Paper and board - Determination of tensile properties - Part 3: Constant rate of elongation method (100 mm/min)-Test method. Standard national organization of Iran. 14471-3, 2013.
- Standard Test Method for Determination of Effect of Dry Heat on Properties of Paper and Board, Annual Book of ASTM Standards, 10.01, D 776 – 92, 2001.
 - Standard test methods for Paper, board and pulp- Determination of pH of aqueous extracts- Part 1: Cold extraction. Standard national organization of Iran. 3568-1, 2007.
- Teixeira, F.S., dos Reis, T.A., Sgubin, L., Thome, L.E., Bei, I.W., Clemencio, R.E., Correa, B. and Salvadori, M.C., 2018. Disinfection of ancient paper contaminated with fungi using supercritical carbon dioxide. Journal of Cultural Heritage, 30,110-116.
- Vinas, V. and Vinas, R., 1992. Traditional restoration techniques: a RAMP study, UNESCO, Paris, 34.
- Volke, L., Ahn, K., Hahner, U., Gindl‑Altmutter, W. and Potthast, A., 2017. Nano meets the sheet: adhesive-free application of nanocellulosic suspensions in paper conservation. Heritage science, 5(23): 2-17.
- Xu, Sh., Girouard, N., Schueneman, G., Shofner, M.L. and Meredith, J.C., 2013. Mechanical and thermal properties of waterborne epoxy composites containing cellulose nanocrystals. Polymer Journal, 54 (24): 6589- 6598.
- Zervos, S., 2010. Natural and accelerated ageing of cellulose and paper: A literature review. 393-402.
- Zervos, S. and Alexopoulou, I.,­ 2015. Paper conservation methods: a literature review. Cellulose, 22(5): 2859-2897.